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Valence and conduction bands information


Filling of the electronic states in various types of materials at equilibrium. Here, height is energy while width is the density of available states for a certain energy in the material listed. The shade follows the Fermi–Dirac distribution (black: all states filled, white: no state filled). In metals and semimetals the Fermi level EF lies inside at least one band.
In insulators and semiconductors the Fermi level is inside a band gap; however, in semiconductors the bands are near enough to the Fermi level to be thermally populated with electrons or holes. "intrin." indicates intrinsic semiconductors.

In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in which electrons are normally present at absolute zero temperature, while the conduction band is the lowest range of vacant electronic states. On a graph of the electronic band structure of a semiconducting material, the valence band is located below the Fermi level, while the conduction band is located above it.

The distinction between the valence and conduction bands is meaningless in metals, because conduction occurs in one or more partially filled bands that take on the properties of both the valence and conduction bands.

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Valence and conduction bands

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In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of...

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Band gap

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the conduction band in insulators and semiconductors. It is the energy required to promote an electron from the valence band to the conduction band. The...

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Direct and indirect band gaps

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gap". The band gap is called "direct" if the crystal momentum of electrons and holes is the same in both the conduction band and the valence band; an electron...

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Free electron

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electric charge Valence electron, as an outer shell electron that is associated with an atom Valence and conduction bands, as a conduction band electron relative...

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Intermediate band photovoltaics

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of a cell. It introduces an intermediate band (IB) energy level in between the valence and conduction bands. Theoretically, introducing an IB allows two...

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Periodic table

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lutetium is primary, sharing both valence electron count and valence orbital type. As chemical reactions involve the valence electrons, elements with similar...

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Optically stimulated luminescence

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Electrons are in the conduction band and holes in the valence band. The electrons that have been excited to the conduction band may become entrapped in...

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Quasi Fermi level

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each band, the conduction band and valence band can each have an individual population that is internally in equilibrium, even though the bands are not...

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Solar cell

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of a cell. It introduces an intermediate band (IB) energy level in between the valence and conduction bands. Theoretically, introducing an IB allows two...

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Fine electronic structure

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interactions between charge carriers. Valence and conduction bands split slightly compared to the difference between the various bands. Some mechanisms that allow...

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Carrier generation and recombination

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forbidden band or band gap between two allowed bands called the valence band and the conduction band. The valence band, immediately below the forbidden band, is...

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Antibonding molecular orbital

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Bonding molecular orbital Valence and conduction bands Valence bond theory Molecular orbital theory Conjugated system Atkins P. and de Paula J. Atkins Physical...

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Electronic properties of graphene

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Graphene is a semimetal whose conduction and valence bands meet at the Dirac points, which are six locations in momentum space, the vertices of its hexagonal...

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Valence electron

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contributing one valence electron. The presence of valence electrons can determine the element's chemical properties, such as its valence—whether it may...

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Flat band potential

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of the semiconductor and therefore preventing any band bending of the conduction and valence band. An application of the flat band potential can be found...

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Topological insulator

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exists an energy gap between the valence and conduction bands of the material. But in a topological insulator, these bands are, in an informal sense, "twisted"...

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Graphene

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nanotubes and polycyclic aromatic hydrocarbons, and (partially) in fullerenes and glassy carbon. The valence band is touched by a conduction band, making...

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Electric current

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in the conduction band, the band immediately above the valence band. The ease of exciting electrons in the semiconductor from the valence band to the...

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Free electron model

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narrow conduction bands also exist. This diversity is not predicted by the model and can only by explained by analysing the valence and conduction bands. Additionally...

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Electron hole

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effective mass), so a conduction-band electron responds to forces as if it had the mass m*. Electrons near the top of the valence band behave as if they have...

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Surface properties of transition metal oxides

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equations are useful in describing the populations of valence and conduction bands in terms of holes and electrons for the bulk metal. n {\displaystyle n}...

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OLED

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(HOMO and LUMO) of organic semiconductors are analogous to the valence and conduction bands of inorganic semiconductors. Originally, the most basic polymer...

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Semimetal

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small overlap between the bottom of the conduction band and the top of the valence band. According to electronic band theory, solids can be classified as...

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Dirac cone

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materials, at energies near the Fermi level, the valence band and conduction band take the shape of the upper and lower halves of a conical surface, meeting...

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Band diagram

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semiconductor. The conduction band edge may also be indicated in an insulator, simply to demonstrate band bending effects. EV: The valence band edge likewise...

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Density of states

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of electrons at the band edge between the valence and conduction bands in a semiconductor, for an electron in the conduction band, an increase of the...

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Extrinsic semiconductor

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greater than that of the intrinsic semiconductor and lies closer to the conduction band than the valence band. Examples: phosphorus, arsenic, antimony, etc...

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