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Norrish reaction information


A Norrish reaction, named after Ronald George Wreyford Norrish, is a photochemical reaction taking place with ketones and aldehydes. Such reactions are subdivided into Norrish type I reactions and Norrish type II reactions.[1] While of limited synthetic utility these reactions are important in the photo-oxidation of polymers such as polyolefins,[2] polyesters, certain polycarbonates and polyketones.

  1. ^ Named Organic Reactions, 2nd Edition, Thomas Laue and Andreas Plagens, John Wiley & Sons: Chichester, England, New York, 2005. 320 pp. ISBN 0-470-01041-X
  2. ^ Grause, Guido; Chien, Mei-Fang; Inoue, Chihiro (November 2020). "Changes during the weathering of polyolefins". Polymer Degradation and Stability. 181: 109364. doi:10.1016/j.polymdegradstab.2020.109364. S2CID 225243217.

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Norrish reaction

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A Norrish reaction, named after Ronald George Wreyford Norrish, is a photochemical reaction taking place with ketones and aldehydes. Such reactions are...

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Ronald George Wreyford Norrish

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George Wreyford Norrish FRS (9 November 1897 – 7 June 1978) was a British chemist who was awarded the Nobel Prize in Chemistry in 1967. Norrish was born in...

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Ketone

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a reaction that proceeds via an enol (see Haloform reaction) With heavy water to give an α-deuterated ketone Fragmentation in photochemical Norrish reaction...

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Norrish

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Norrish is a surname. Notable people with the surname include: Jason Norrish (born 1972), Australian rules footballer Merwyn Norrish (born 1926), New Zealand...

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McLafferty rearrangement

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leading to his name being associated with the process. The Type II Norrish reaction is the equivalent photochemical process α-cleavage A. J. C. Nicholson...

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Photochemistry

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organic reactions are electrocyclic reactions, radical reactions, photoisomerization, and Norrish reactions. Alkenes undergo many important reactions that...

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Ozonolysis

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surface ketone groups that can cause further gradual degradation via Norrish reactions if the polymer is exposed to light. To minimize this problem, many...

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Dodecahedrane

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newly formed ketone group then forms another C–C bond by photochemical Norrish reaction to 19 whose alcohol group is induced to eliminate with TsOH to alkene...

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Polyethylene terephthalate

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acetaldehyde over the object's lifespan. This proceeds via a Type II Norrish reaction. When acetaldehyde is produced, some of it remains dissolved in the...

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Acetaldehyde

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photo-oxidation of polyethylene terephthalate (PET), via a Type II Norrish reaction. Although the levels produced by this process are minute acetaldehyde...

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Organic photochemistry

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It is possible to quench triplet reactions. Common organic photochemical reactions include: Norrish Type I, the Norrish Type II, the racemization of optically...

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Fries rearrangement

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polyurethane, is exposed to the sun (aliphatic carbonyls undergo Norrish reactions, which are somewhat similar). In this case, photolysis of the ester...

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Autoacceleration

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Autoacceleration (gel effect, Trommsdorff–Norrish effect) is a dangerous reaction behavior that can occur in free-radical polymerization systems. It is...

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Flash photolysis

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technique was developed in 1949 by Manfred Eigen, Ronald George Wreyford Norrish and George Porter, who won the 1967 Nobel Prize in Chemistry for this invention...

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Photolabile protecting group

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traditionally identified as Norrish Type II reaction as their mechanism was first described by Norrish in 1935. Norrish elucidated that an incident photon...

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Formaldehyde

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from the original on 2023-04-20. Retrieved 2023-04-20. Bevington, J. C.; Norrish, R. G. W. (1951-03-07). "The catalyzed polymerization of gaseous formaldehyde"...

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Rosalind Franklin

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Ronald George Wreyford Norrish, the 1920 Chair of Physical Chemistry at the University of Cambridge. Disappointed by Norrish's lack of enthusiasm, she...

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George Porter

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research at the University of Cambridge supervised by Ronald George Wreyford Norrish where he began the work that ultimately led to them becoming Nobel Laureates...

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Manfred Eigen

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George Wreyford Norrish and George Porter, the Nobel Prize in Chemistry. They were cited for their studies of extremely fast chemical reactions induced in...

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Index of chemistry articles

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Robert Wilhelm Bunsen Rock crystal Roentgenium Ronald George Wreyford Norrish Rose quartz Roumanite Rubidium Ruby Rudolph A. Marcus Rudolph Pariser Ruthenium...

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Togo national football team attack

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ambush". BBC News. 8 January 2010. Retrieved 8 January 2010. White, Duncan; Norrish, Mike (9 January 2010). "Togo pull out of African Nations Cup after bus...

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List of career achievements by Cristiano Ronaldo

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Archived from the original on 15 December 2022. Retrieved 24 August 2017. Norrish, Mike (2 December 2008). "Manchester United's Cristiano Ronaldo wins Ballon...

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