Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Tributylphosphine is the organophosphorus compound with the chemical formula P(CH2CH2CH2CH3)3, often abbreviated as PBu3. It is a tertiary phosphine. It is an oily liquid at room temperature, with a nauseating odor. It reacts slowly with atmospheric oxygen, and rapidly with other oxidizing agents, to give the corresponding phosphine oxide. It is usually handled using air-free techniques.
Tributylphosphine is the organophosphorus compound with the chemical formula P(CH2CH2CH2CH3)3, often abbreviated as PBu3. It is a tertiary phosphine....
azide to an amine. Triphenylphosphine or tributylphosphine are most commonly used, yielding tributylphosphine oxide or triphenylphosphine oxide as a side...
Hazards Flash point 86 °C (187 °F; 359 K) Related compounds Related Tributylphosphine Except where otherwise noted, data are given for materials in their...
aldehydes and ketones. Subsequent work demonstrated that the ligand tributylphosphine (PBu3) improved the selectivity of the cobalt-catalysed process. The...
yellow solids. Phosphine tellurides like trioctylphoshine telluride, tributylphosphine telluride and tricyclohexylphosphine telluride are reagents used in...
Grieco. The alcohol first reacts with o-nitrophenylselenocyanate and tributylphosphine to form a selenide via a nucleophilic substitution on the electron-deficient...
produce lead selenide. "Trioctylphosphine Selenide (TOPSe 15-6657) and Tributylphosphine Sulfide (TBPS 15-6658) for Quantum Dot Preparation". {{cite journal}}:...
amines and phosphines (ref). A ligand exchange reaction in which tributylphosphine ligands were displaced by primary alkylamine ligands on chloride terminated...
reaction the Grignard reagent combines with iron acetylacetonate and tributylphosphine to give an ill-defined aryliron intermediate, which then reacts with...
with the use of trialkyl phosphines such as trimethylphosphine or tributylphosphine. Aziridines are reactive substrates in ring-opening reactions with...
to form an oxaphosphonium salt. The aryl selenium anion displaces tributylphosphine oxide forming the alkyl aryl selenide species. The selenide is then...
similar selenoxide elimination using o-nitrophenylselenocyanate and tributylphosphine to cause the elimination of the elements of H2O. A. Krief, L. Hevesi...
varying amounts of benzene and biphenyl. It forms stable complexes with tributylphosphine and triphenylphosphine. When dissolved in dimethyl sulfide, phenylcopper...
doctorate considered nickelocene, cobaltocene and cyclopentadienyl (tributylphosphine)-copper in organic synthesis. After earning her doctorate, Moberg...
Ultraviolet irradiation. In this way, the commercially important tributylphosphine and trioctylphosphine are prepared in good yields from 1-butene and...
1002/9780470147306.ch1. ISBN 9780470147306. Vedejs E, Diver ST (1 April 1993). "Tributylphosphine: a remarkable acylation catalyst". Journal of the American Chemical...
of the indenyl ligand from η5 to η3. The corresponding reaction of tributylphosphine with (η5-C5H5)Mo(CO)3CH3 was 10 x slower. The term indenyl effect...
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