Heinz Hunsdiecker Cläre Hunsdiecker Alexander Borodin
Reaction type
Substitution reaction
Identifiers
Organic Chemistry Portal
hunsdiecker-reaction
RSC ontology ID
RXNO:0000106
The Hunsdiecker reaction (also called the Borodin reaction or the Hunsdiecker–Borodin reaction) is a name reaction in organic chemistry whereby silver salts of carboxylic acids react with a halogen to produce an organic halide.[1] It is an example of both a decarboxylation and a halogenation reaction as the product has one fewer carbon atoms than the starting material (lost as carbon dioxide) and a halogen atom is introduced its place.[2][3] A catalytic approach has been developed.[4]
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and 26 Related for: Hunsdiecker reaction information
The Hunsdieckerreaction (also called the Borodin reaction or the Hunsdiecker–Borodin reaction) is a name reaction in organic chemistry whereby silver...
Heinz Hunsdiecker (22 January 1904 – 22 November 1981) was a German chemist who together with his wife Cläre Hunsdiecker (1903–1995) improved a reaction of...
1942. The method is generally known as either the Hunsdieckerreaction or the Hunsdiecker–Borodin reaction. During 1862, Borodin returned to the Medical–Surgical...
short lived intermediate in the Hunsdieckerreaction. Acetyl hypochlorite is reported to be produced by the reaction of acetic anhydride and dichlorine...
substitution reaction involves radicals. An example is the Hunsdieckerreaction. Coupling reactions are a class of metal-catalyzed reactions involving an...
Schmidt reaction converts carboxylic acids to amines. Carboxylic acids are decarboxylated in the Hunsdieckerreaction. The Dakin–West reaction converts...
acetate and a lithium halide. The reaction is a variation of the Hunsdieckerreaction. A New Method for Halodecarboxylation of Acids Using Lead(IV) Acetate...
methods, such as the Balz–Schiemann reaction, are used to prepare fluorinated aromatic compounds. In the Hunsdieckerreaction, carboxylic acids are converted...
chemistry, often as acyl hypohalites (see the Hunsdieckerreaction). Sodium hypohalite is used in the haloform reaction as a test for methyl ketones. The Cl-O...
1-bromo-3-chlorocyclobutane can also be prepared via a modified Hunsdieckerreaction from 3-chlorocyclobutanecarboxylic acid using mercuric oxide and...
dicarboxylic acid 6. The acid is decarboxylated with a modified Hunsdieckerreaction to a dibromide 7, which is reductively debrominated with tributyltin...
substitution of carboxylic acid to iodide is demonstrated by a modified Hunsdieckerreaction. Homolytic cleavage of O-I bond generates CO2 and vinyl radical....
formation of gas which drives the reaction forward. Barton–McCombie deoxygenation Hunsdieckerreaction Kochi reaction Krapcho decarboxylation Kolbe electrolysis...
the synthesis of haloalkanes from carboxylic acids are Hunsdieckerreaction and Kochi reaction. Many chloro and bromoalkanes are formed naturally. The...
Born and Robert Oppenheimer Borodin–Hunsdieckerreaction – Alexander Borodin, Hienz Hunsdiecker, and Clare Hunsdiecker (née Dieckmann) Borrmann effect (a...
group for a proton. The Wohl–Ziegler reaction involves allylic bromination of alkenes. The Hunsdieckerreaction converts silver salts of carboxylic acids...
decarboxylations are generally radical reactions. These include the Kolbe electrolysis and Hunsdiecker-Kochi reactions. The Barton decarboxylation is an unusual...
National Academy of Sciences. He developed the Kochi reaction, a variation on the Hunsdieckerreaction. Kochi was of Japanese descent and he and his family...
Crich, D.; Motherwell, W. B. (1983). "A practical alternative to the hunsdieckerreaction". Tetrahedron Letters. 24 (45): 4979. doi:10.1016/S0040-4039(01)99826-0...
functionalized with urea, guanidine, thiourea and aminosilane. Using the Hunsdieckerreaction, carbon nanotubes treated with nitric acid can react with iodosobenzenediacetate...
be effected by heating in quinoline in the presence of copper salts. Hunsdiecker decarboxylation can be achieved by heating the silver salt. It is excreted...
ineffective methods: From salts of fluoroacetic acid using a Hunsdiecker type of reaction. From dibromofluoromethane by reductive debromination with a...
to disulfides.: 406–408 In air, tris(thiophenyl)stibine catalyzes a Hunsdiecker-like decarboxylative oxidation of anhydrides to alcohols.: 411 In ultraviolet...
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