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Cellulose information


Cellulose[1]
Cellulose, a linear polymer of D-glucose units (two are shown) linked by β(1→4)-glycosidic bonds
Three-dimensional structure of cellulose
Identifiers
CAS Number
  • 9004-34-6 checkY
ChEMBL
  • ChEMBL2109009 ☒N
ChemSpider
  • None
ECHA InfoCard 100.029.692 Edit this at Wikidata
EC Number
  • 232-674-9
E number E460 (thickeners, ...)
KEGG
  • C00760
PubChem CID
  • 14055602
UNII
  • SMD1X3XO9M checkY
CompTox Dashboard (EPA)
  • DTXSID3050492 Edit this at Wikidata
Properties
Chemical formula
(C
12
H
20
O
10
)
n
Molar mass 162.1406 g/mol per glucose unit
Appearance white powder
Density 1.5 g/cm3
Melting point 260–270 °C; 500–518 °F; 533–543 K Decomposes[2]
Solubility in water
none
Thermochemistry
Std enthalpy of
formation fH298)
−963,000 kJ/mol[clarification needed]
Std enthalpy of
combustion cH298)
−2828,000 kJ/mol[clarification needed]
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
1
0
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp)[2]
REL (Recommended)
TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp)[2]
IDLH (Immediate danger)
N.D.[2]
Related compounds
Related compounds
Starch
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Cellulose is an organic compound with the formula (C
6
H
10
O
5
)
n
, a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units.[3][4] Cellulose is an important structural component of the primary cell wall of green plants, many forms of algae and the oomycetes. Some species of bacteria secrete it to form biofilms.[5] Cellulose is the most abundant organic polymer on Earth.[6] The cellulose content of cotton fiber is 90%, that of wood is 40–50%, and that of dried hemp is approximately 57%.[7][8][9]

Cellulose is mainly used to produce paperboard and paper. Smaller quantities are converted into a wide variety of derivative products such as cellophane and rayon. Conversion of cellulose from energy crops into biofuels such as cellulosic ethanol is under development as a renewable fuel source. Cellulose for industrial use is mainly obtained from wood pulp and cotton.[6] Cellulose is also greatly affected by direct interaction with several organic liquids.[10]

Some animals, particularly ruminants and termites, can digest cellulose with the help of symbiotic micro-organisms that live in their guts, such as Trichonympha. In human nutrition, cellulose is a non-digestible constituent of insoluble dietary fiber, acting as a hydrophilic bulking agent for feces and potentially aiding in defecation.

  1. ^ Nishiyama Y, Langan P, Chanzy H (2002). "Crystal Structure and Hydrogen-Bonding System in Cellulose Iβ from Synchrotron X-ray and Neutron Fiber Diffraction". J. Am. Chem. Soc. 124 (31): 9074–9082. doi:10.1021/ja0257319. PMID 12149011.
  2. ^ a b c d NIOSH Pocket Guide to Chemical Hazards. "#0110". National Institute for Occupational Safety and Health (NIOSH).
  3. ^ Crawford, R. L. (1981). Lignin biodegradation and transformation. New York: John Wiley and Sons. ISBN 978-0-471-05743-7.
  4. ^ Updegraff D. M. (1969). "Semimicro determination of cellulose in biological materials". Analytical Biochemistry. 32 (3): 420–424. doi:10.1016/S0003-2697(69)80009-6. PMID 5361396.
  5. ^ Romeo T (2008). Bacterial biofilms. Berlin: Springer. pp. 258–263. ISBN 978-3-540-75418-3.
  6. ^ a b Klemm D, Heublein, Brigitte, Fink, Hans-Peter, Bohn, Andreas (2005). "Cellulose: Fascinating Biopolymer and Sustainable Raw Material". Angew. Chem. Int. Ed. 44 (22): 3358–3393. doi:10.1002/anie.200460587. PMID 15861454.
  7. ^ Cellulose. (2008). In Encyclopædia Britannica. Retrieved January 11, 2008, from Encyclopædia Britannica Online.
  8. ^ Chemical Composition of Wood. Archived October 13, 2018, at the Wayback Machine. ipst.gatech.edu.
  9. ^ Piotrowski, Stephan and Carus, Michael (May 2011) Multi-criteria evaluation of lignocellulosic niche crops for use in biorefinery processes Archived April 3, 2021, at the Wayback Machine. nova-Institut GmbH, Hürth, Germany.
  10. ^ Mantanis GI, Young RA, Rowell RM (1995). "Swelling of compressed cellulose fiber webs in organic liquids". Cellulose. 2 (1): 1–22. doi:10.1007/BF00812768. ISSN 0969-0239.

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Cellulose

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Cellulose is an organic compound with the formula (C 6H 10O 5) n, a polysaccharide consisting of a linear chain of several hundred to many thousands of...

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Rayon

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sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. Many types and grades...

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Cellulose acetate

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biochemistry, cellulose acetate refers to any acetate ester of cellulose, usually cellulose diacetate. It was first prepared in 1865. A bioplastic, cellulose acetate...

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Carboxymethyl cellulose

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Carboxymethyl cellulose (CMC) or cellulose gum is a cellulose derivative with carboxymethyl groups (-CH2-COOH) bound to some of the hydroxyl groups of...

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Cellulose insulation

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Cellulose insulation is plant fiber used in wall and roof cavities to insulate, draught proof and reduce noise. Building insulation in general is...

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Microcrystalline cellulose

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Microcrystalline cellulose (MCC) is a term for refined wood pulp and is used as a texturizer, an anti-caking agent, a fat substitute, an emulsifier, an...

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Methyl cellulose

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Methyl cellulose (or methylcellulose) is a compound derived from cellulose. It is sold under a variety of trade names and is used as a thickener and emulsifier...

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Hydroxyethyl cellulose

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Hydroxyethyl cellulose is a gelling and thickening agent derived from cellulose. It is widely used in cosmetics, cleaning solutions, and other household...

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Cellulose fiber

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Cellulose fibers (/ˈsɛljʊloʊs, -loʊz/) are fibers made with ethers or esters of cellulose, which can be obtained from the bark, wood or leaves of plants...

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Cell wall

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In land plants, the primary cell wall comprises polysaccharides like cellulose, hemicelluloses, and pectin. Often, other polymers such as lignin, suberin...

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Nitrocellulose

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Nitrocellulose (also known as cellulose nitrate, flash paper, flash cotton, guncotton, pyroxylin and flash string, depending on form) is a highly flammable...

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Bacterial cellulose

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Bacterial cellulose is an organic compound with the formula (C 6H 10O 5) n produced by certain types of bacteria. While cellulose is a basic structural...

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Hemicellulose

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such as arabinoxylans, present along with cellulose in almost all terrestrial plant cell walls. Cellulose is crystalline, strong, and resistant to hydrolysis...

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Diethylaminoethyl cellulose

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Diethylaminoethyl cellulose (DEAE-C) is a positively charged resin used in ion-exchange chromatography, a type of column chromatography, for the separation...

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Polysaccharide

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starch, glycogen and galactogen and structural polysaccharides such as cellulose and chitin. Polysaccharides are often quite heterogeneous, containing...

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Cellulosic ethanol

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Cellulosic ethanol is ethanol (ethyl alcohol) produced from cellulose (the stringy fiber of a plant) rather than from the plant's seeds or fruit. It can...

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Hypromellose

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methyl cellulose) Trade names include Methocel and Walocel. The global leading producer is now DuPont, formerly manufactured under Dow Wolff Cellulosics GmbH...

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Ethyl cellulose

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Ethyl cellulose (or ethylcellulose) is a derivative of cellulose in which some of the hydroxyl groups on the repeating glucose units are converted into...

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Lyocell

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textiles for clothing and other purposes. It is a form of regenerated cellulose made by dissolving pulp and dry jet-wet spinning. Unlike rayon made by...

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Cellulose acetate butyrate

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Cellulose acetate butyrate (CAB) is a mixed ester thermoplastic derivative of cellulose acetate that contains both acetate and butyrate functional groups...

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Fiber

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their origin: Vegetable fibers are generally based on arrangements of cellulose, often with lignin: examples include cotton, hemp, jute, flax, abaca,...

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Hydroxypropyl cellulose

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Hydroxypropyl cellulose (HPC) is a derivative of cellulose with both water solubility and organic solubility. It is used as an excipient, and topical ophthalmic...

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Lacquer thinner

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Lacquer thinner, also known as cellulose thinner, is usually a mixture of solvents able to dissolve a number of different resins or plastics used in modern...

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Nanocellulose

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nano-structured cellulose. This may be either cellulose nanocrystal (CNC or NCC), cellulose nanofibers (CNF) also called nanofibrillated cellulose (NFC), or...

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Cellulose electrode

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A cellulose electrode is a welding electrode that has a coating containing organic materials. About 30% of the coating weight is cellulose. In some countries...

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Dissolving pulp

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Dissolving pulp, also called dissolving cellulose, is bleached wood pulp or cotton linters that has a high cellulose content (> 90%). It has special properties...

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Cellulose triacetate

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Cellulose triacetate, triacetate, CTA or TAC is a chemical compound produced from cellulose and a source of acetate esters, typically acetic anhydride...

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Oxidized cellulose

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Oxidized cellulose is a water-insoluble derivative of cellulose. It can be produced from cellulose by the action of an oxidizing agent, such as chlorine...

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