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Acetone azine information


Acetone azine[1][2]
Names
Preferred IUPAC name
1,2-Di(propan-2-ylidene)hydrazine
Systematic IUPAC name
Acetone azine
Other names
    • Ketazine
    • Acetone ketazine
    • Dimethyl ketazine
    • 2-Propanone, 2-(1-methylethylidene)hydrazone
    • Acetone isopropylidenehydrazone
    • Dipropan-2-ylidenehydrazine
    • Diisopropylidene hydrazine
    • N-(propan-2-ylideneamino)propan-2-imine
Identifiers
CAS Number
  • 627-70-3 checkY
3D model (JSmol)
  • Interactive image
Beilstein Reference
 4-01-00-03207
ChemSpider
  • 71417 checkY
ECHA InfoCard 100.010.009 Edit this at Wikidata
EC Number
  • 211-009-6
PubChem CID
  • 79085
UNII
  • Q18Y7G3ZPB checkY
CompTox Dashboard (EPA)
  • DTXSID1060845 Edit this at Wikidata
InChI
  • InChI=1S/C6H12N2/c1-5(2)7-8-6(3)4/h1-4H3 checkY
    Key: PFLUPZGCTVGDLV-UHFFFAOYSA-N checkY
SMILES
  • N(\N=C(/C)C)=C(\C)C
Properties
Chemical formula
 C6H12N2
Molar mass 112.176 g·mol−1
Appearance Pale-yellow liquid
Density 0.842 g cm−3
Melting point −125 °C (−193 °F; 148 K)
Boiling point 133 °C (271 °F; 406 K)
Refractive index (nD)
 1.454
Hazards
GHS labelling:
Pictograms
 GHS02: Flammable GHS08: Health hazard GHS06: Toxic
Signal word
 Danger
Hazard statements
 H226, H302, H311, H315, H319, H335, H350
Precautionary statements
 P201, P261, P280, P305+P351+P338, P308+P313
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 2: Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Flash point between 38 and 93 °C (100 and 200 °F). E.g. diesel fuelInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
3
2
0
Flash point 31 °C (88 °F; 304 K)
Related compounds
Related compounds
 Hydrazine

Acetone

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Acetone azine is the simplest ketazine. It is an intermediate in some hydrazine manufacturing processes.

  1. ^ "Acetone azine MSDS (Santa Cruz Biotechnology)" (PDF).
  2. ^ "Acetone azine MSDS (Sigma Aldrich)".

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Acetone azine

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Acetone azine is the simplest ketazine. It is an intermediate in some hydrazine manufacturing processes. Acetone azine can be prepared from acetone and...

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alternative routes. Ketazines are azines derived from ketones. For example, acetone azine is the simplest ketazine. Aldazines are azines derived from aldehydes....

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the synthesis of 2-diazopropane [fr]. Acetone hydrazone can be produced on large scale by reaction of acetone azine with hydrazine, a more convenient reaction...

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itself, hydrazones condense with a second equivalent of a carbonyl to give azines: R2C=N−NH2 + R2C=O → R2C=N−N=CR2 + H2O Hydrazones are intermediates in the...

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prepared by reducing nitro compounds under basic conditions or by reducing the azines. Tri- or tetrasubstituted aliphatic hydrazines are water-insoluble weakly...

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Non-17α-alkylated derivatives Marketed Bolazine (an azine dimer prodrug of drostanolone) Drostanolone (2α-methyl-DHT) Epitiostanol (2α,3α-epithio-DHT)...

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