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Naled information


Naled
Skeletal formula of Naled
Ball-and-stick model of the Naled molecule
Names
IUPAC name
Dimethyl-1,2-dibromo-2,2-dichlorethyl phosphate
Other names
Dibrom, 1,2-Dibromo-2,2-dichloroethyl dimethyl phosphate
Identifiers
CAS Number
  • 300-76-5 checkY
3D model (JSmol)
  • Interactive image
Beilstein Reference
2049930
ChEBI
  • CHEBI:38729
ChEMBL
  • ChEMBL1887067
ChemSpider
  • 4267
ECHA InfoCard 100.005.545 Edit this at Wikidata
EC Number
  • 206-098-3
KEGG
  • C18749
PubChem CID
  • 4420
RTECS number
  • TB9450000
UNII
  • PAM1AI9KU1 checkY
UN number 3018 2783
CompTox Dashboard (EPA)
  • DTXSID1024209
InChI
  • InChI=1S/C4H7Br2Cl2O4P/c1-10-13(9,11-2)12-3(5)4(6,7)8/h3H,1-2H3
    Key: BUYMVQAILCEWRR-UHFFFAOYSA-N
  • InChI=1/C4H7Br2Cl2O4P/c1-10-13(9,11-2)12-3(5)4(6,7)8/h3H,1-2H3
    Key: BUYMVQAILCEWRR-UHFFFAOYAA
SMILES
  • COP(=O)(OC)OC(C(Cl)(Cl)Br)Br
Properties
Chemical formula
C4H7O4PBr2Cl2[1]
Molar mass 380.8 g/mol[1]
Appearance Colorless to white solid or straw-colored liquid[1]
Density 1.96 g/mL (25°C)[1]
Melting point 27 °C; 80 °F; 300 K[1]
Boiling point decomposes[1]
Vapor pressure 0.0002 mmHg (20°C)[1]
Hazards
GHS labelling:
Pictograms
GHS07: Exclamation markGHS09: Environmental hazard
Signal word
Warning
Hazard statements
H302, H312, H315, H319, H400
Precautionary statements
P264, P270, P273, P280, P301+P312, P302+P352, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P391, P501
Flash point noncombustible[1]
Lethal dose or concentration (LD, LC):
LD50 (median dose)
156 mg/kg (inhaled, mouse)
222 mg/kg (oral, mouse)
160 mg/kg (oral, rat)
430 mg/kg (oral, mammal)
250 mg/kg (oral, rat)
330 mg/kg (oral, mouse)[2]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 3 mg/m3 [skin][1]
REL (Recommended)
TWA 3 mg/m3 [skin][1]
IDLH (Immediate danger)
200 mg/m3[1]
Safety data sheet (SDS) MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Naled (Dibrom) is an organophosphate insecticide.[3][4] Its chemical name is dimethyl 1,2-dibromo-2,2-dichloroethylphosphate.

Naled is stable in anhydrous condition and must be stored away from light. It must also be stored under normal pressure and temperatures. It degrades in the presence of water and alkali, and produces toxic chloride fumes if exposed to acids or acidic fumes. Contact with metals, reducing agents, or sulfhydryls cause naled to release bromide and revert to dichlorvos.[4]

  1. ^ a b c d e f g h i j k NIOSH Pocket Guide to Chemical Hazards. "#0225". National Institute for Occupational Safety and Health (NIOSH).
  2. ^ "Dimethyl-1,2-dibromo-2,2-dichlorethyl phosphate (Naled)". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH). 4 December 2014. Retrieved 17 March 2015.
  3. ^ "Naled Facts". Pesticides Reregistration. Environmental Protection Agency. Archived from the original on 14 June 2012. Retrieved 16 November 2011.
  4. ^ a b "Naled". Extoxnet. Cornell University. Retrieved 16 November 2011.

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