The inorganic imide is an inorganic chemical compound containing
an anion with the chemical formula HN2−, in which nitrogen atom is covalently bonded to one hydrogen atom (as in lithium imide Li2NH and calcium imide CaNH). The other name of that anion is monohydrogen nitride.
functional groups with the chemical formulas −NH− or =NH, in which nitrogen atom is also covalently bonded to one hydrogen atom, with two covalent single bonds or one covalent double bond from the nitrogen atom to other atoms, respectively (as in heptasulfur imide S7NH, sulfur diimide S(=NH)2 and nitroxyl O=NH).
Organic imides have the functional groups −NH− or =NH as well.
The imides are related to the inorganic amides, containing the H2N− anions, the nitrides, containing the N3− anions and the nitridohydrides or nitride hydrides, containing both nitride N3− and hydride H− anions.
In addition to solid state imides, molecular imides are also known in dilute gases, where their spectrum can be studied.
When covalently bound to a metal, an imide ligand produces a transition metal imido complex.
When the hydrogen of the imide group is substituted by an organic group, an organoimide results. Complexes of actinide and rare earth elements with organoimides are known.[1]
^Schädle, Dorothea; Anwander, Reiner (2019). "Rare-earth metal and actinide organoimide chemistry". Chemical Society Reviews. 48 (24): 5752–5805. doi:10.1039/c8cs00932e. PMID 31720564. S2CID 207938163.
The inorganicimide is an inorganic chemical compound containing an anion with the chemical formula HN2−, in which nitrogen atom is covalently bonded...
polyimides. Inorganicimides are also known as solid state or gaseous compounds, and the imido group (=NH) can also act as a ligand. Most imides are cyclic...
Lithium imide is an inorganic compound with the chemical formula Li2NH. This white solid can be formed by a reaction between lithium amide and lithium...
Heptasulfur imide is the inorganic compound with the formula S7NH. It is a pale yellow solid that is, like elemental sulfur, highly soluble in carbon disulfide...
carbocycles).[citation needed] Inorganic atoms form cyclic compounds as well. Examples include sulfur and nitrogen (e.g. heptasulfur imide S7NH, trithiazyl trichloride...
Preparative Inorganic Chemistry. Vol. 1 (2nd ed.). New York, NY: Academic Press. p. 1043. Greenlee, K. W.; Henne, A. L. (1946). "Sodium Amide". Inorganic Syntheses...
In chemistry, an ester is a compound derived from an acid (organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group...
Kurpil, B.; Antonietti, M. (June 2017). "Highly crystalline poly(heptazine imides) by mechanochemical synthesis for photooxidation of various organic substrates...
ammonolysed quickly and completely by liquid ammonia as follows to form an imide: SiS 2 + 4 NH 3 → Si(NH) 2 + 2 NH 4SH It reacts with the sulfides of sodium...
Polyimide (sometimes abbreviated PI) is a polymer containing imide groups belonging to the class of high-performance plastics. With their high heat-resistance...
The term carbonyl can also refer to carbon monoxide as a ligand in an inorganic or organometallic complex (a metal carbonyl, e.g. nickel carbonyl). The...
In chemistry a phosphine imide (sometimes abbreviated to phosphinimide) also known as a iminophosphorane is a functional group with the formula R3P=NR...
of the bacterium Neisseria meningitidis or on proteins localized nearby. Imides are structurally related analogues, where the bridging oxygen is replaced...
pharmaceuticals such as Prozac have trifluoromethyl groups. For information on inorganic halide chemistry, see halide. Halocarbons are typically classified in...
medium. It may be, for example, a compound of lithium bis(fluorosulfonyl)imide (LiFSI) and high molecular weight poly(ethylene oxide) (PEO), a high molecular...
dichloride (or disulphur dichloride by the British English spelling) is the inorganic compound of sulfur and chlorine with the formula S2Cl2. It is an amber...
the removal of one or more hydroxyl groups from an oxoacid, including inorganic acids. It contains a double-bonded oxygen atom and an organyl group (R−C=O)...
sometimes a disulfide bridge and usually derived from two thiol groups. In inorganic chemistry, the anion appears in a few rare minerals, but the functional...
hydrolysis of oximes proceeds easily by heating in the presence of various inorganic acids, and the oximes decompose into the corresponding ketones or aldehydes...
compounds containing multiple nitrile groups are known as cyanocarbons. Inorganic compounds containing the −C≡N group are not called nitriles, but cyanides...
hydride (LiAlH4) reduces some but not all sulfones to sulfides.: 1851 In inorganic chemistry, when the group −S(=O)2− is not connected to any carbon atoms...
Global Information