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Singlet state information


Examples of atoms in singlet, doublet, and triplet states.

In quantum mechanics, a singlet state usually refers to a system in which all electrons are paired. The term 'singlet' originally meant a linked set of particles whose net angular momentum is zero, that is, whose overall spin quantum number . As a result, there is only one spectral line of a singlet state. In contrast, a doublet state contains one unpaired electron and shows splitting of spectral lines into a doublet, and a triplet state has two unpaired electrons and shows threefold splitting of spectral lines.

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Singlet state

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In quantum mechanics, a singlet state usually refers to a system in which all electrons are paired. The term 'singlet' originally meant a linked set of...

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Singlet oxygen

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Singlet oxygen, systematically named dioxygen(singlet) and dioxidene, is a gaseous inorganic chemical with the formula O=O (also written as 1 [O 2] or...

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Singlet

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up singlet in Wiktionary, the free dictionary. Singlet may refer to: singlet state, in theoretical physics, a quantum state with zero spin Singlet fission...

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Triplet state

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aligning oppositely to give S = 0, a spin singlet. Most molecules encountered in daily life exist in a singlet state because all of their electrons are paired...

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Gluon

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a "color singlet" state, which is mathematically analogous to a spin singlet state. Such states allow interaction with other color singlets, but not with...

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Intersystem crossing

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singlet ground state is excited (via absorption of radiation) to a higher energy level, either an excited singlet state or an excited triplet state will...

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Phosphorescence

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fluorescent "singlet state" to a slower emitting "triplet state". The slower timescales of the reemission are associated with "forbidden" energy state transitions...

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Deuterium

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state of isospin called singlet, or in a symmetric state called triplet. In terms of the "down" state and "up" state, the singlet is 1 2 ( | ↑↓ ⟩ − | ↓↑...

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Thermally activated delayed fluorescence

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intersystem crossing (RISC) converting it to a singlet state, which can then de-excite to the ground state and emit light in a process termed fluorescence...

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Quantum state

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trace 1. A more complicated case is given (in bra–ket notation) by the singlet state, which exemplifies quantum entanglement: | ψ ⟩ = 1 2 ( | ↑↓ ⟩ − | ↓↑...

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Photodynamic therapy

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or transfer from a substrate molecule and highly reactive state of oxygen known as singlet oxygen (Type II). PDT is a multi-stage process. First a photosensitiser...

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Doublet state

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whereas singlet systems and triplet systems have significantly lower efficiencies or rely on noble metals such as Pt and Ir to emit light. Singlet state Triplet...

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Helium atom

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be the spin anti-symmetric state (singlet state) or orthohelium to be spin symmetric state (triplet state). The singlet state is given as: | χ s = 0 , m...

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Triplet oxygen

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independent spin states in total. Exchange interaction splits these into a singlet state (total spin S = 0) and a set of 3 degenerate triplet states (S = 1)...

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Diatomic carbon

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with corresponding energy levels. The state with the lowest energy level, or ground state, is a singlet state (1Σ+ g), which is systematically named...

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Excited state

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excited states are often called metastable. Long-lived nuclear isomers and singlet oxygen are two examples of this. Atoms can be excited by heat, electricity...

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Carbene

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125–140° for triplet methylene and 102° for singlet methylene. Most carbenes have a nonlinear triplet ground state. For simple hydrocarbons, triplet carbenes...

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Singlet fission

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Singlet fission is a spin-allowed process, unique to molecular photophysics, whereby one singlet excited state is converted into two triplet states. The...

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Fluorenylidene

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unusual property that the triplet ground state is only 1.1 kcal/mol (4.6 kJ/mol) lower in energy than the singlet state. For this reason, fluorenylidene has...

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Photobleaching

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modifications in covalent bonds are caused by transition from a singlet state to the triplet state of the fluorophores. The number of excitation cycles to achieve...

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Isoscalar

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isospin. Isoscalars are a singlet state, with total isospin 0 and the third component of isospin 0, much like a singlet state in a 2-particle addition...

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Photoluminescence

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this triplet state, electron transition (relaxation) back to the lower singlet state energies is quantum mechanically forbidden, meaning that it happens...

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Norrish reaction

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photochemical singlet state. Through intersystem crossing the triplet state can be obtained. On cleavage of the α-carbon bond from either state, two radical...

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Superdeterminism

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S2CID 121627152. Hall, Michael J. W. (2010-12-16). "Local Deterministic Model of Singlet State Correlations Based on Relaxing Measurement Independence". Physical Review...

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Photosensitizer

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transform into an excited singlet state. The single electron in the excited singlet state then flips in its intrinsic spin state via Intersystem crossing...

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Spin chemistry

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molecule, may have opposite spin (singlet; anticorrelated), or the same spin (triplet; correlated). The singlet state is called such because there is only...

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Nitrenium ion

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carbenes, and can exist in either a singlet or a triplet state. The parent nitrenium ion, NH+2, is a ground state triplet species with a gap of 30 kcal/mol...

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