Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Acetyl bromide is an acyl bromide compound. As is expected, it may be prepared by reaction between phosphorus tribromide and acetic acid:[2]
3 CH3COOH + PBr3 → 3 CH3COBr + H3PO3
As usual for an acid halide, acetyl bromide hydrolyzes rapidly in water, forming acetic acid and hydrobromic acid. It also reacts with alcohols and amines to produce acetate esters and acetamides, respectively.
^Acetyl bromide[permanent dead link] at Sigma-Aldrich
^Theodore M. Burton and Ed. F. Degering (1940). "The Preparation of Acetyl Bromide". J. Am. Chem. Soc.62: 227. doi:10.1021/ja01858a502.
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Bromide" Inorganic Syntheses, 1947, vol. 2, 147ff. doi:10.1002/9780470132333.ch43 Burton, T. M.; Degerping, E. F. (1940). "The Preparation of Acetyl Bromide"...
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chloride. Acyl chlorides are the most commonly encountered acyl halides, but acetyl iodide is the one produced (transiently) on the largest scale. Billions...