Lanthanide triflates are triflate salts of the lanthanides. These salts have been investigated for application in organic synthesis as Lewis acid catalysts. These catalysts function similarly to aluminium chloride or ferric chloride, but they are water-tolerant (stable in water). Commonly written as Ln(OTf)3·(H2O)9 the nine waters are bound to the lanthanide, and the triflates are counteranions, so more accurately lanthanide triflate nonahydrate is written as [Ln(H2O)9](OTf)3.[1]
^Harrowfield, J. M.; Keppert, D. L.; Patrick, J. M.; White, A. H. (1983). "Structure and stereochemistry in "f-block" complexes of high coordination number. VIII. The [M(unidentate)9] system. Crystal structures of [M(OH2)9] [CF3SO3]3, M = lanthanum, gadolinium, lutetium, or yttrium". Australian Journal of Chemistry. 36 (3): 483–492. doi:10.1071/CH9830483.
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Lanthanide triflates are triflate salts of the lanthanides. These salts have been investigated for application in organic synthesis as Lewis acid catalysts...
Lanthanides in the periodic table The lanthanide (/ˈlænθənaɪd/) or lanthanoid (/ˈlænθənɔɪd/) series of chemical elements comprises at least the 14 metallic...
Lawrance, G. A.; Lay, P. A.; Sargeson, A. M.; Taube, H. (1990). "Trifluoromethanesulfonates and Trifluoromethanesulfonato-O Complexes". Inorganic Syntheses...
Lutetium compounds are compounds formed by the lanthanide metal lutetium (Lu). In these compounds, lutetium generally exhibits the +3 oxidation state,...
M.; Macklin, John W. (May 1976). "Vibration spectra and structure of lanthanide fluorosulfate compounds". Inorganic Chemistry. 15 (5): 1216–1220. doi:10...
Transition Metal Acetonitrile Cations with Tetrafluoroborate or Trifluoromethanesulfonate Anions. Inorganic Syntheses. Vol. 33. pp. 75–83. doi:10.1002/0471224502...
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