Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Trimethylphosphine is an organophosphorus compound with the formula P(CH3)3, commonly abbreviated as PMe3. This colorless liquid has a strongly unpleasant odor, characteristic of alkylphosphines. The compound is a common ligand in coordination chemistry.
^ ab"Trimethylphosphine (CHEBI:35890)". Chemical Entities of Biological Interest (ChEBI). UK: European Bioinformatics Institute. 6 June 2006. IUPAC Names. Retrieved 25 September 2011.
and 25 Related for: Trimethylphosphine information
Trimethylphosphine is an organophosphorus compound with the formula P(CH3)3, commonly abbreviated as PMe3. This colorless liquid has a strongly unpleasant...
3 HOC6H5 → P(OC6H5)3 + 3 HCl Triphenylphosphite is a precursor to trimethylphosphine, it serves as a source of P3+ that is less electrophilic than phosphorus...
synthesis of organic compounds containing phosphorus, which he named "trimethylphosphine" and "triethylphosphine", in analogy with "amine" (organo-nitrogen...
tetramethylphosphonium and the bromide anion. It is prepared by treating trimethylphosphine with methyl bromide. Deprotonation gives methylenetrimethylphosphine...
triethylphosphine gained acceptance earlier than did the simpler trimethylphosphine, as illustrated by the preparation of the hydride complex trans-PtHCl(PEt3)2...
Pyridine N 128 Acetonitrile N 60 DMA O 112 DMSO O 105 THF O 90.4 Et2O O 78.8 Acetone O 76.0 EtOAc O 75.5 Trimethylphosphine P 97.3 Tetrahydrothiophene S 51.6...
organolithium compounds: 3 RMgX + PCl3 → PR3 + 3 MgX2 In the case of trimethylphosphine, triphenyl phosphite is used in place of the highly electrophilic...
(SDS) Fisher Scientific Related compounds Related tertiary phosphines Trimethylphosphine Phosphine Related compounds Triphenylamine Triphenylarsine Triphenylstibine...
in low oxidation states. It is cheaper and less air-sensitive than trimethylphosphine and other trialkylphosphines. Although its complexes are generally...
acids, with concomitant opening of the cluster. An example involving trimethylphosphine: B5H9 + 2 P(CH3)3 → B5H9·2P(CH3)3 Some higher boranes, especially...
2]pentane 39 °C Ruthenium(VIII) oxide 40 °C Nickel carbonyl 42.1 °C Trimethylphosphine 43 °C Gallane liquid decomposes at 0 °C. Nitroxyl and diazene are...
dichlorotrimethyltantalum has also been reported with trimethylphosphine by Sattler. Trimethylphosphine was introduced by vapour transfer to dichlorotrimethyltantalum...
produced by anaerobic bacteria in antimony-rich soils. In contrast to trimethylphosphine, trimethylstibine is a weaker Lewis base. It is used in the production...
converted into aziridines with the use of trialkyl phosphines such as trimethylphosphine or tributylphosphine. Aziridines are reactive substrates in ring-opening...
preparation of zirconocene complex by reaction diphenylzirconocene with trimethylphosphine. Cp2ZrPh2 + PMe3 → Cp2Zr(C6H4)(PMe3) + PhH The preparation of Ta(η5-C5Me5)(C6H4)Me2...
dimethyldiborane: (CH3)BH2.BH3 and (CH3)2BH.BH3. It reacts as a gas with trimethylphosphine to form a solid Lewis salt with a heat of formation of −41 kcal per...
has a smaller cone angle and better acceptor properties relative to trimethylphosphine. A representative derivative is the colorless tetrahedral complex...
atoms linked to the metal atom. This was first shown in 2003. The bis(trimethylphosphine) thiirane S-oxide complex of platinum, when heated in toluene at 110 °C...
reaction, air-free techniques are often employed when handling say, trimethylphosphine. Less basic phosphines, such as methyldiphenylphosphine are converted...
hydride, and alkyl derivatives of (pentamethylcyclopentadienyl)bis(trimethylphosphine)ruthenium." Organometallics, 3.2 (1984): 274–278. Tilley Group Website...
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