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Iodine trifluoride dioxide information


Iodine trifluoride dioxide
Names
Other names
Iodyl trifluoride
Identifiers
CAS Number
  • 25402-50-0 checkY
3D model (JSmol)
  • Interactive image
InChI
  • InChI=1S/F3IO2/c1-4(2,3,5)6
    Key: IEYUHHXVKPWNHY-UHFFFAOYSA-N
SMILES
  • F[I](=O)(=O)(F)F
Properties
Chemical formula
F3IO2
Molar mass 215.898 g·mol−1
Appearance yellow crystals
Melting point 41 °C (106 °F; 314 K)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
ignites on contact with flammable organic substances
Related compounds
Related compounds
Iodosyl trifluoride
Iodosyl pentafluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Iodine trifluoride dioxide is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula IO2F3.[1][2][3] The compound was first obtained by Engelbrecht and Petersy in 1969.[4]

  1. ^ Haynes, William M. (4 June 2014). CRC Handbook of Chemistry and Physics. CRC Press. p. 4-67. ISBN 978-1-4822-0868-9. Retrieved 24 May 2023.
  2. ^ "iodine trifluoride dioxide". ChemSrc. Retrieved 24 May 2023.
  3. ^ Carter, H. A.; Ruddick, J. N.; Sams, J. R.; Aubke, F. (1 January 1975). "Some reactions of iodine(VII) dioxide trifluoride, IO2F3". Inorganic and Nuclear Chemistry Letters. 11 (1): 29–34. doi:10.1016/0020-1650(75)80142-5. ISSN 0020-1650. Retrieved 24 May 2023.
  4. ^ Advances in Inorganic Chemistry. Academic Press. 1 November 1983. p. 180. ISBN 978-0-08-057876-7. Retrieved 24 May 2023.

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Iodine trifluoride dioxide

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Iodine trifluoride dioxide is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula IO2F3. The compound was first obtained by...

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Chlorine trifluoride dioxide

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Chlorine trifluoride dioxide is an inorganic compound of chlorine, fluorine, and oxygen with the chemical formula ClO2F3. Synthesis of chlorine trifluoride dioxide...

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Iodine

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−45 °C, with iodine trifluoride in trichlorofluoromethane at −78 °C, or with silver(I) fluoride at 0 °C. Iodine monochloride (ICl) and iodine monobromide...

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Interhalogen

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fluorinating agent. It has the same molecular shape as chlorine trifluoride. Iodine trifluoride (IF3) is a yellow solid that decomposes above −28 °C. It can...

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Iodine compounds

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and sulfur dioxide (to phosgene, nitrosyl chloride, and sulfuryl chloride respectively), iodine will not do so. Furthermore, iodination of metals tends...

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Oxidizing agent

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and other analogous halogen oxyanions Fluorides of chlorine, bromine, and iodine Hexavalent chromium compounds such as chromic and dichromic acids and chromium...

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Bromine

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fluorinating reagent than chlorine trifluoride. It reacts vigorously with boron, carbon, silicon, arsenic, antimony, iodine, and sulfur to give fluorides,...

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Bromine dioxide

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Bromine dioxide is the chemical compound composed of bromine and oxygen with the formula BrO2. It forms unstable yellow to yellow-orange crystals. It...

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List of inorganic compounds

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Germanium dioxide – GeO2 Gold(III) oxide – Au2O3 Hafnium dioxide – HfO2 Holmium(III) oxide – Ho2O3 Indium(I) oxide – In2O Indium(III) oxide – In2O3 Iodine pentoxide...

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Chlorine

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225 °C, though it must then be separated and purified from chlorine trifluoride and its reactants. Its properties are mostly intermediate between those...

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Thiophosphoryl fluoride

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"Reaction of phosphorus trifluoride and thiophosphoryl fluoride with iodine monochloride and oxidation of phosphorus trifluoride with nitryl chloride, iodic...

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Bromine compounds

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fluorinating reagent than chlorine trifluoride. It reacts vigorously with boron, carbon, silicon, arsenic, antimony, iodine, and sulfur to give fluorides,...

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Fluorine

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tetrachloride, normally incombustible, may explode. Although nitrogen trifluoride is stable, nitrogen requires an electric discharge at elevated temperatures...

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Electrophile

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electrophile. As observed by Olah, a mixture of acetic acid and boron trifluoride is able to remove a hydride ion from isobutane when combined with hydrofluoric...

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Uranium compounds

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prepared by hydrofluorination of uranium dioxide. Reduction of UF 4 with hydrogen at 1000 °C produces uranium trifluoride (UF 3). Under the right conditions...

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Industrial gas

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ammonia (NH3) carbon dioxide (CO2) carbon monoxide (CO) hydrogen chloride (HCl) nitrous oxide (N2O) nitrogen trifluoride (NF3) sulfur dioxide (SO2) sulfur hexafluoride...

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Inorganic nonaqueous solvent

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members include sulfur dioxide, sulfuryl chloride fluoride, dinitrogen tetroxide, antimony trichloride, and bromine trifluoride. These solvents have proven...

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HSAB theory

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cases are also identified: borderline acids are trimethylborane, sulfur dioxide and ferrous Fe2+, cobalt Co2+ caesium Cs+ and lead Pb2+ cations. Borderline...

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Standard Gibbs free energy of formation

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Boron trichloride Solid BCl3 −388.7 Bromine Bromine Liquid Br2 0 Bromine trifluoride Gas BrF3 −229.4 Hydrobromic acid Gas HBr −53.4 Calcium Calcium Solid...

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List of viscosities

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1021/ie50501a040. Hetherington, G.; Robinson, P.L. (1956). "The Viscosities of Iodine Pentafluoride and Ditellurium Decafluoride". Journal of the Chemical Society...

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Nitrogen

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gas; it burns in fluorine with a greenish-yellow flame to give nitrogen trifluoride. Reactions with the other nonmetals are very complex and tend to lead...

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Standard enthalpy of formation

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of formation. For example, the standard enthalpy of formation of carbon dioxide is the enthalpy of the following reaction under the above conditions: C...

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Acid

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which form a covalent bond with an electron pair. An example is boron trifluoride (BF3), whose boron atom has a vacant orbital that can form a covalent...

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Iodosyl pentafluoride

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iodine, fluorine, and oxygen with the chemical formula IOF5. Reaction of iodine heptafluoride with water. IF7 + H2O → IOF5 + 2HF Reaction of iodine heptafluoride...

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Polyhalogen ions

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three halogen atoms are tightly bound. The fluorine–fluorine bond of trifluoride, with bond order 0.5, has a bond-strength is 30 kcal/mol, only 8 kcal/mol...

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Thorium

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which tarnishes olive gray when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high melting point. Thorium...

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Xenon compounds

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in each oxidation state is analogous to that of the neighboring element iodine in the immediately lower oxidation state. Three fluorides are known: XeF...

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Lanthanide compounds

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of the lanthanides form trihalides with fluorine, chlorine, bromine and iodine. They are all high melting and predominantly ionic in nature. The fluorides...

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Metalloid

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tinea versicolor. Iodine is used as a disinfectant in various forms. Bismuth is an ingredient in some antibacterials. Boron trifluoride and trichloride...

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