Chemical reaction which replaces a hydrogen on an arene with sulfonic acid, –NH–SO3H
See also: Desulfonation reaction
In organic chemistry, aromatic sulfonation is an organic reaction in which a hydrogen atom on an arene is replaced by a sulfonic acid (−SO2OH) functional group in an electrophilic aromatic substitution.[1] Aryl sulfonic acids are used as detergents, dye, and drugs.
^March, Jerry (1985), Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, 3rd edition, New York: Wiley, ISBN 9780471854722, OCLC 642506595.
and 28 Related for: Aromatic sulfonation information
In organic chemistry, aromaticsulfonation is an organic reaction in which a hydrogen atom on an arene is replaced by a sulfonic acid (−SO2OH) functional...
most important electrophilic aromatic substitutions are aromatic nitration, aromatic halogenation, aromaticsulfonation, alkylation Friedel–Crafts reaction...
reactions of this type that take place are aromatic nitration, aromatic halogenation, aromaticsulfonation and acylation and alkylating Friedel-Crafts...
sulfonatesin satisfactory yields with Ms2O. Examples of aromaticsulfonation with Ms2O: Sulfonation of chlorobenzene resulted in addition of methylsulfonyl...
is prepared from the sulfonation of benzene using concentrated sulfuric acid: This conversion illustrates aromaticsulfonation, which has been called...
5′-indigodisulfonic acid sodium salt, is an organic salt derived from indigo by aromaticsulfonation, which renders the compound soluble in water. It is approved for...
SO3 groups to substrates. Often the substrates are organic, as in aromaticsulfonation. For activated substrates, Lewis base adducts of sulfur trioxide...
chemistry. For example, sulfa drugs are sulfonamides derived from aromaticsulfonation. Chiral sulfinamides are used in asymmetric synthesis, while sulfenamides...
preserve an aromatic ring. For beta substitution, the intermediate has only six resonance structures, and only two of these are aromatic. Sulfonation gives...
variety of groups found in the structure of lignin. Sulfonation occurs on the side chains, not on the aromatic ring like in p-toluenesulfonic acid. Kraft lignin...
nickel Electrophilic halogenation to 9-bromophenanthrene with bromine Aromaticsulfonation to 2 and 3-phenanthrenesulfonic acids with sulfuric acid Ozonolysis...
unsaturated compounds (mostly aromatics). Significant chemical functionalization of the oil (chlorination, sulfonation, etc.) can interfere with the measurement...
amines contain only H and alkyl substituents. Aromatic amines have the nitrogen atom connected to an aromatic ring. Amines, alkyl and aryl alike, are organized...
reaction of nonanoic acid (or its esters) with phenol followed by aromaticsulfonation using SO3 to form a sulfonic acid at the para-position. NOBS was...
chloride. Using electrophilic aromatic substitution, many functional groups are introduced onto the benzene framework. Sulfonation of benzene involves the use...
yield the "decolorized" adduct with sulfonation at the central carbon as described and shown. The free, uncharged aromatic amine groups then react with the...
naphthylsulfonic acids. It is the reverse of sulfonation. The temperature of desulfonation correlates with the ease of the sulfonation. This reactivity is exploited...
called sulfonates. Aryl sulfonic acids are produced by the process of sulfonation. Usually the sulfonating agent is sulfur trioxide. A large scale application...
juiːn/), also known as toluol (/ˈtɒl.ju.ɒl, -ɔːl, -oʊl/), is a substituted aromatic hydrocarbon with the chemical formula C6H5CH3, often abbreviated as PhCH3...
with the formula C4H4S. Consisting of a planar five-membered ring, it is aromatic as indicated by its extensive substitution reactions. It is a colorless...
Pyrimidine (C4H4N2; /pɪˈrɪ.mɪˌdiːn, paɪˈrɪ.mɪˌdiːn/) is an aromatic, heterocyclic, organic compound similar to pyridine (C5H5N). One of the three diazines...
triphenylphosphine oxide. Aromatic N-oxides are reduced to the corresponding amine in high yield at room temperature with irradiation: Sulfonation of PPh3 gives...
Liu, Gao (March 2021). "Sulfonated aromatic polymer as a future proton exchange membrane: A review of sulfonation and crosslinking methods". Renewable...
Anthraquinone, also called anthracenedione or dioxoanthracene, is an aromatic organic compound with formula C 14H 8O 2. Isomers include various quinone...
Other electrophilic aromatic substitution reactions can also be promoted with trifluoroacetic anhydride, including nitration, sulfonation and nitrosylation...
Phenol (also known as carbolic acid, phenolic acid, or benzenol) is an aromatic organic compound with the molecular formula C6H5OH. It is a white crystalline...
nitroanthraquinone (3), which is obtained by sulfonation or nitration of anthraquinone (1). Synthesis of 1-aminoanthraquinone Sulfonation in α position is reversible and...