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Diphenylchlorarsine information


Diphenylchlorarsine
Names
Preferred IUPAC name
Diphenylarsinous chloride
Other names
diphenylchlorarsine, diphenylchloroarsenic, chlorodiphenylarsane, sneezing gas
Identifiers
CAS Number
  • 712-48-1 checkY
3D model (JSmol)
  • Interactive image
  • Interactive image
Abbreviations Ph2AsCl
ChemSpider
  • 12306 checkY
ECHA InfoCard 100.010.839 Edit this at Wikidata
PubChem CID
  • 12836
UNII
  • 1H39V3559B checkY
CompTox Dashboard (EPA)
  • DTXSID30858733 Edit this at Wikidata
InChI
  • InChI=1S/C12H10AsCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H checkY
    Key: YHHKGKCOLGRKKB-UHFFFAOYSA-N checkY
  • InChI=1/C12H10AsCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
    Key: YHHKGKCOLGRKKB-UHFFFAOYAA
SMILES
  • Cl[As](C1=CC=CC=C1)C2=CC=CC=C2
  • Cl[As](c1ccccc1)c2ccccc2
Properties
Chemical formula
C12H10AsCl
Molar mass 264.59 g mol−1
Appearance colorless crystalline solid
Density 1.55 g/cm3
Melting point 42 °C (108 °F; 315 K)
Boiling point 307.2 °C (585.0 °F; 580.3 K)
Magnetic susceptibility (χ)
-145.5·10−6 cm3/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Diphenylchloroarsine (DA) is the organoarsenic compound with the formula (C6H5)2AsCl. It is highly toxic and was once used in chemical warfare. It is also an intermediate in the preparation of other organoarsenic compounds. The molecule consists of a pyramidal As(III) center attached to two phenyl rings and one chloride. It was also known as sneezing oil during World War I by the Allies.

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