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Dichlororuthenium tricarbonyl dimer information


Dichlororuthenium tricarbonyl dimer
Names
Other names
hexacarbonyldi-μ-chlorodichlorodiruthenium
Identifiers
CAS Number
  • 22594-69-0 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 21171219
ECHA InfoCard 100.159.029 Edit this at Wikidata
PubChem CID
  • 10951331
CompTox Dashboard (EPA)
  • DTXSID60449451 Edit this at Wikidata
InChI
  • InChI=1S/6CO.4ClH.2Ru/c6*1-2;;;;;;/h;;;;;;4*1H;;/q;;;;;;;;;;2*+2/p-4
    Key: JYHHJVKGDCZCCL-UHFFFAOYSA-J
SMILES
  • O#C[Ru+2]1([Cl-])(C#O)(C#O)[Cl-][Ru+2]([Cl-])(C#O)(C#O)(C#O)[Cl-]1
Properties
Chemical formula
C6Cl4O6Ru2
Molar mass 512.00 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Dichlororuthenium tricarbonyl dimer is an organoruthenium compound with the formula [RuCl2(CO)3]2. A yellow solid, the molecule features a pair of octahedral Ru centers bridged by a pair of chloride ligands. The complex is a common starting material in ruthenium chemistry.[1]

  1. ^ Haukka, Matti; Kiviaho, Jari; Ahlgren, Markku; Pakkanen, Tapani A. (1995). "Studies on Catalytically Active Ruthenium Carbonyl Bipyridine Systems. Synthesis and Structural Characterization of [Ru(bpy)(CO)2Cl2], [Ru(bpy)(CO)2Cl(C(O)OCH3)], [Ru(bpy)(CO)2Cl]2, and [Ru(bpy)(CO)2ClH] (Bpy = 2,2'-Bipyridine)". Organometallics. 14 (2): 825–833. doi:10.1021/om00002a033.

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