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Sodium arsenide information


Sodium arsenide
Names
IUPAC name
Disodioarsanylsodium
Identifiers
CAS Number
  • 12044-25-6
3D model (JSmol)
  • Interactive image
ChemSpider
  • 74787
ECHA InfoCard 100.031.762 Edit this at Wikidata
EC Number
  • 234-952-5
PubChem CID
  • 82879
CompTox Dashboard (EPA)
  • DTXSID0065222 Edit this at Wikidata
InChI
  • InChI=1S/As.3Na
    Key: MMQSOEGXVXPNSH-UHFFFAOYSA-N
SMILES
  • [Na][As]([Na])[Na]
Properties
Chemical formula
Na3As
Molar mass 143.89 g·mol−1
Appearance Violet brown solid
Density 2.36 g·cm−3
Solubility in water
Hydrolysis
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Toxic, releases AsH3
Related compounds
Other anions
Sodium nitride, sodium phosphide, sodium antimonide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Sodium arsenide, also known as trisodium arsenide, is the inorganic compound of sodium and arsenic with the formula Na3As.[1] It is a dark colored solid that degrades upon contact with water or air. It is prepared by the reaction of the elements at 200–400 °C.[2] The compound is mainly of interest as exhibiting an archetypal structure. The normal pressure "sodium arsenide" phase is adopted by many alkali metal pnictides. At 3.6 gigapascals, Na3As adopts the Li3Bi structure, which is another archetypal structure.[3] Sodium arsenide is a crystalline solid used as a semiconductor and in photo optic applications. Its IUPAC name is disodioarsanylsodium.

At high pressures, Na3As adopts this cubic structure (the so-called Li3Bi motif).
  1. ^ Elements, American. "Sodium Arsenide". American Elements. Retrieved 2018-12-05.
  2. ^ E. Dönges (1963). G. Brauer (ed.). Alkali Metals (2nd ed.). New York: Academic Press. p. 986. {{cite book}}: |work= ignored (help)
  3. ^ Beister, Heinz Jürgen; Syassen, Karl; Klein, Jürgen (1990). "Phase Transition of Na3As under Pressure". Zeitschrift für Naturforschung B. 45 (10): 1388–1392. doi:10.1515/znb-1990-1007. S2CID 197037185.

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Sodium arsenide

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Sodium arsenide, also known as trisodium arsenide, is the inorganic compound of sodium and arsenic with the formula Na3As. It is a dark colored solid that...

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Arsenide

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earth metals, form arsenides with isolated arsenic atoms. They form upon heating arsenic powder with excess sodium gives sodium arsenide (Na3As). The structure...

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Calcium arsenide

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Calcium arsenide is an inorganic compound with the chemical formula Ca2As2 and is one of the arsenides of calcium. It is a hexagonal crystal with a space...

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Arsine

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react with protonic reagents to also produce this gas. Zinc arsenide and sodium arsenide are suitable precursors: Zn3As2 + 6 H+ → 2 AsH3 + 3 Zn2+ Na3As...

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Sodium phosphide

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The compound crystallizes in a hexagonal motif, often called the sodium arsenide structure. Like K3P, solid Na3P features pentacoordinate P centers...

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Pnictogen

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pnictogens fully reduced include yttrium nitride, calcium phosphide, sodium arsenide, indium antimonide, and even double salts like aluminum gallium indium...

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Lithium nitride

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known: beta-Li3N, formed from the alpha phase at 0.42 GPa has the sodium arsenide (Na3As) structure; gamma-Li3N (same structure as lithium bismuthide...

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Strukturbericht designation

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C2/m Aluminium chloride structure D017 BaS3 P421m D018 Na3As P63/mmc Sodium arsenide structure D019 Ni3Sn P63/mmc D020 Al3Ni Pnma D021 Cu3P P3c1 (original...

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Praseodymium arsenide

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PrAs}}} Praseodymium arsenide forms cubic crystals, space group F m3m, cell parameters a = 0.6009 nm, Z = 4, and structure like sodium chloride. When heated...

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List of inorganic compounds

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Ac2O3 Aluminium antimonide – AlSb Aluminium arsenate – AlAsO4 Aluminium arsenide – AlAs Aluminium diboride – AlB2 Aluminium bromide – AlBr3 Aluminium carbide...

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Cubic crystal system

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itself, lead(II) nitrate, many compound semiconductors (such as gallium arsenide and cadmium telluride), and a wide array of other binary compounds.[citation...

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Lattice constant

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diodes and diode lasers. For example, gallium arsenide, aluminium gallium arsenide, and aluminium arsenide have almost equal lattice constants, making it...

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Alkali metal

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The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr). Together with...

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Hsp104

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Hsp104 expression include: Heat or cold shock Hydrogen peroxide Ethanol Sodium Arsenide The role of Hsp104 when interaction with Sup35 Prion Propagation is...

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Gallium

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0 °C (98.6 °F). Gallium is predominantly used in electronics. Gallium arsenide, the primary chemical compound of gallium in electronics, is used in microwave...

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Coordination number

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distorted structures. Nickel arsenide, NiAs has a structure where nickel and arsenic atoms are 6-coordinate. Unlike sodium chloride where the chloride...

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Arsenic

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devices. It is also a component of the III–V compound semiconductor gallium arsenide. Arsenic and its compounds, especially the trioxide, are used in the production...

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Cobalt extraction

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copper-cobaltite precipitates and is fed back to the leaching process. Sodium hydrosulfide (NaHS) is added (along with some metallic cobalt as a catalyst)...

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Cinnabar

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refractive index is 3.08 (sodium light wavelengths), versus the indices for diamond and the non-mineral gallium(III) arsenide (GaAs), which are 2.42 and...

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Organosodium chemistry

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chemistry is the chemistry of organometallic compounds containing a carbon to sodium chemical bond. The application of organosodium compounds in chemistry is...

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Index of chemistry articles

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alkene Allingite allotrope Allotropy alloy Alum Aluminium Aluminium gallium arsenide Aluminium oxide Alunite Alvite amalgams Amazonite Amber Amblygonite Amedeo...

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Praseodymium antimonide

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At a pressure of 13 GPa, a phase transition also occurs. Praseodymium arsenide Praseodymium bismuthide Diagrammy sostojanija dvojnych metalličeskich sistem:...

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Silicon dioxide

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silicon it is more widely used compared to other semiconductors like gallium arsenide or indium phosphide. Silicon dioxide could be grown on a silicon semiconductor...

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List of refractive indices

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Standard refractive index measurements are taken at the "yellow doublet" sodium D line, with a wavelength (λ) of 589 nanometers. There are also weaker dependencies...

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Arsenic trioxide

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elemental arsenic, arsenic alloys, and arsenide semiconductors. Bulk arsenic-based compounds sodium arsenite and sodium cacodylate are derived from the trioxide...

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Ternary compound

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example is sodium phosphate, Na3PO4. The sodium ion has a charge of 1+ and the phosphate ion has a charge of 3–. Therefore, three sodium ions are needed...

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