Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Iodine trichloride is an interhalogen compound of iodine and chlorine. It is bright yellow but upon time and exposure to light it turns red due to the presence of elemental iodine. In the solid state is present as a planar dimer I2Cl6, with two bridging Cl atoms.[1]
It can be prepared by reacting iodine with an excess of liquid chlorine at −70 °C. In the molten state it is conductive, which may indicate dissociation:[2]
I2Cl6 ⇌ ICl+ 2 + ICl− 4
Iodine trichloride can be created by heating a mixture of liquid iodine and chlorine gas to 105 °C.
It is an oxidizing agent, capable of causing fire on contact with organic materials.
^K. H. Boswijk; E. H. Wiebenga (1954). "The crystal structure of I2Cl6 (ICl3)". Acta Crystallographica. 7 (5): 417–423. doi:10.1107/S0365110X54001260.
^Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
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heavier than Y), and iodine is no exception. Iodine forms all three possible diatomic interhalogens, a trifluoride and trichloride, as well as a pentafluoride...
monochloride liquid is collected. Excess chlorine converts iodine monochloride into iodinetrichloride in a reversible reaction: ICl + Cl2 ⇌ ICl3 ICl has two...
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such as in concentrated hydrochloric acid), iodic acid is reduced to iodinetrichloride, a golden yellow compound in solution and no further reduction occurs...
and chlorine, while iodine is the least reactive of them all. The facility of dehydrohalogenation follows the reverse trend: iodine is most easily removed...
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of Chemistry Introduction to Chemistry (1871) To the knowledge of iodinetrichloride ; Athens 1877 Analysis of chrome iron stone ; Athens 1877 Analysis...
with iodine. Among the binary compounds of ruthenium, these high oxidation states are known only in the oxides and fluorides. Ruthenium trichloride is a...
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