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Partial molar property information


In thermodynamics, a partial molar property is a quantity which describes the variation of an extensive property of a solution or mixture with changes in the molar composition of the mixture at constant temperature and pressure. It is the partial derivative of the extensive property with respect to the amount (number of moles) of the component of interest. Every extensive property of a mixture has a corresponding partial molar property.

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Partial molar property

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a partial molar property is a quantity which describes the variation of an extensive property of a solution or mixture with changes in the molar composition...

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Apparent molar property

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In thermodynamics, an apparent molar property of a solution component in a mixture or solution is a quantity defined with the purpose of isolating the...

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Intensive and extensive properties

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thermodynamic properties may be expressed on a molar basis, and their name may be qualified with the adjective molar, yielding terms such as molar volume, molar internal...

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Chemical potential

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number of particles is expressed in moles, the chemical potential is the partial molar Gibbs free energy. At chemical equilibrium or in phase equilibrium,...

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Excess property

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excess molar property, and z {\displaystyle z} denotes the particular property under consideration. From the properties of partial molar properties, z =...

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Mole fraction

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In chemistry, the mole fraction or molar fraction, also called mole proportion or molar proportion, is a quantity defined as the ratio between the amount...

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Partial specific volume

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{\displaystyle \sum _{i}\rho _{i}\cdot {\bar {v_{i}}}=1} Partial molar property Apparent molar property Buxbaum, Engelbert (2011). "25: Centrifugation". Biophysical...

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Thermodynamic activity

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equivalent of activity for partial pressure Chemical equilibrium Electrochemical potential Excess chemical potential Partial molar property Thermodynamic equilibrium...

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Molar concentration

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Molar concentration (also called molarity, amount concentration or substance concentration) is a measure of the concentration of a chemical species, in...

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Molar pregnancy

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conception may or may not contain fetal tissue. These molar pregnancies are categorized into two types: partial moles and complete moles, where the term 'mole'...

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Specific heat capacity

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m}=\left({\frac {\partial C}{\partial n}}\right)_{p}&={\text{molar heat capacity at constant pressure}}\\C_{V,m}=\left({\frac {\partial C}{\partial n}}\right)_{V}&={\text{molar...

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Amount of substance

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by its amount of substance is an intensive property of the substance, usually named by the prefix "molar" or the suffix "per mole". For example, the...

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Specific volume

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{RT}{PM}}} Specific volume is commonly applied to: Molar volume Volume (thermodynamics) Partial molar volume Imagine a variable-volume, airtight chamber...

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Heat capacity

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Dividing the heat capacity by the amount of substance in moles yields its molar heat capacity. The volumetric heat capacity measures the heat capacity per...

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Ideal solution

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standing for partial molar volume: ( ∂ ln ⁡ f i ∂ P ) T , x i = v i ¯ R T . {\displaystyle \left({\frac {\partial \ln f_{i}}{\partial P}}\right)_{T,x_{i}}={\frac...

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Density of air

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but for different gasses (measuring their partial pressure), it is again different and depends upon molar mass, giving 8.7 for nitrogen, 7.6 for oxygen...

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Enthalpy change of solution

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_{i}\left(1+{\frac {T}{\epsilon }}{\frac {\partial \epsilon }{\partial T}}\right)} Apparent molar property Enthalpy of mixing Heat of dilution Heat of...

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Internal energy

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measured by changes in the system's properties, such as temperature, entropy, volume, electric polarization, and molar constitution. The internal energy...

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Murugesapillai Maheswaran

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prove that if the partial molar property of one component of a multicomponent mixture or solution is known then the partial molar property of all the other...

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Magnetic susceptibility

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commonly used M and H. There are two other measures of susceptibility, the molar magnetic susceptibility (χm) with unit m3/mol, and the mass magnetic susceptibility...

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Partial pressure

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gas component, e.g. oxygen. It can be approximated both from partial pressure and molar fraction: V X = V t o t × p X p t o t = V t o t × n X n t o t...

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Van der Waals equation

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{\displaystyle VN_{\text{A}}/N} (molar volume) used here, Gibbs did as well, so do most engineers. Also the property, V / N {\displaystyle V/N} the reciprocal...

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Fugacity

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equal to the pressure of an ideal gas which has the same temperature and molar Gibbs free energy as the real gas. Fugacities are determined experimentally...

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Ideal gas

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ISBN 0-07-238332-1. "CODATA Value: molar volume of ideal gas (273.15 K, 100 kPa)". Retrieved 2023-09-01. "CODATA Value: molar volume of ideal gas (273.15 K...

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Heat capacity ratio

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{c_{P}}{c_{V}}},} where C is the heat capacity, C ¯ {\displaystyle {\bar {C}}} the molar heat capacity (heat capacity per mole), and c the specific heat capacity...

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Compressibility

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_{T}=-{\frac {1}{V}}\left({\frac {\partial V}{\partial p}}\right)_{T},} where the subscript T indicates that the partial differential is to be taken at constant...

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Volume fraction

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Breathalyzer Alcohol proof Apparent molar property For non-ideal mixtures, see Partial molar volume and Excess molar quantity Percentage Mass fraction (chemistry)...

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Ideal gas law

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moles), is equal to total mass of the gas (m) (in kilograms) divided by the molar mass, M (in kilograms per mole): n = m M . {\displaystyle n={\frac {m}{M}}...

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Enthalpy of fusion

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unit of mass, it is usually called the specific heat of fusion, while the molar heat of fusion refers to the enthalpy change per amount of substance in...

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