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Uranium borohydride information


Uranium borohydride
Uranium borohydride
Identifiers
CAS Number
  • 12523-77-2 checkY
3D model (JSmol)
  • Interactive image
PubChem CID
  • 135046781
InChI
  • InChI=1S/2BH5.U/h2*1H5;/q2*-1;+2 checkY
    Key: KUMAXXHQRVBPEC-UHFFFAOYSA-N checkY
  • InChI=1/2BH5.U/h2*1H5;/q2*-1;+2
    Key: KUMAXXHQRVBPEC-UHFFFAOYAW
SMILES
  • [BH4-].[BH4-].[U+4].[BH4-].[BH4-]
Properties
Chemical formula
U(BH4)4
Molar mass 297.27 g/mol
Solubility in other solvents Decomposes
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Uranium borohydride is the inorganic compound with the empirical formula U(BH4)4. Two polymeric forms are known, as well as a monomeric derivative that exists in the gas phase. Because the polymers convert to the gaseous form at mild temperatures, uranium borohydride once attracted much attention. It is solid green.[1]

  1. ^ Cite error: The named reference ephritikhine was invoked but never defined (see the help page).

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Uranium borohydride

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Uranium borohydride is the inorganic compound with the empirical formula U(BH4)4. Two polymeric forms are known, as well as a monomeric derivative that...

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is bidentate. Some homoleptic borohydride complexes are volatile. One example is uranium borohydride. Metal borohydride complexes can often be prepared...

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Sodium borohydride, also known as sodium tetrahydridoborate and sodium tetrahydroborate, is an inorganic compound with the formula NaBH4 (sometimes written...

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increased during World War II due to the potential of uranium borohydride for enrichment of the uranium isotopes and as a source of hydrogen for inflating...

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have sufficient reactivity, obtained by reaction of uranocene with uranium borohydride is the half-sandwich compound (COT)U(BH4)2 discovered in 1983 by...

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Jaqueline Kiplinger

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uranium (IV), and uranium (VI) complexes. Her more recent work details a new route to uranium and thorium metallocene borohydrides. The uranium complex had...

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List of CAS numbers by chemical compound

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39416–30–3 BeAl2O4 beryllium aluminate 120041–06–7 Be(BH4)2 beryllium borohydride 17440–85–6 BeB2 beryllium boride 12228–40–9 BeBr2 beryllium bromide 7787–46–4...

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Ulmas Mirsaidov

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phase equilibrium in ternary system "non-transient metal borohydride – transient element borohydride – solvent". Based on these investigations, a synthesis...

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reacting with sulfur, phosphorus, phosphorus halides, and potassium borohydride. It dissolves exothermically in water to form dark-green solutions that...

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Thorium compounds

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its cerium, uranium, neptunium, and plutonium analogues and has a distorted icosahedral structure. Particularly important is the borohydride, Th(BH 4) 4...

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Borosilicate glass

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the glass can react with sodium hydride upon heating to produce sodium borohydride, a common laboratory reducing agent. Fused quartz is also found in some...

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boryllides are extraordinarily rare. Strong bases do not deprotonate a borohydride R2BH to the boryl anion R2B−, instead forming the octet-complete adduct...

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process (see direct borohydride fuel cell) creates hydrogen as needed, but has other issues, such as the high price of the sodium borohydride that is the raw...

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soil remediation. nZVI nanoparticles can be prepared by using sodium borohydride as the key reductant. NaBH4 (0.2 M) is added into FeCl3•6H2 (0.05 M)...

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Antimony

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produced by treating Sb3+ salts with hydride reagents such as sodium borohydride. Stibine decomposes spontaneously at room temperature. Because stibine...

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Sodium

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chemistry. Metallic sodium is used mainly for the production of sodium borohydride, sodium azide, indigo, and triphenylphosphine. A once-common use was...

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H2 USA

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Proton-exchange membrane fuel cell Solid oxide fuel cell By fuel Direct borohydride fuel cell Direct carbon fuel cell Direct-ethanol fuel cell Direct methanol...

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