Gradual destruction of materials by chemical reaction with its environment
For the Front Line Assembly album, see Corrosion (album).
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Mechanical failure modes
Buckling
Corrosion
Corrosion fatigue
Creep
Fatigue
Fouling
Fracture
Hydrogen embrittlement
Impact
Liquid metal embrittlement
Mechanical overload
Metal-induced embrittlement
Stress corrosion cracking
Sulfide stress cracking
Thermal shock
Wear
Yielding
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.[1][2]
In the most common use of the word, this means electrochemical oxidation of metal in reaction with an oxidant such as oxygen, hydrogen, or hydroxide. Rusting, the formation of red-orange iron oxides, is a well-known example of electrochemical corrosion. This type of corrosion typically produces oxides or salts of the original metal and results in a distinctive coloration. Corrosion can also occur in materials other than metals, such as ceramics or polymers, although in this context, the term "degradation" is more common. Corrosion degrades the useful properties of materials and structures including mechanical strength, appearance, and permeability to liquids and gases.
Many structural alloys corrode merely from exposure to moisture in air, but the process can be strongly affected by exposure to certain substances. Corrosion can be concentrated locally to form a pit or crack, or it can extend across a wide area, more or less uniformly corroding the surface. Because corrosion is a diffusion-controlled process, it occurs on exposed surfaces. As a result, methods to reduce the activity of the exposed surface, such as passivation and chromate conversion, can increase a material's corrosion resistance. However, some corrosion mechanisms are less visible and less predictable.
The chemistry of corrosion is complex; it can be considered an electrochemical phenomenon. During corrosion at a particular spot on the surface of an object made of iron, oxidation takes place and that spot behaves as an anode. The electrons released at this anodic spot move through the metal to another spot on the object, and reduce oxygen at that spot in presence of H+ (which is believed to be available from carbonic acid (H2CO3) formed due to dissolution of carbon dioxide from air into water in moist air condition of atmosphere. Hydrogen ion in water may also be available due to dissolution of other acidic oxides from the atmosphere). This spot behaves as a cathode.
^Jones, Denny A. (1991). Principles and prevention of corrosion. New York : Toronto : New York: Macmillan Pub. Co. ; Collier Macmillan Canada ; Maxwell Macmillan International Pub. Group. ISBN 978-0-02-361215-2.
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