The conformer of methylcyclohexane with equatorial methyl is favored by 1.74 kcal/mol (7.3 kJ/mol) relative to the conformer where methyl is axial.
In organic chemistry, a ring flip (also known as a ring inversion or ring reversal) is the interconversion of cyclic conformers that have equivalent ring shapes (e.g., from a chair conformer to another chair conformer) that results in the exchange of nonequivalent substituent positions.[1] The overall process generally takes place over several steps, involving coupled rotations about several of the molecule's single bonds, in conjunction with minor deformations of bond angles. Most commonly, the term is used to refer to the interconversion of the two chair conformers of cyclohexane derivatives, which is specifically referred to as a chair flip, although other cycloalkanes and inorganic rings undergo similar processes.
^IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "ring reversal (ring inversion)". doi:10.1351/goldbook.LR05397
chemistry, a ringflip (also known as a ring inversion or ring reversal) is the interconversion of cyclic conformers that have equivalent ring shapes (e...
longer), the isomers are termed atropisomers (see: atropisomerism). The ring-flip of substituted cyclohexanes constitutes another common form of conformational...
A ring counter is a type of counter composed of flip-flops connected into a shift register, with the output of the last flip-flop fed to the input of the...
trans-decalin 4: cis-decalin ring-flip The only possible way to join the two six-membered rings in the trans position means the second ring needs to start from...
major industrial accident caused by an explosion of cyclohexane Hexane Ringflip Cyclohexane (data page) "Hexanaphthene". dictionary.com. Archived from...
A flip clock (also known as a "flap clock") is an electromechanical, digital time keeping device with the time indicated by numbers that are sequentially...
usually worn with barefoot sandals, anklets, bare feet or flip flops. Like finger rings, toe rings come in many shapes and forms, from intricately designed...
Flip chip, also known as controlled collapse chip connection or its abbreviation, C4, is a method for interconnecting dies such as semiconductor devices...
cyclohexane. Because many compounds feature structurally similar six-membered rings, the structure and dynamics of cyclohexane are important prototypes of a...
consisted of two identical sites for the ring to move between without any preference, in a manner analogous to the ringflip in an unsubstituted cyclohexane....
standing on the ring apron, pulls on the top rope using the momentum to hurl over the ropes and into the ring. A simple front-flip used to modify an...
Cheese puffs, cheese curls, cheese balls, cheese ball puffs, cheesy puffs, or corn curls are a puffed corn snack, coated with a mixture of cheese or cheese-flavored...
Ring of Honor (ROH) is an American professional wrestling promotion based in Jacksonville, Florida. The promotion was founded by Rob Feinstein on February...
The Flip Video Mino was a smaller version of the Flip Video camcorder. The original Mino captured video in 640x480 resolution at 30 frames per second...
cyclohexenes. A bulky group like t-butyl locks the ring in a chair conformation and prevents ringflips. With 4-t-butylcyclohexene, oxymercuration yields...
such as iTunes. This is also referred to as "flick-book view." Ring switching is like flip switching, except the windows move in a circle, with the current...
(which is usually shaped as a small post, bead, ramp, or occasionally, a ring), forming a line of aim that points straight at the desired target. Open...
chair conformers of cyclohexane (and many other cyclic compounds) is called ring flipping. Carbon–hydrogen bonds that are axial in one configuration become...
Guardian. 22 February 2012. Jason Joseph, Rick Joseph (2007). 101 Ways to Flip the Bird. Broadway Books. ISBN 978-0-7679-2681-2. Acharya, Raghav; Challita...
Bulky Aryl Groups and the NOESY/EXSY Experimental Observation of Two-Ring-Flip Mechanism for Helicity Reversal of Molecular Propellers." European Journal...
his research team proposed a new mechanism, dubbed "the reaction-driven ringflip". Bachovchin's work in the area of drug design and development has led...
made his film debut in the comedy-drama Flipped, and is known for his roles in the crime film The Bling Ring (2013), the drama Perfect High (2015), the...
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