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Sodium polysulfide information


Sodium polysulfide

Sodium pentasulfide, a representative component of sodium polysulfide
Names
Other names
Sodium sulfane; Viradon
Identifiers
CAS Number
  • 1344-08-7
  • tetrasulfide: 12034-39-8
3D model (JSmol)
  • tetrasulfide: Interactive image
  • pentasulfide: Interactive image
ChemSpider
  • tetrasulfide: 74748
ECHA InfoCard 100.014.261 Edit this at Wikidata
EC Number
  • 215-686-9
PubChem CID
  • tetrasulfide: 82835
  • pentasulfide: 129677176
UN number UN3266
CompTox Dashboard (EPA)
  • DTXSID9051296 Edit this at Wikidata
SMILES
  • tetrasulfide: [Na+].[Na+].[S-]SS[S-]
  • pentasulfide: [Na+].[Na+].[S-]SSS[S-]
Properties
Chemical formula
Na2Sx
Hazards
GHS labelling:
Pictograms
GHS02: FlammableGHS05: CorrosiveGHS06: ToxicGHS09: Environmental hazard
Signal word
Danger
Hazard statements
H228, H301, H311, H314, H400
Precautionary statements
P210, P240, P241, P260, P264, P270, P273, P280, P301+P310, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P322, P330, P361, P363, P370+P378, P391, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3
0
1
Flash point Non-combustible
Safety data sheet (SDS) AGFA
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Sodium polysulfide is a general term for salts with the formula Na2Sx, where x = 2 to 5. The species Sx2−, called polysulfide anions, include disulfide (S22−), trisulfide (S32−), tetrasulfide (S42−), and pentasulfide (S52−). In principle, but not in practice, the chain lengths could be longer.[1][2] The salts are dark red solids that dissolve in water to give highly alkaline and corrosive solutions. In air, these salts oxidize, and they evolve hydrogen sulfide by hydrolysis.

  1. ^ Steudel, Ralf (2003-10-23). Elemental Sulfur and Sulfur-Rich Compounds I. Berlin Heidelberg: Springer Science & Business Media. ISBN 978-3-540-40191-9.
  2. ^ Steudel, Ralf (2003-11-17). Elemental Sulfur and Sulfur-Rich Compounds II. Berlin Heidelberg: Springer Science & Business Media. ISBN 978-3-540-40378-4.

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Sodium polysulfide

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Sodium polysulfide is a general term for salts with the formula Na2Sx, where x = 2 to 5. The species Sx2−, called polysulfide anions, include disulfide...

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Polysulfide

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maintain liquid polysulfide and Na+-conductive membranes that are unreactive toward sodium, sulfur, and sodium sulfide. Polysulfides are ligands in coordination...

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Sodium thiosulfate

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Na2S2O3 + 3 H2O Upon heating to 300 °C, it decomposes to sodium sulfate and sodium polysulfide: 4 Na2S2O3 → 3 Na2SO4 + Na2S5 Thiosulfate salts characteristically...

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Sodium sulfide

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solids, although technical grades of sodium sulfide are generally yellow to brick red owing to the presence of polysulfides and commonly supplied as a crystalline...

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Sodium tetrasulfide

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ClC3H6Si(OEt)3 → S4[C3H6Si(OEt)3]2 + 2 NaCl Sometimes as a mixture with other polysulfides, sodium tetrasulfide is used to produce the polymer called thiokol. The reaction...

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Thiokol

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In the course of an experiment involving ethylene dichloride and sodium polysulfide, they created a gum whose outstanding characteristic was a terrible...

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Chemical coloring of metals

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carbonate decreases, more yellow-green. Black for copper Solution of sodium polysulfide 2.5%, items must be submerged in the solution after color developing...

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List of fungicides

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simeconazole [Wikidata] sodium azide sodium bicarbonate sodium orthophenylphenoxide sodium pentachlorophenoxide sodium polysulfide spiroxamine [Wikidata]...

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Disulfide

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alkylation of alkali metal di- and polysulfides gives disulfides. "Thiokol" polymers arise when sodium polysulfide is treated with an alkyl dihalide....

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Hydrogen disulfide

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polysulfane is produced by the reaction of hydrochloric acid with aqueous sodium polysulfide. The polysulfane precipitates as an oil. Upon contact with water or...

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Potassium pentasulfide

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several polysulfide salts with the general formula M2Sn, where M = Li, Na, K and n = 2, 3, 4, 5, 6. The polysulfide salts of potassium and sodium are similar...

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Nanodot

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tridoped hierarchical porous carbon as efficient electrocatalysis of polysulfide conversion for lithium-sulfur batteries". Electrochimica Acta. 299: 600–609...

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Ion

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causes sodium and chlorine to undergo a chemical reaction, wherein the "extra" electron is transferred from sodium to chlorine, forming sodium cations...

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Sulfur dye

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organosulfur compounds consisting of sulfide (–S–), disulfide (–S–S–) and polysulfide (–Sn–) links in heterocyclic rings. They feature thiazoles, thiazone...

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Sulfur compounds

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gives various polysulfides with the formula Sx2-, many of which have been obtained crystalline form. Illustrative is the production of sodium tetrasulfide:...

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Magnesium compounds

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reacting hydrogen sulfide with magnesium oxide in suspension. Magnesium polysulfides have been studied in magnesium-sulfur batteries. Magnesium selenide is...

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Calcium sulfide

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used as an insecticide. The active ingredient is probably a calcium polysulfide, not CaS. Calcium sulfide decomposes upon contact with water, including...

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Flow battery

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reaction. Traditional redox flow battery chemistries include vanadium, polysulfide–bromide (Regenesys), iron (IRFB), and uranium. Redox fuel cells are less...

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Photographic print toning

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according to the chemical mixture; Polysulfide or 'direct' toners – these do not require a bleaching stage. Except for polysulfide toners, sepia toning is done...

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List of insecticides

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silafluofen silica gel sodium arsenite sodium cyanide sodium fluoride sodium silicofluoride sodium tetrathiocarbonate sodium thiocyanate sophamide [Wikidata]...

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Qualitative inorganic analysis

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Sn2+, Sn4+ are soluble in yellow ammonium sulfide, where they form polysulfide complexes. This group is determined by adding the salt in water and then...

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Polyphenylene sulfide

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fiber in which the fiber-forming substance is a long chain synthetic polysulfide in which at least 85% of the sulfide (–S–) linkages are attached directly...

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List of battery types

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battery Nickel–zinc battery Organic radical battery Polymer-based battery Polysulfide–bromide battery Potassium-ion battery Rechargeable alkaline battery Rechargeable...

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