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Chalcopyrite information


Chalcopyrite
General
CategorySulfide mineral
Formula
(repeating unit)
CuFeS2
IMA symbolCcp[1]
Strunz classification2.CB.10a
Crystal systemTetragonal
Crystal classScalenohedral (42m)
H-M symbol: (4 2m)
Space groupI42d
Unit cella = 5.289 Å,
c = 10.423 Å; Z = 4
Identification
Formula mass183.54 g/mol
ColorBrass yellow, may have iridescent purplish tarnish.
Crystal habitPredominantly the disphenoid and resembles a tetrahedron, commonly massive, and sometimes botryoidal.
TwinningPenetration twins
CleavageIndistinct on {011}
FractureIrregular to uneven
TenacityBrittle
Mohs scale hardness3.5–4
LusterMetallic
StreakGreenish black
DiaphaneityOpaque
Specific gravity4.1–4.3
Optical propertiesOpaque
SolubilitySoluble in HNO3
Other characteristicsmagnetic on heating
References[2][3][4][5][6]

Chalcopyrite (/ˌkælkəˈpˌrt, -k-/[7][8] KAL-kə-PY-ryte, -⁠koh-) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black.[9]

On exposure to air, chalcopyrite tarnishes to a variety of oxides, hydroxides, and sulfates. Associated copper minerals include the sulfides bornite (Cu5FeS4), chalcocite (Cu2S), covellite (CuS), digenite (Cu9S5); carbonates such as malachite and azurite, and rarely oxides such as cuprite (Cu2O). It is rarely found in association with native copper. Chalcopyrite is a conductor of electricity.[10]

Copper can be extracted from chalcopyrite ore using various methods. The two predominant methods are pyrometallurgy and hydrometallurgy, the former being the most commercially viable.[11]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Klein, Cornelis and Cornelius S. Hurlbut, Jr., Manual of Mineralogy, Wiley, 20th ed., 1985, pp. 277 – 278 ISBN 0-471-80580-7
  3. ^ Palache, C., H. Berman, and C. Frondel (1944) Dana’s system of mineralogy, (7th edition), v. I, 219–224
  4. ^ "Chalcopyrite". Mindat.org.
  5. ^ Chalcopyrite data on Webmineral.com
  6. ^ Chalcopyrite in the Handbook of Mineralogy
  7. ^ "chalcopyrite". Lexico UK English Dictionary. Oxford University Press. Archived from the original on 2020-03-22.
  8. ^ "chalcopyrite". Merriam-Webster.com Dictionary. Retrieved 2016-01-21.
  9. ^ Haldar, S. K. (2020-01-01), Haldar, S. K. (ed.), "Chapter 1 - Minerals and rocks", Introduction to Mineralogy and Petrology (Second Edition), Oxford: Elsevier, pp. 1–51, doi:10.1016/b978-0-12-820585-3.00001-6, ISBN 978-0-12-820585-3, S2CID 226592959, retrieved 2023-02-10
  10. ^ Havlík, Tomáš (2008-01-01), Havlík, Tomáš (ed.), "Chapter 10 - Effect of The Electronic Structure on leaching of Sulphide Semiconductors", Hydrometallurgy, Woodhead Publishing Series in Metals and Surface Engineering, Woodhead Publishing, pp. 294–308, doi:10.1533/9781845694616.294, ISBN 978-1-84569-407-4, retrieved 2023-02-10
  11. ^ Cite error: The named reference Daehn-2022 was invoked but never defined (see the help page).

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Chalcopyrite

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Chalcopyrite (/ˌkælkəˈpaɪˌraɪt, -koʊ-/ KAL-kə-PY-ryte, -⁠koh-) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical...

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Bornite

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widely in porphyry copper deposits along with the more common chalcopyrite. Chalcopyrite and bornite are both typically replaced by chalcocite and covellite...

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Pentlandite

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and light brownish bronze streak. In contrast, pyrite, pyrrhotite and chalcopyrite will all display much darker streaks: brownish black, greyish black,...

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Orichalcum

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In later years "orichalcum" was used to describe the sulfide mineral chalcopyrite and also to describe brass. These usages are difficult to reconcile with...

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List of copper ores

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Image Name Formula % Copper when pure Chalcopyrite CuFeS2 34.5 Chalcocite Cu2S 79.8 Covellite CuS 66.5 Bornite 2Cu2S·CuS·FeS 63.3 Tetrahedrite Cu3SbS3...

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Biomining

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"A Moderately Thermophilic Mixed Microbial Culture for Bioleaching of Chalcopyrite Concentrate at High Pulp Density". Applied and Environmental Microbiology...

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Creighton Mine

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Creighton Mine. Common ore minerals found at the Creighton mine include chalcopyrite, cubanite, galena, ilmenite, magnetite, pentlandite, pyrite, and pyrrhotite...

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Phosphophyllite

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Bavaria, Germany. It is often found in association with the minerals chalcopyrite and triphylite. Phosphophyllite has been synthesized synthetically by...

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Iron oxide copper gold ore deposits

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identified. Ore minerals in IOCG deposits are typically copper-iron sulfide chalcopyrite and gangue pyrite, forming 10–15% of the rock mass. Supergene profiles...

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Crystal

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industrially-produced single crystal. A specimen consisting of a bornite-coated chalcopyrite crystal nestled in a bed of clear quartz crystals and lustrous pyrite...

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List of minerals

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zeolites) Chaidamuite Chalcanthite Chalcocite Chalconatronite Chalcophyllite Chalcopyrite Challacolloite Chambersite Chamosite Changbaiite Chaoite Chapmanite Charlesite...

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Covellite

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of copper sulfide deposits. Commonly found as coatings on chalcocite, chalcopyrite, bornite, enargite, pyrite, and other sulfides, it often occurs as pseudomorphic...

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Sudbury Basin

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platinum group and other metals. This magma formed into pyrrhotite, chalcopyrite and pentlandite rocks, as well as cubanite and magnetite. In 1856 while...

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Layered intrusion

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magmatic sulfide assemblage is composed of Pyrrhotite, Pentlandite, and Chalcopyrite, with lesser to trace amounts of Pyrite, Cubanite and magnetite. The...

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Sphalerite

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volcanogenic massive sulfide deposits. It is found in association with galena, chalcopyrite, pyrite (and other sulfides), calcite, dolomite, quartz, rhodochrosite...

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Ural Mountains

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economically valuable ores and minerals. Eastern regions are rich in chalcopyrite, nickel oxide, gold, platinum, chromite and magnetite ores, as well as...

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Pyrite

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metal and diatomic anions differ from that of pyrite. Despite its name, chalcopyrite (CuFeS 2) does not contain dianion pairs, but single S2− sulfide anions...

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Pyrrhotite

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associated and mined with other sulfide minerals like pentlandite, pyrite, chalcopyrite, and magnetite, and has been found globally. Pyrrhotite exists as a number...

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Ore

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high conductivity, corrosion resistance Sulphide minerals, including chalcopyrite (CuFeS2; primary ore mineral) in sulphide deposits, or porphyry copper...

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Hispaniola

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thick oxide cap. Below that cap is a supergene zone containing pyrite, chalcopyrite, and sphalerite. Below the supergene zone is found the unaltered massive...

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Extractive metallurgy

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investigation. Metal sulfides (e.g., pyrite FeS2, arsenopyrite FeAsS, chalcopyrite CuFeS2) are normally processed by chemical oxidation either in aqueous...

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Yellow copper

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colloquial name for various minerals and alloys with high copper content: Chalcopyrite Brass This disambiguation page lists articles associated with the title...

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Stillwater igneous complex

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sulfides include pyrrhotite, pentlandite (containing up to 5% Pd), and chalcopyrite along with lesser amounts of moncheite ((Pt,Pd)(Te,Bi)2), cooperite ((Pt...

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Galena

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found in hydrothermal veins in association with sphalerite, marcasite, chalcopyrite, cerussite, anglesite, dolomite, calcite, quartz, barite, and fluorite...

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Sedimentary exhalative deposits

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ore minerals in SEDEX deposits are fine-grained sphalerite and galena, chalcopyrite is significant in some deposits; silver-bearing sulfosalts are frequent...

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Copper indium gallium selenide

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gallium selenide). CIGS is a tetrahedrally bonded semiconductor, with the chalcopyrite crystal structure, and a bandgap varying continuously with x from about...

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Crystal detector

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cup (on right), while the chalcopyrite crystal was mounted in a cup on an adjustable arm facing it (on left). The chalcopyrite crystal was moved forward...

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Glossary of chemical formulae

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7789-19-7 CuF2 copper(II) fluoride 11113-59-0 CuFeS2 copper iron sulfide chalcopyrite 12015-76-8 CuFe2O4 copper(II) iron(II) oxide 37220-43-2 CuFe2S3 copper...

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