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Boron arsenide information


Boron arsenide
Identifiers
CAS Number
  • 12005-69-5 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 8461243
PubChem CID
  • 10285774
InChI
  • InChI=1S/AsB/c1-2
    Key: DBKNIEBLJMAJHX-UHFFFAOYSA-N
SMILES
  • [B][As]
Properties
Chemical formula
BAs
Molar mass 85.733 g/mol[1]
Appearance Brown cubic crystals[1]
Density 5.22 g/cm3[1]
Melting point 1,100 °C (2,010 °F; 1,370 K) decomposes[1]
Solubility in water
Insoluble
Band gap 1.82 eV
Thermal conductivity 1300 W/(m·K) (300 K)
Structure[2]
Crystal structure
Cubic (sphalerite), cF8, No. 216
Space group
F43m
Lattice constant
a = 0.4777 nm
Formula units (Z)
4
Related compounds
Other anions
Boron nitride
Boron phosphide
Boron antimonide
Other cations
Aluminium arsenide
Gallium arsenide
Indium arsenide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Boron subarsenide
Identifiers
CAS Number
  • 12005-70-8 checkY
Properties
Chemical formula
B12As2
Molar mass 279.58 g/mol
Density 3.56 g/cm3[3]
Solubility in water
Insoluble
Band gap 3.47 eV
Structure[4]
Crystal structure
Rhombohedral, hR42, No. 166
Space group
R3m
Lattice constant
a = 0.6149 nm, b = 0.6149 nm, c = 1.1914 nm
α = 90°, β = 90°, γ = 120°
Formula units (Z)
6
Related compounds
Other anions
Boron suboxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Boron arsenide (or Arsenic boride) is a chemical compound involving boron and arsenic, usually with a chemical formula BAs. Other boron arsenide compounds are known, such as the subarsenide B12As2. Chemical synthesis of cubic BAs is very challenging and its single crystal forms usually have defects.

  1. ^ a b c d Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.53. ISBN 1-4398-5511-0.
  2. ^ Perri, J. A; La Placa, S; Post, B (1958). "New group III-group V compounds: BP and BAs". Acta Crystallographica. 11 (4): 310. doi:10.1107/S0365110X58000827.
  3. ^ Villars, Pierre (ed.) "B12As2 (B6As) Crystal Structure" in Inorganic Solid Phases, Springer, Heidelberg (ed.) SpringerMaterials
  4. ^ Morosin, B; Aselage, T. L; Feigelson, R. S (2011). "Crystal Structure Refinements of Rhombohedral Symmetry Materials Containing Boron-Rich Icosahedra". MRS Proceedings. 97. doi:10.1557/PROC-97-145.

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Boron arsenide

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Boron arsenide (or Arsenic boride) is a chemical compound involving boron and arsenic, usually with a chemical formula BAs. Other boron arsenide compounds...

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Gallium arsenide

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Gallium arsenide (GaAs) is a III-V direct band gap semiconductor with a zinc blende crystal structure. Gallium arsenide is used in the manufacture of...

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Boron nitride

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Boron nitride is a thermally and chemically resistant refractory compound of boron and nitrogen with the chemical formula BN. It exists in various crystalline...

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Boron pnictide

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Boron pnictide can refer to any of the following materials: Normal boron pnictides: Boron nitride, BN Boron phosphide, BP Boron arsenide, BAs Boron subpnictides:...

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Aluminium arsenide

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Aluminium arsenide (AlAs) is a semiconductor material with almost the same lattice constant as gallium arsenide and aluminium gallium arsenide and wider...

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Electron mobility

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Ren, Zhifeng; Chen, Gang (2022). "High ambipolar mobility in cubic boron arsenide". Science. 377 (6604): 437–440. Bibcode:2022Sci...377..437S. doi:10...

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List of semiconductor materials

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semiconductors have both advantages and disadvantages. For example, gallium arsenide (GaAs) has six times higher electron mobility than silicon, which allows...

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Boron phosphide

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K) high thermal conductivity of ~ 460 W/(m·K) at room temperature Boron arsenide Boron nitride Aluminium phosphide Gallium phosphide Madelung, O. (2004)...

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Boron group

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The boron group are the chemical elements in group 13 of the periodic table, consisting of boron (B), aluminium (Al), gallium (Ga), indium (In), thallium...

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Boron trioxide

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gallium arsenide single crystal As an acid catalyst in organic synthesis As a starting material for the production of other boron compounds, such as boron carbide...

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Cubic crystal system

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semiconductors (such as gallium arsenide and cadmium telluride), and a wide array of other binary compounds.[citation needed] The boron group pnictogenides usually...

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Bas

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to: Bas (name), a given name and a surname Bas (rapper) (born 1987) Boron arsenide (BAs), a chemical compound Barium sulfide (BaS), a chemical compound...

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List of thermal conductivities

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Yongjie (2018). "Experimental observation of high thermal conductivity in boron arsenide". Science. 361 (6402): 575–578. Bibcode:2018Sci...361..575K. doi:10...

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Phonon scattering

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temperature. The predicted significance of four-phonon scattering in boron arsenide was confirmed by experiments. Mass-difference impurity scattering is...

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Physics World

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FLASH proton therapy Perfecting light transmission and absorption Cubic boron arsenide is a champion semiconductor Detecting an Aharonov–Bohm effect for gravity...

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List of CAS numbers by chemical compound

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number BAs boron arsenide 12005–69–5 BAsO4 boron arsenate 13510–31–1 BBr3 boron tribromide 10294–33–4 BCl3 boron trichloride 10294–34–5 BF3 boron trifluoride...

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Semiconductor

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germanium, gallium arsenide, and elements near the so-called "metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most...

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Glossary of chemical formulae

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Synonyms CAS number BAs boron arsenide 12005-69-5 BBr3 boron tribromide 10294-33-4 BCl3 boron trichloride 10294-34-5 BF3 boron trifluoride 7637-07-2 BH3...

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Hexagonal crystal family

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Metalloid

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the literature of chemistry. The six commonly recognised metalloids are boron, silicon, germanium, arsenic, antimony and tellurium. Five elements are...

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List of inorganic compounds

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H3BO3 Boron carbide – B4C Boron nitride – BN Boron suboxide – B6O Boron tribromide – BBr3 Boron trichloride – BCl3 Boron trifluoride – BF3 Boron triiodide...

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Band gap

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Gallium

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0 °C (98.6 °F). Gallium is predominantly used in electronics. Gallium arsenide, the primary chemical compound of gallium in electronics, is used in microwave...

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Czochralski method

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single crystals of semiconductors (e.g. silicon, germanium and gallium arsenide), metals (e.g. palladium, platinum, silver, gold), salts and synthetic...

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