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Deuterated methanol information


Deuterated methanol
Names
Preferred IUPAC name
(2H3)Methan(2H)ol
Identifiers
CAS Number
  • 811-98-3
3D model (JSmol)
  • Interactive image
Beilstein Reference
1733278
ChEBI
  • CHEBI:156265
ChemSpider
  • 64640 checkY
ECHA InfoCard 100.011.253 Edit this at Wikidata
EC Number
  • 212-378-6
PubChem CID
  • 71568
UN number 1230
CompTox Dashboard (EPA)
  • DTXSID801010038 Edit this at Wikidata
InChI
  • InChI=1S/CH4O/c1-2/h2H,1H3/i1D3,2D
    Key: OKKJLVBELUTLKV-MZCSYVLQSA-N
SMILES
  • [2H]OC([2H])([2H])[2H]
Properties
Chemical formula
CD4O
Molar mass 36.0665 g mol−1
Density 0.888 g cm−3
Melting point −98 °C (−144 °F; 175 K)
Boiling point 65 °C (149 °F; 338 K)
Thermochemistry
Heat capacity (C)
87.9 J K−1 mol−1
Hazards
GHS labelling:
Pictograms
GHS02: FlammableGHS06: ToxicGHS08: Health hazard
Signal word
Warning
Hazard statements
H225, H301, H311, H331, H370
Precautionary statements
P210, P233, P240, P241, P242, P243, P260, P261, P264, P270, P271, P280, P301+P310, P302+P352, P303+P361+P353, P304+P340, P307+P311, P311, P312, P321, P322, P330, P361, P363, P370+P378, P403+P233, P403+P235, P405, P501
Flash point 11 °C (52 °F; 284 K)
Related compounds
Related compounds
Methanol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Deuterated methanol (CD3OD), is a form (called an isotopologue) of methanol (CH3OH) in which the hydrogen atoms ("H") are replaced with deuterium (heavy hydrogen) isotope ("D").[1] Deuterated methanol is a common solvent used in NMR spectroscopy.

Deuterated methanol was first detected in interstellar space was Orion-KL in 1988 by scientists at the Max Planck Institute for Radio Astronomy.[2]

  1. ^ Bizzocchi, L.; Caselli, P.; Spezzano, S.; Leonardo, E. (2014-09-01). "Deuterated methanol in the pre-stellar core L1544". Astronomy & Astrophysics. 569: A27. arXiv:1408.2491. Bibcode:2014A&A...569A..27B. doi:10.1051/0004-6361/201423858. ISSN 0004-6361.
  2. ^ Mauersberger, R.; Henkel, C.; Jacq, T.; Walmsley, C. M. (1988-04-01). "Deuterated methanol in Orion". Astronomy and Astrophysics. 194: L1–L4. Bibcode:1988A&A...194L...1M. ISSN 0004-6361.

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Deuterated methanol

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Deuterated methanol (CD3OD), is a form (called an isotopologue) of methanol (CH3OH) in which the hydrogen atoms ("H") are replaced with deuterium (heavy...

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Proton nuclear magnetic resonance

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D2O, deuterated acetone, (CD3)2CO, deuterated methanol, CD3OD, deuterated dimethyl sulfoxide, (CD3)2SO, and deuterated chloroform, CDCl3. However, a solvent...

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Deuterated solvent

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Deuterated acetone Deuterated benzene Deuterated chloroform Deuterated dichloromethane Deuterated DMF Deuterated DMSO Deuterated ethanol Deuterated methanol...

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Methanol

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Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical compound and the simplest aliphatic alcohol, with the...

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Acetic acid

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the manufacture of indigo dye. Because both methanol and carbon monoxide are commodity raw materials, methanol carbonylation long appeared to be attractive...

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Deuterated etifoxine

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Deuterated etifoxine (developmental code name GRX-917) is a deuterated drug which is under development for the treatment of anxiety disorders and mood...

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Deuterium

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instrument tuned for light-hydrogen. Deuterated solvents (including heavy water, but also compounds like deuterated chloroform, CDCl3) are therefore routinely...

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Heavy water

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to humans, but a large amount would be needed for poisoning to occur. Deuterated water (HDO) occurs naturally in normal water and can be separated through...

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Dichloromethane

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Atmospheric abundances of dichloromethane have been increasing in recent years. Deuterated dichloromethane Chloromethane Trichloromethane Tetrachloromethane List...

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Isopropyl alcohol

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polyvinyl butyral, many oils, alkaloids, and natural resins. Unlike ethanol or methanol, isopropyl alcohol is not miscible with salt solutions and can be separated...

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Formic acid

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formic acid are called formates. Industrially, formic acid is produced from methanol. In nature, formic acid is found in most ants and in stingless bees of...

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Cyclohexane

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moderate pressures above 30 MPa, where phase IV appears exclusively in deuterated cyclohexane (application of pressure increases the values of all transition...

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Formaldehyde

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such as methanol, is usually added to suppress oxidation and polymerization. A typical commercial-grade formalin may contain 10–12% methanol in addition...

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Ethanol

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antiseptic, disinfectant, solvent for some medications, and antidote for methanol poisoning and ethylene glycol poisoning. It is used as a chemical solvent...

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Ethylene glycol

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less stringent environmental regulations. The oxidative carbonylation of methanol to dimethyl oxalate provides a promising approach to the production of...

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Dimethyl ether

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distillation of methanol and sulfuric acid. Approximately 50,000 tons were produced in 1985 in Western Europe by dehydration of methanol: 2 CH3OH → (CH3)2O...

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Chloroform

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and sodium hypochlorite: 3 NaOCl + (CH3)2CO → CHCl3 + 2 NaOH + CH3COONa Deuterated chloroform is an isotopologue of chloroform with a single deuterium atom...

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NMR tube

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an appropriate solvent. For 1H NMR experiments, this will usually be a deuterated solvent such as CDCl3. Sufficient solvent should be used in order to fill...

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Outer space

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v t e Molecules detected in outer space Molecules Deuterated molecules Ammonia Ammonium ion Formaldehyde Formyl radical Heavy water Hydrogen cyanide Hydrogen...

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Methyl acetate

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carbonylation of methanol as a byproduct of the production of acetic acid. Methyl acetate also arises by esterification of acetic acid with methanol in the presence...

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Silicone grease

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xylene, mineral spirits, and chlorinated hydrocarbons. It is insoluble in methanol, ethanol, and water. Thermal grease often consists of a silicone-grease...

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Propylene

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Related is the Methanol-to-Olefins/Methanol-to-Propene process. It converts synthesis gas (syngas) to methanol, and then converts the methanol to ethylene...

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Methylamine

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It is the simplest primary amine. Methylamine is sold as a solution in methanol, ethanol, tetrahydrofuran, or water, or as the anhydrous gas in pressurized...

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Potassium cyanide

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Solubility in water 71.6 g/100 ml (25 °C) 100 g/100 ml (100 °C) Solubility in methanol 4.91 g/100 ml (20 °C) Solubility in glycerol soluble Solubility in formamide...

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List of interstellar and circumstellar molecules

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(9 May 2016). "The ALMA-PILS survey: First detections of deuterated formamide and deuterated isocyanic acid in the interstellar medium". Astronomy & Astrophysics...

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Methanethiol

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carbon atom, like methanol. It is a weak acid, with a pKa of ~10.4, but is about a hundred thousand times more acidic than methanol. The colorless salt...

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Decaborane

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Yagyu, J.; Arai, T.; Asakura, N.; Itami, K. "Boronization effects using deuterated-decaborane (B10D14) in JT-60U". 15th PSI Gifu, P1-05. Sokendai, Japan:...

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