Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Cumene (isopropylbenzene) is an organic compound that contains a benzene ring with an isopropyl substituent. It is a constituent of crude oil and refined fuels. It is a flammable colorless liquid that has a boiling point of 152 °C. Nearly all the cumene that is produced as a pure compound on an industrial scale is converted to cumene hydroperoxide, which is an intermediate in the synthesis of other industrially important chemicals, primarily phenol and acetone (known as the cumene process).
^Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. pp. 139, 597. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4.
^Physical and Thermodynamic Properties of Pure Chemicals Data Compilation. Washington, D.C.: Taylor and Francis. 1989.
^ abcNIOSH Pocket Guide to Chemical Hazards. "#0159". National Institute for Occupational Safety and Health (NIOSH).
^ abc"Cumene". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
Cumene (isopropylbenzene) is an organic compound that contains a benzene ring with an isopropyl substituent. It is a constituent of crude oil and refined...
The cumene process (cumene-phenol process, Hock process) is an industrial process for synthesizing phenol and acetone from benzene and propylene. The term...
Cumene hydroperoxide is the organic compound with the formula C6H5C(CH3)2OOH. An oily liquid, it is classified as an organic hydroperoxide. Products of...
for its production, but the cumene process is the dominant technology. Accounting for 95% of production (2003) is the cumene process, also called Hock process...
styrene as a monomer cumene – isopropylbenzene; a feedstock in the cumene process phenol – hydroxybenzene; often made by the cumene process acetone – dimethyl...
reactive intermediates. It is also used more widely for chemicals such as cumene which are traded within the chemical industry but are not generally of value...
in major commercial processes. In the cumene process, acetone and phenol are produced by decomposition of cumene hydroperoxide (Me = methyl): C6H5CMe2(O2H)...
useful resins and fragrances. Acetophenone is formed as a byproduct of the cumene process, the industrial route for the synthesis of phenol and acetone. In...
manufacture of chemicals with more complex structures, such as ethylbenzene and cumene, of which billions of kilograms are produced annually. Although benzene...
dehydrated to give styrene, a useful monomer. Cumene hydroperoxide derived from oxygenation of cumene (isopropylbenzene), which affords cumyl alcohol...
above methods, as acetone is itself normally prepared from propene via the cumene process. IPA cost is primarily driven by raw material (acetone or propylene)...
reddish brown liquid that is a mixture of hydrocarbons (toluene, xylene, and cumene, etc.), could also be intended in some contexts. In older usage,[when?]...
acetone is produced via the cumene process; as a result, acetone production is tied to phenol production. In the cumene process, benzene is alkylated...
production of important chemicals such as propylene oxide, acrylonitrile, cumene, butyraldehyde, and acrylic acid. In the year 2013 about 85 million tonnes...
It is synthesized as a by-product in the autoxidation of cumene, which mainly affords cumene hydroperoxide. Alternatively, it can be produced by the addition...
starting material for the synthesis of acetone before the development of the cumene process: Ca(CH3COO)2 → CaCO3(s) + (CH3)2CO A saturated solution of calcium...
as a solution in (aromatic) solvents, commonly toluene but also xylene, cumene, or mesitylene, Used in large excess, it activates precatalysts for alkene...
industrially in two main ways. The most widely used route is similar to the cumene process in reaction mechanism and involves the dialkylation of benzene with...
analogous to the cumene process begins with cyclohexylbenzene, which is oxidized to a hydroperoxide, akin to the production of cumene hydroperoxide. Via...
estimated to be 1.42 ug/Kg bw/day. Calcium xylene sulfonate and sodium cumene sulfonate have been shown to cause temporary, slight eye irritation in animals...
fundamental benzene-based feedstocks such as ethylbenzene (precursor to styrene), cumene (precursor to phenol and acetone), linear alkylbenzene sulfonates (for detergents)...
organic synthesis. It is chiral. Together with tert-butyl hydroperoxide and cumene hydroperoxide, ethylbenzene hydroperoxide is important commercially. The...
aerobic oxidation of cyclohexane. Acetone is prepared by air-oxidation of cumene. For specialized or small scale organic synthetic applications, ketones...