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Excited state information


After absorbing energy, an electron may jump from the ground state to a higher energy excited state.
Excitations of copper 3d orbitals on the CuO2 plane of a high-Tc superconductor. The ground state (blue) is x2y2 orbitals; the excited orbitals are in green; the arrows illustrate inelastic x-ray spectroscopy.

In quantum mechanics, an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that is, more energy than the absolute minimum). Excitation refers to an increase in energy level above a chosen starting point, usually the ground state, but sometimes an already excited state. The temperature of a group of particles is indicative of the level of excitation (with the notable exception of systems that exhibit negative temperature).

The lifetime of a system in an excited state is usually short: spontaneous or induced emission of a quantum of energy (such as a photon or a phonon) usually occurs shortly after the system is promoted to the excited state, returning the system to a state with lower energy (a less excited state or the ground state). This return to a lower energy level is often loosely described as decay and is the inverse of excitation.

Long-lived excited states are often called metastable. Long-lived nuclear isomers and singlet oxygen are two examples of this.

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Excited state

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an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that...

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Excited

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(2005) "Excited" (M People song) (1992) Excitation (disambiguation) Excited state, an elevation in energy level above an arbitrary baseline energy state Exciter...

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Intersystem crossing

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singlet ground state is excited (via absorption of radiation) to a higher energy level, either an excited singlet state or an excited triplet state will form...

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Excited state intramolecular proton transfer

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Excited state intramolecular proton transfer (ESIPT) is a process in which photoexcited molecules relax their energy through tautomerization by transfer...

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Ground state

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An excited state is any state with energy greater than the ground state. In quantum field theory, the ground state is usually called the vacuum state or...

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Excimer

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short for excited dimer) is a short-lived polyatomic molecule formed from two species that do not form a stable molecule in the ground state. In this case...

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Population inversion

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a group of atoms or molecules) exists in a state in which more members of the system are in higher, excited states than in lower, unexcited energy states...

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Radioactive decay

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nuclide. Except for gamma decay or internal conversion from a nuclear excited state, the decay is a nuclear transmutation resulting in a daughter containing...

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Nuclear isomer

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nuclear isomer is a metastable state of an atomic nucleus, in which one or more nucleons (protons or neutrons) occupy excited state (higher energy) levels. "Metastable"...

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Fluorescence

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Fluorescence occurs when an excited molecule, atom, or nanostructure, relaxes to a lower energy state (usually the ground state) through emission of a photon...

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Photoinduced electron transfer

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Photoinduced electron transfer (PET) is an excited state electron transfer process by which an excited electron is transferred from donor to acceptor...

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Vibrational energy relaxation

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the vibrationally excited state of the electronic excited state. The process of the energy relaxation from these vibrationally excited states can be observed...

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Stokes shift

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a molecule or atom) absorbs a photon, it gains energy and enters an excited state. The system can relax by emitting a photon. The Stokes shift occurs...

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Sisyphus cooling

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Consider, for example, an atom with ground state angular momentum J = 1 2 {\textstyle J={\frac {1}{2}}} and excited state angular momentum J ′ = 3 2 {\textstyle...

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Laser

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must be in the proper excited state so that the photons can trigger them. In most materials, atoms or molecules drop out of excited states fairly rapidly...

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Scintillator

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the form of light). Sometimes, the excited state is metastable, so the relaxation back down from the excited state to lower states is delayed (necessitating...

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Energy level

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ground state. If it is at a higher energy level, it is said to be excited, or any electrons that have higher energy than the ground state are excited. An...

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Stimulated emission

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of a specific frequency can interact with an excited atomic electron (or other excited molecular state), causing it to drop to a lower energy level....

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Phosphorescence

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states (0 is the ground state, and 1 the excited state). Transitions can also occur to higher energy levels, but the first excited state is denoted for simplicity...

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Helium atom

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approximations, such as the Hartree–Fock method, can be used to estimate the ground state energy and wavefunction of the atom. Historically, the first such helium...

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Singlet oxygen

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state where all electrons are spin paired. It is kinetically unstable at ambient temperature, but the rate of decay is slow. The lowest excited state...

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Laser pumping

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in the medium, producing excited states in its atoms. When for a period of time the number of particles in one excited state exceeds the number of particles...

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