Titanocene Y also known as bis[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dichloride or dichloridobis(η5-(p-methoxybenzyl)cyclopentadienyl)titanium is an organotitanium compound that has been investigated for use as an anticancer drug.[1]
^Sweeney NJ, Mendoza O, Müller-Bunz H, Pampillón C, Rehmann FJ, Strohfeldt K, Tacke M (2005). "Novel benzyl substituted titanocene anti-cancer drugs". Journal of Organometallic Chemistry. 690 (21–22): 4537–4544. doi:10.1016/j.jorganchem.2005.06.039.
TitanoceneY also known as bis[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dichloride or dichloridobis(η5-(p-methoxybenzyl)cyclopentadienyl)titanium...
Titanocene pentasulfide is the organotitanium compound with the formula (C5H5)2TiS5, commonly abbreviated as Cp2TiS5. This metallocene exists as a bright...
Titanocene dichloride is the organotitanium compound with the formula (η5-C5H5)2TiCl2, commonly abbreviated as Cp2TiCl2. This metallocene is a common reagent...
and reduction of aldehydes. Cp2Ti(CO)2 is prepared by the reduction of titanocene dichloride with magnesium as a slurry in THT under an atmosphere of carbon...
chemistry, is an aluminium-containing derivative of titanocene that arises from the reaction of titanocene dichloride with trimethylaluminium. It is used for...
with polysulfur dichloride: H2Sx + SyCl2 → cyclo-Sx+y + 2 HCl A second strategy uses titanocene pentasulfide as a source of the S2−5 unit. This complex...
alkylated via salt metathesis reactions. Illustrative is the methylation of titanocene dichloride to give the Petasis reagent: (C5H5)2TiCl2 + 2 ClMgCH3 → (C5H5)2Ti(CH3)2...
developed a light-driven "closed cycle of water splitting using ansa-titanocene(III/IV) triflate complexes". An Indium gallium nitride (InxGa1-xN) photocatalyst...
(η5-C5H5)2VCl2 (commonly abbreviated as Cp2VCl2). It is a structural analogue of titanocene dichloride but with vanadium(IV) instead of titanium(IV). This compound...
(or the LiBH4) on the corresponding metal halide. One example is the titanocene derivative: 2 (C5H5)2TiCl2 + 4 NaBH4 → 2 (C5H5)2TiBH4 + 4 NaCl + B2H6...
for the methylenation of esters and ketones, is prepared from TMA and titanocene dichloride. In combination with 20 to 100 mol % Cp2ZrCl2 (zirconocene...
variants were initially examined with zirconocene bis(amido) complexes. Titanocene amido and sulfonamido complexes catalyze the intra-molecular hydroamination...
rings engage in degenerate ring flipping. One well-studied example is titanocene pentasulfide, where the inversion barrier is high relative to cyclohexane's...
(Me = CH3, Ph = C6H5). Another example is the metalacycle derived from titanocene dichloride, (C5H5)2Ti(SiPh2)5. Transition metal silane complexes are coordination...
activated by treatment with trimethylaluminium. Kaminsky discovered that titanocene and related complexes emulated some aspects of these Ziegler–Natta catalysts...
related (Ph3P)2Ni(CH2)4. Another example of a metallacyclopentane is the titanocene derivative Cp2Ti(CH2)4. Metallacyclopentanes are intermediates in the...
Closely related to the metallocenes are the metallocene derivatives, e.g. titanocene dichloride or vanadocene dichloride. Certain metallocenes and their derivatives...
disulfides oxidize low valence metals, as illustrated by the oxidation of titanocene dicarbonyl: (C5H5)2Ti(CO)2 + (C6H5S)2 → (C5H5)2Ti(SC6H5)2 + 2 CO Some...
to the lack of d to d transitions. Examples: titanium tetrachloride, titanocene dichloride, Schwartz's reagent. d1 Examples: molybdenum(V) chloride, vanadyl...
have been intensively studied. The most common organotitanium complex is titanocene dichloride ((C5H5)2TiCl2). Related compounds include Tebbe's reagent and...
Leijun; Samuel, Edmond (1997). "Preparation and characterization of titanocene silyl hydrides [Cp2Ti(μ-HSiH2)]2 and [Cp2Ti(μ-HSiH2)(μ-H)TiCp2]". Chemical...
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