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Titanocene pentasulfide information


Titanocene pentasulfide
Names
Other names
titanocene pentasulfide
Identifiers
CAS Number
  • 12116-82-4 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 57542900
PubChem CID
  • 92000650
CompTox Dashboard (EPA)
  • DTXSID50746542 Edit this at Wikidata
InChI
  • InChI=1S/2C5H5.H2S5.Ti/c2*1-2-4-5-3-1;1-3-5-4-2;/h2*1-5H;1-2H;/q2*-1;;+4/p-2
    Key: JDSOAGYVYGEMJJ-UHFFFAOYSA-L
SMILES
  • [CH-]1C=CC=C1.[CH-]1C=CC=C1.S1SSSS[Ti2+]1
Properties
Chemical formula
C10H10S5Ti
Molar mass 338.382
Appearance red solid
Structure
Coordination geometry
Dist. tetrahedral
Related compounds
Related compounds
Zirconocene pentasulfide
Titanocene dichloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Titanocene pentasulfide is the organotitanium compound with the formula (C5H5)2TiS5, commonly abbreviated as Cp2TiS5. This metallocene exists as a bright red solid that is soluble in organic solvents. It is of academic interest as a precursor to unusual allotropes of elemental sulfur as well as some related inorganic rings.

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Titanocene pentasulfide

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Titanocene pentasulfide is the organotitanium compound with the formula (C5H5)2TiS5, commonly abbreviated as Cp2TiS5. This metallocene exists as a bright...

Word Count : 385

Allotropes of sulfur

Last Update:

dichloride: H2Sx + SyCl2 → cyclo-Sx+y + 2 HCl A second strategy uses titanocene pentasulfide as a source of the S2−5 unit. This complex is easily made from...

Word Count : 2475

Ring flip

Last Update:

engage in degenerate ring flipping. One well-studied example is titanocene pentasulfide, where the inversion barrier is high relative to cyclohexane's...

Word Count : 1087

Ralf Steudel

Last Update:

several new allotropes, often using titanocene pentasulfide. Two examples are S11 and S13, which resulted from the titanocene reagent and S6Cl2 and S8Cl2, respectively...

Word Count : 469

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