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Boric acid information


Orthoboric acid
Structural formula
Structural formula
Space-filling model
Space-filling model
Boric acid crystals
Names
IUPAC name
Boric acid[1]
Other names
Orthoboric acid, Boracic acid, Sassolite, Borofax, Trihydroxyborane, Boranetriol, Hydrogen borate, Acidum boricum
Identifiers
CAS Number
  • 10043-35-3 checkY
3D model (JSmol)
  • Interactive image
  • Interactive image
ChEBI
  • CHEBI:33118 checkY
ChEMBL
  • ChEMBL42403 checkY
ChemSpider
  • 7346 checkY
ECHA InfoCard 100.030.114 Edit this at Wikidata
EC Number
  • 233-139-2
E number E284 (preservatives)
KEGG
  • D01089 checkY
PubChem CID
  • 7628
UNII
  • R57ZHV85D4 checkY
CompTox Dashboard (EPA)
  • DTXSID1020194 Edit this at Wikidata
InChI
  • InChI=1S/BH3O3/c2-1(3)4/h2-4H checkY
    Key: KGBXLFKZBHKPEV-UHFFFAOYSA-N checkY
  • InChI=1/BH3O3/c2-1(3)4/h2-4H
    Key: KGBXLFKZBHKPEV-UHFFFAOYAI
SMILES
  • OB(O)O
  • [OH+]=[B-](O)O
Properties
Chemical formula
BH3O3
Molar mass 61.83 g·mol−1
Appearance White crystalline solid
Density 1.435 g/cm3
Melting point 170.9 °C (339.6 °F; 444.0 K)
Boiling point 300 °C (572 °F; 573 K)
Solubility in water
2.52 g/100 mL (0 °C)
4.72 g/100 mL (20 °C)
5.7 g/100 mL (25 °C)
19.10 g/100 mL (80 °C)
27.53 g/100 mL (100 °C)
Solubility in other solvents Soluble in lower alcohols
moderately soluble in pyridine
very slightly soluble in acetone
log P -0.29[2]
Acidity (pKa) 9.24 (first proton), 12.4 (second), 13.3 (complete)
Conjugate base Borate
Magnetic susceptibility (χ)
-34.1·10−6 cm3/mol
Structure
Molecular shape
Trigonal planar
Dipole moment
0 D
Pharmacology
ATC code
S02AA03 (WHO) D08AD (WHO)
Hazards
GHS labelling:
Pictograms
GHS08: Health hazard
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Flash point Nonflammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
2660 mg/kg, oral (rat)
Related compounds
Related compounds
Boron trioxide
Borax
Supplementary data page
Boric acid (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Boric acid, more specifically orthoboric acid, is a compound of boron, oxygen, and hydrogen with formula B(OH)3. It may also be called hydrogen orthoborate, trihydroxidoboron or boracic acid.[3] It is usually encountered as colorless crystals or a white powder, that dissolves in water, and occurs in nature as the mineral sassolite. It is a weak acid that yields various borate anions and salts, and can react with alcohols to form borate esters.

Boric acid is often used as an antiseptic, insecticide, flame retardant, neutron absorber, or precursor to other boron compounds.

The term "boric acid" is also used generically for any oxoacid of boron, such as metaboric acid HBO2 and tetraboric acid H2B4O7.

  1. ^ Cite error: The named reference ncbi was invoked but never defined (see the help page).
  2. ^ Cite error: The named reference chemsrc was invoked but never defined (see the help page).
  3. ^ Cite error: The named reference webster was invoked but never defined (see the help page).

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Boric acid

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Boric acid, more specifically orthoboric acid, is a compound of boron, oxygen, and hydrogen with formula B(OH)3. It may also be called hydrogen orthoborate...

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Borax

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easily converted to boric acid and other borates, which have many applications. Its reaction with hydrochloric acid to form boric acid is: Na2B4O7·10H2O...

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Boron trioxide

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Another method is heating boric acid above ~300 °C. Boric acid will initially decompose into steam, (H2O(g)) and metaboric acid (HBO2) at around 170 °C...

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Borate

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solution, boric acid B(OH)3 can act as a weak Brønsted acid, that is, a proton donor, with pKa ~ 9. However, it more often acts as a Lewis acid, accepting...

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Mineral acid

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Hydrochloric acid HCl Nitric acid HNO3 Phosphoric acid H3PO4 Sulfuric acid H2SO4 Boric acid H3BO3 Hydrofluoric acid HF Hydrobromic acid HBr Perchloric acid HClO4...

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Tetraboric acid

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boric acid. Tetraboric acid is formally the parent acid of the tetraborate anion [B4O7]2−. Tetraboric acid can be obtained by heating orthoboric acid...

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Metaboric acid

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decomposition of boric acid. Metaboric acid is formally the parent acid of the metaborate anions. The main forms of metaboric acid are: Modification...

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Roach bait

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roach baits. Boric acid is not a bait in the dry form, but rather broadcast as a dust, that is both a toxin and a desiccant. Boric acid is often formulated...

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Boric

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Boric is a chemistry term that refers to substances containing boron, such as: boric acid or orthoboric acid, B(OH)3 metaboric acid, an acid containing...

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Thermometric titration

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surfactant complex. Acidic solutions of fluoride (including hydrofluoric acid) can be determined by a simple thermometric titration with boric acid. B(OH)3 + 3F−...

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Boron

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electrons for forming covalent bonds, resulting in many compounds such as boric acid, the mineral sodium borate, and the ultra-hard crystals of boron carbide...

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Triethyl borate

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formula B(OCH2CH3)3. It is an ester of boric acid and ethanol. It has few applications. It is a weak Lewis acid (AN = 17 as measured by the Gutmann–Beckett...

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Dakin oxidation

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the acid catalyst (23). Adding boric acid to the acid-catalyzed reaction mixture increases the yield of phenol product over phenyl carboxylic acid product...

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Pressurized water reactor

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supplied to the reactor as an emergency coolant. Depending on burnup, boric acid or another neutron poison will have to be added to emergency coolant to...

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Nickel electroplating

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basket filled with nickel pieces, Edward Weston initiated the use of boric acid (patent issued in 1878), Bancroft figured out the role of chlorides in...

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Piero Ginori Conti

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fortunes in Tuscany. In 1904, Piero Ginori Conti became the head of the boric acid extraction firm founded by his wife's great-grandfather in Larderello...

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TBE buffer

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mixture of Tris base, boric acid and EDTA. In molecular biology, TBE and TAE buffers are often used in procedures involving nucleic acids, the most common...

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Electrogalvanization

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/ Ammonium Chloride) - or (non-ammonium chloride, potassium chloride/Boric acid) or sulfate baths. Dedicated to plating at high speed in plants where...

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Boronic acid

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A boronic acid is an organic compound related to boric acid (B(OH)3) in which one of the three hydroxyl groups (−OH) is replaced by an alkyl or aryl group...

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Boro glycerine

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Boro-glycerine is a transparent yellow, tasteless, compound of boric acid and glycerine. It is a powerful antiseptic and is used primarily in oral and...

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Tetrahydroxydiboron

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resulting tetramethoxydiboron, B2(OCH3)4, to produce what they termed sub-boric acid. The methanol used in this process can be recycled: BCl3   → −   HCl + ...

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Tetrahydroxyborate

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of boric acid. Tetrahydroxyborate has a symmetric tetrahedral geometry,: p.203–205  isoelectronic with the hypothetical compound orthocarbonic acid (C(OH)4)...

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Boron phosphate

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acid and boric acid. It is a white infusible solid that evaporates above 1450 °C. Boron phosphate is synthesized from phosphoric acid and boric acid at...

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Acid

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Strong acids and some concentrated weak acids are corrosive, but there are exceptions such as carboranes and boric acid. The second category of acids are...

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Silicic acid

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resin, or by treating sodium silicates with concentrated sulfuric acid. Boric acid Greenwood, N. N.; Earnshaw, A. (2012). Chemistry of the Elements. Elsevier...

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Tetrafluoroborate

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salts with the Lewis acid BF3, treatment of tetrafluoroboric acid with base, or by treatment of boric acid with hydrofluoric acid. The popularization of...

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Sodium borate

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"Solubility isotherms in the system sodium oxide-boric oxide-water. Revised solubility-temperature curves of boric acid, borax, sodium pentaborate, and sodium metaborate"...

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Kjeldahl method

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is dipped into a known volume of standard acid (i.e. acid of known concentration). A weak acid like boric acid (H3BO3) in excess of ammonia is often used...

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