Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Acetone hydrazone (isopropylidenehydrazine) is the product of condensation of acetone and hydrazine, as typical for hydrazone formation. It is an intermediate in the synthesis of 2-diazopropane [fr].[2]
Acetone hydrazone can be produced on large scale by reaction of acetone azine with hydrazine, a more convenient reaction than direct reaction of acetone and hydrazine.[3] Likewise, it is susceptible to disproportionation to revert to acetone azine and hydrazine, especially in the presence of water.[3]
The chemical is one of the metabolic products of the antihypertensive pharmaceutical hydralazine, and itself also have antihypertensive effects.[4]
^"Acetone hydrazone". pubchem.ncbi.nlm.nih.gov.
^Andrews, S. D.; Day, A. C.; Raymond, P.; Whiting, M. C. (1970). "2-Diazopropane". Organic Syntheses: 27; Collected Volumes, vol. 6, 1988, p. 392.
^ abDay, A. C.; Whiting, M. C. "Acetone Hydrazone". Organic Syntheses; Collected Volumes, vol. 6, p. 10.
Acetonehydrazone (isopropylidenehydrazine) is the product of condensation of acetone and hydrazine, as typical for hydrazone formation. It is an intermediate...
Collected Volumes, vol. 6, p. 242. Day, A. C.; Whiting, M. C. (1970). "Acetonehydrazone". Organic Syntheses. 50: 3; Collected Volumes, vol. 6, p. 10. Fischer...
ammonia to produce acetonehydrazone. The hydrazone then condenses with a further molecule of acetone to produce the azine. The acetone azine product is...
carbonyl is its reaction with acetone to give the acetone azine. The latter reacts further with hydrazine to yield acetonehydrazone: 2 (CH3)2CO + N2H4 → 2 H2O...
Metabolic products include the N-acetyl derivative, pyruvic acid hydrazone, and acetonehydrazone, each of which may also contribute to reducing blood pressure...
2-diazopropane [fr] from acetonehydrazone. Other oxidizing reagents are lead tetraacetate, manganese dioxide and the Swern reagent. Tosyl hydrazones RRC=N-NHTs are...
(which contains a carbon–oxygen double bond C=O). The simplest ketone is acetone (where R and R' is methyl), with the formula (CH3)2CO. Many ketones are...
16α-17α,21-tetrahydroxypregna-1,4-diene-3,20-dione cyclic 16,17-acetal with acetone, is a synthetic halogenated cyclic ketal pregnane corticosteroid. It is...
C3H8N2 (molar mass: 72.11 g/mol, exact mass: 72.0688 u) may refer to: Acetonehydrazone Imidazolidine Pyrazolidine This set index page lists chemical structure...
Benzylideneacetone can be efficiently prepared by the base-induced condensation of acetone and benzaldehyde: CH3C(O)CH3 + C6H5CHO → C6H5CH=CHC(O)CH3 + H2O However...
with a second molecule of ammonia to give the hydrazone: Me(Et)CONH + NH3 → Me(Et)C=NNH2 + H2O The hydrazone then condenses with a second equivalent of ketone...
oximes are 102- to 103-fold more resistant to hydrolysis than analogous hydrazones. Oximes can be synthesized by condensation of an aldehyde or a ketone...
Methyl ethyl ketone peroxide, benzoyl peroxide and to a smaller degree acetone peroxide are used as initiators for radical polymerization of some thermosets...
within a carbonyl compound decreases. The pKa values of acetaldehyde and acetone are 16.7 and 19 respectively, Infrared spectroscopy: the C=O double bond...
formation (ΔfH⦵298) −15 to −9 kJ mol−1 Related compounds Related compounds Acetone Carbon monoxide Acetic acid Except where otherwise noted, data are given...
treatment of potassium selenocyanate with alkyl halides in alcohol or acetone solution. Aryl selenocyanates are generally prepared by treatment of potassium...
aldehyde 4.2 and hydrazone 3.6 using a Shapiro coupling reaction. Retrosynthetic Scheme II indicates that both the aldehyde and the hydrazone used in the Shapiro...
group. Thus the simplest thioketone is thioacetone, the sulfur analog of acetone. Unhindered alkylthioketones typically tend to form polymers or rings....
can be deprotonated. For example, the acidity of the methyl groups in acetone ((CH3)2CO) is about 1020 times more acidic than methane. The resulting...
azo compounds pose the risk of explosion. AIBN is produced by converting acetone cyanohydrin to the hydrazine derivative followed by oxidation: 2 (CH3)2C(CN)OH...
These proline-derived auxiliaries and catalysts, including the Enders hydrazone reaction and Corey–Itsuno reduction, have been reviewed, as have MacMillan’s...
formed by the oxidation of diphenylamine with potassium permanganate in acetone. Hydrazines can be divided into three groups according to the degree of...
sometimes called a formal or the methylenedioxy group. The acetal formed from acetone is sometimes called an acetonide. Used in a more general sense, the term...
Global Information
