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Molybdocene dichloride information


Molybdocene dichloride
Names
IUPAC name
dichlorobis(η5-cyclopentadienyl)molybdenum(IV)
Other names
molybdocene dichloride,
molybdenocene dichloride,
dichloridobis(cyclopentadienyl)molybdenum(IV)
Identifiers
CAS Number
  • 12184-22-4
3D model (JSmol)
  • Interactive image
ChemSpider
  • 398274
ECHA InfoCard 100.159.644 Edit this at Wikidata
PubChem CID
  • 452153
CompTox Dashboard (EPA)
  • DTXSID10923978 Edit this at Wikidata
InChI
  • InChI=1S/2C5H5.2ClH.Mo/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q2*-1;;;+2/p-2
    Key: QGGWSCVAFKWITK-UHFFFAOYSA-L
  • InChI=1/2C5H5.2ClH.Mo/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q2*-1;;;+2/p-2/r2C5H5.Cl2Mo/c2*1-2-4-5-3-1;1-3-2/h2*1-5H;/q2*-1;
    Key: QGGWSCVAFKWITK-OWLYHJECAX
SMILES
  • [cH-]1cccc1.[cH-]1cccc1.Cl[Mo+2]Cl
Properties
Chemical formula
 C10H10Cl2Mo
Molar mass 297.04 g·mol−1
Appearance greenish-brown powder
Solubility in water
 insoluble, moisture sensitive
Hazards
Safety data sheet (SDS) [1]
Related compounds
Related compounds
 Ferrocene
Zirconocene dichloride
Vanadocene dichloride
Niobocene dichloride
Titanocene dichloride
Tantalocene dichloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Molybdocene dichloride is the organomolybdenum compound with the formula (η5-C5H5)2MoCl2 and IUPAC name dichlorobis(η5-cyclopentadienyl)molybdenum(IV), and is commonly abbreviated as Cp2MoCl2. It is a brownish-green air- and moisture-sensitive powder. In the research laboratory, it is used to prepare many derivatives.

  1. ^ "42-0100 Molybdenum " Bis(cyclopentadienyl)molybdenum dichloride, 99%". Strem Chemicals. 27 July 2011. Retrieved 5 February 2012.

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Molybdocene dichloride

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Molybdocene dichloride is the organomolybdenum compound with the formula (η5-C5H5)2MoCl2 and IUPAC name dichlorobis(η5-cyclopentadienyl)molybdenum(IV)...

Word Count : 377

Titanocene dichloride

Last Update:

Titanocene dichloride is the organotitanium compound with the formula (η5-C5H5)2TiCl2, commonly abbreviated as Cp2TiCl2. This metallocene is a common reagent...

Word Count : 1771

Molybdocene dihydride

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cyclopentadienide, and sodium borohydride. The dihydride converts to molybdocene dichloride upon treatment with chloroform. The compound adopts a "clamshell"...

Word Count : 218

Zirconocene dichloride

Last Update:

Cl-Zr-Cl angle of 97.1° is wider than in niobocene dichloride (85.6°) and molybdocene dichloride (82°). This trend helped to establish the orientation...

Word Count : 986

Niobocene dichloride

Last Update:

angle of 85.6° is narrower than in zirconocene dichloride (97.1°) but wider than in molybdocene dichloride (82°). This trend is consistent with the orientation...

Word Count : 405

Bent metallocene

Last Update:

count. In the d2-complex molybdocene dichloride (Cp2MoCl2) the Cl-Mo-Cl angle is 82°. In the d1 complex niobocene dichloride, this angle is more open...

Word Count : 944

Organomolybdenum chemistry

Last Update:

Li4[Mo2(CH3)8]. With the formula of the type Cp2MoX2 molybdocene dichloride (X = Cl) and molybdocene dihydride (X = H) are both known as are ansa metallocene...

Word Count : 1939
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