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Core electron information


Core electrons are the electrons in an atom that are not valence electrons and do not participate in chemical bonding.[1] The nucleus and the core electrons of an atom form the atomic core. Core electrons are tightly bound to the nucleus. Therefore, unlike valence electrons, core electrons play a secondary role in chemical bonding and reactions by screening the positive charge of the atomic nucleus from the valence electrons.[2]

The number of valence electrons of an element can be determined by the periodic table group of the element (see valence electron):

  • For main-group elements, the number of valence electrons ranges from 1 to 8 (ns and np orbitals).
  • For transition metals, the number of valence electrons ranges from 3 to 12 (ns and (n−1)d orbitals).
  • For lanthanides and actinides, the number of valence electrons ranges from 3 to 16 (ns, (n−2)f and (n−1)d orbitals).

All other non-valence electrons for an atom of that element are considered core electrons.

  1. ^ Rassolov, Vitaly A.; Pople, John A.; Redfern, Paul C.; Curtiss, Larry A. (2001-12-28). "The definition of core electrons". Chemical Physics Letters. 350 (5–6): 573–576. Bibcode:2001CPL...350..573R. doi:10.1016/S0009-2614(01)01345-8.
  2. ^ Miessler, G. L. (1999). Inorganic Chemistry. Prentice Hall.

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valence electrons and form a negative ion, or else to share valence electrons and form a covalent bond. Similar to a core electron, a valence electron has...

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has 2 electrons, and so on. The configuration is often abbreviated by writing only the valence electrons explicitly, while the core electrons are replaced...

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a core state electron can be removed leaving behind a hole. As this is an unstable state, the core hole can be filled by an outer shell electron, whereby...

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periods and electron wavefunctions that approximate, under some conditions, classical orbits of electrons about the nuclei. The core electrons shield the...

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describing the location and wave-like behavior of an electron in an atom. This function describes the electron's charge distribution around the atom's nucleus...

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systems with negative electron affinity and the emission from excited states, or a few hundred keV photons for core electrons in elements with a high...

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collecting the emitted secondary electrons generated in the electron cascade that follows the creation of the primary core hole in the absorption process...

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modern 18-column periodic table, the d electrons of zinc, cadmium, and (almost always) mercury behave as core electrons and do not take part in bonding. This...

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to replace the atomic all-electron potential (full-potential) such that core states are eliminated and the valence electrons are described by pseudo-wavefunctions...

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electron microscope (SEM) is a type of electron microscope that produces images of a sample by scanning the surface with a focused beam of electrons....

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sign due to all the core electrons of the atoms. Stronger forms of magnetism usually require localized rather than itinerant electrons. However, in some...

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