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Ring forming reaction information


A ring forming reaction or ring-closing reaction in organic chemistry is a general term for a variety of reactions that introduce one or more rings into a molecule. A heterocycle forming reaction is such a reaction that introduces a new heterocycle.[1][2] Important classes of ring forming reactions include annulations[3] and cycloadditions.

  1. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (1995) "Heterocyclic compounds". doi:10.1351/goldbook.H02798
  2. ^ Katritzky, A. R.; Pozharskii, A. F. (2000). Handbook of Heterocyclic Chemistry (2nd ed.). Academic Press. ISBN 0080429882.
  3. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "annulation". doi:10.1351/goldbook.A00367

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Ring forming reaction

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chemical reaction used in organic chemistry for ring formation. It was discovered by Robert Robinson in 1935 as a method to create a six membered ring by forming...

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intermolecular reaction is the Claisen condensation. Dieckmann condensations are highly effective routes to 5-, 6-, and 7-member rings, but poor for larger rings. Deprotonation...

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chemical reaction used to synthesize quinolines. It is named after the Czech chemist Zdenko Hans Skraup (1850-1910). In the archetypal Skraup reaction, aniline...

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Annulation

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annulation (from Latin anellus 'little ring'; occasionally annelation) is a chemical reaction in which a new ring is constructed on a molecule. Examples...

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Fischer indole synthesis

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(or ring compound) is a term for a compound in the field of chemistry in which one or more series of atoms in the compound is connected to form a ring. Rings...

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synthesis or Hantzsch dihydropyridine synthesis is a multi-component organic reaction between an aldehyde such as formaldehyde, 2 equivalents of a β-keto ester...

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forming an alkene (11), and one equivalent gets incorporated into the indole ring. The nitroso intermediate (4) has been isolated from the reaction....

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Gewald reaction

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Electrocyclic reaction

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by the following criteria: Reactions can be either photochemical or thermal. Reactions can be either ring-opening or ring-closing (electrocyclization)...

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temporary reversal of the ring-forming reaction, resulting in the open-chain form, followed by a reforming of the ring. The ring closure step may use a different...

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Cycloaddition

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cyclopropane rings, as these have significant π character. For example, an analog for the Diels-Alder reaction is the quadricyclane-DMAD reaction: In the (i+j+...

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Fischer oxazole synthesis

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of dehydration reaction which can occur under mild conditions in a rearrangement of the groups that would not seem possible. The reaction occurs by dissolving...

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