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Tetrachloroaluminate information


Tetrachloroaluminate
Names
IUPAC name
Tetrachloroaluminate(1–)
Systematic IUPAC name
Tetrachloroaluminate(1-)
Other names
 
  • Aluminate(1-), tetrachloro
  • tetrachloridoaluminate(1-)
  • tetrachloridoaluminate(1-); tetrachloroalumanuide
  • tetrachloroalumanuide
Identifiers
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:30110
ChemSpider
  • 10737456
Gmelin Reference
2297
PubChem CID
  • 3728926
InChI
  • InChI=1S/Al.4ClH/h;4*1H/q+3;;;;/p-4
    Key: BXILREUWHCQFES-UHFFFAOYSA-J
  • InChI=1S/Al.4ClH/h;4*1H/q+3;;;;/p-4
    Key: BXILREUWHCQFES-UHFFFAOYSA-J
SMILES
  • Cl[Al-](Cl)(Cl)Cl
Properties
Chemical formula
AlCl4
Molar mass 168.78 g·mol−1
Structure
Point group
Td
Molecular shape
Tetrahedral
Hybridisation sp3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Tetrachloroaluminate [AlCl4] is an anion formed from aluminium and chlorine. The anion has a tetrahedral shape, similar to carbon tetrachloride where carbon is replaced with aluminium. Some tetrachloroaluminates are soluble in organic solvents, creating an ionic non-aqueous solution, making them suitable as component of electrolytes for batteries. For example, lithium tetrachloroaluminate is used in some lithium batteries.

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Tetrachloroaluminate

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Tetrachloroaluminate [AlCl4]− is an anion formed from aluminium and chlorine. The anion has a tetrahedral shape, similar to carbon tetrachloride where...

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Sodium tetrachloroaluminate

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Sodium tetrachloroaluminate, also known as natrium chloroaluminate, is a chemical compound with the formula NaAlCl4. It was discovered in the 20th century...

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Lithium tetrachloroaluminate

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Lithium tetrachloroaluminate is an inorganic compound with the formula Li[AlCl4]. It consists of lithium cations Li+ and tetrahedral tetrachloroaluminate anions...

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Oxidation state

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200803465. PMID 18830949. Cd(I) has been observed in cadmium(I) tetrachloroaluminate (Cd2(AlCl4)2); see Holleman, Arnold F.; Wiberg, Egon; Wiberg, Nils...

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Aluminium chloride

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even weak Lewis bases such as benzophenone and mesitylene. It forms tetrachloroaluminate ([AlCl4]−) in the presence of chloride ions. Aluminium chloride reacts...

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Aluminate

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nuclear power industry. Examples are: Tetrachloroaluminate ion AlCl− 4 found in for example lithium tetrachloroaluminate. Tetrahydroaluminate ion AlH− 4 found...

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Aluminium cyanide

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The pure compound was produced in 2001 by the reaction of lithium tetrachloroaluminate and trimethylsilyl cyanide in diethyl ether and its crystals form...

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Glossary of chemical formulae

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AlCl4K potassium tetrachloroaluminate 13821-13-1 AlCl4Na sodium tetrachloroaluminate 7784-16-9 AlCl4Rb rubidium tetrachloroaluminate 17992-02-8 AlCl6K3...

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List of CAS numbers by chemical compound

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actinium(III) oxide 12002–61–8 Ag silver 7440-22-4 AgAlCl4 silver tetrachloroaluminate 27039–77–6 AgBr silver bromide 7785–23–1 AgBrO3 silver bromate 7783–89–3...

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Thionyl chloride

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negative electrode (anode); the electrolyte is typically lithium tetrachloroaluminate. The overall discharge reaction is as follows: 4 Li + 2 SOCl 2 ⟶...

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Lithium metal battery

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Variant is Li–CuFeS2. Li–SOCl2 (IEC code: E) Thionyl chloride Lithium tetrachloroaluminate in thionyl chloride 3.5 V 3.65 V 500–700 1,200 Liquid cathode. For...

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List of inorganic compounds

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g., x = 0.52 is lead zirconium titanate) Plumbane – PbH4 Lithium tetrachloroaluminate – LiAlCl4 Lithium aluminium hydride – LiAlH4 Lithium bromide – LiBr...

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Low valent magnesium compounds

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e.g. mercury(I) chloride) and Cd22+ ions (present in cadmium(I) tetrachloroaluminate). Since then a variety of stable Mg(I) compounds have been prepared...

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Chloroanion

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[BeCl4]2− Tetrachloromagnesate [MgCl4]2− Tetrachloroborate [BCl4]− Tetrachloroaluminate [AlCl4]− Hexachloroaluminate [AlCl6]3− Tetrachlorogallate(III) [GaCl4]−...

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Bismuth polycations

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solid state, particularly in salts where germanium tetrachloride or tetrachloroaluminate serve as the counteranions, but also in amorphous phases such as...

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