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Fluorine nitrate information


Fluorine nitrate
Structural formulas of fluorine nitrate, showing its resonance structure
Ball-and-stick model of the fluorine nitrate molecule
Names
Other names
Nitryl hypofluorite
Identifiers
CAS Number
  • 7789-26-6 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 109875
PubChem CID
  • 123262
UNII
  • 1Q6BYH7F2B
CompTox Dashboard (EPA)
  • DTXSID20228502 Edit this at Wikidata
InChI
  • InChI=1S/FNO3/c1-5-2(3)4
    Key: VHFBTKQOIBRGQP-UHFFFAOYSA-N
SMILES
  • FO[N+](=O)[O-]
Properties
Chemical formula
FNO3
Molar mass 81.002 g·mol−1
Density 2.217 g/L[1]
Melting point −175 °C (−283.0 °F; 98.1 K)
Boiling point −46 °C (−51 °F; 227 K)
Thermochemistry
Std enthalpy of
formation fH298)
+10.46 kJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Explosive gas
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Fluorine nitrate is an unstable derivative of nitric acid with the formula FNO
3
. It is shock-sensitive.[1] Due to its instability, it is often produced from chlorine nitrate as needed[citation needed]. Fluorine nitrate is an inert molecule thought to play a significant role in atmospheric chemistry.[2]

  1. ^ a b Ruff, Otto; Kwasnik, Walter (1935). "The fluorination of nitric acid. The nitroxyfluoride, NO3F". Angewandte Chemie. 48: 238–240. doi:10.1002/ange.19350481604.
  2. ^ Jensen, James O. (2005-03-07). "Vibrational frequencies and structural determination of fluorine nitrate". Journal of Molecular Structure: THEOCHEM. 716 (1): 11–17. doi:10.1016/j.theochem.2004.10.041. ISSN 0166-1280.

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Fluorine nitrate

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Fluorine nitrate is an unstable derivative of nitric acid with the formula FNO 3. It is shock-sensitive. Due to its instability, it is often produced from...

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Nancy J. S.; Leland C. Allen; Raymond A. Firestone (1988). "Fluorine azide and fluorine nitrate: structure and bonding". Inorganic Chemistry. 27 (4): 755–758...

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Tetrafluoroammonium

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perchlorate (ClO− 4). Attempts to make the nitrate salt, NF 4NO 3, were unsuccessful because of quick fluorination: NF+ 4 + NO− 3 → NF 3 + FONO 2. The geometry...

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Halogen

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group in the periodic table consisting of six chemically related elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and the radioactive elements...

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List of gases

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chemical forms including organic nitrogen, ammonium (NH+4), nitrite (NO−2), nitrate (NO−3), nitrous oxide (N2O), nitric oxide (NO) or inorganic nitrogen gas...

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Fertilizer

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nitrogen fixation. The resultant nitric acid was then used as a source of nitrate (NO3−). A factory based on the process was built in Rjukan and Notodden...

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Hydrofluoric acid

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as the fluorine source, including Teflon, fluoropolymers, fluorocarbons, and refrigerants such as freon. Many pharmaceuticals contain fluorine. Most high-volume...

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List of CAS numbers by chemical compound

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Synonyms CAS number FNO3 fluorine nitrate 7789–26–6 FOClO3 fluorine perchlorate 10049–03–3 F2O fluorine monoxide 7783–41–7 F2O2 fluorine dioxide 7783–44–0 Fe...

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Oxidizing agent

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Fenton's reagent Fluorine (F2), chlorine (Cl2), and other halogens Nitric acid (HNO3) and nitrate compounds such as potassium nitrate (KNO3), the oxidizer...

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Nitrogen

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in 1790 when it was found that nitrogen was present in nitric acid and nitrates. Antoine Lavoisier suggested instead the name azote, from the Ancient Greek:...

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Lithium nitrate

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Lithium nitrate is an inorganic compound with the formula LiNO3. It is the lithium salt of nitric acid (an alkali metal nitrate). The salt is deliquescent...

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Glossary of chemical formulae

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FNO nitrosyl fluoride 7789-25-5 FNO2 nitryl fluoride 10022-50-1 FNO3 fluorine nitrate 7789-26-6 FNS thiazyl fluoride 18820-63-8 FNa sodium fluoride 7681-49-4...

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Fluoride nitrate

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Fluoride nitrates are mixed anion compounds that contain both fluoride ions and nitrate ions. Compounds are known for some amino acids and for some heavy...

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Beilstein test

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flame caused by the formation of a copper halide. The test does not detect fluorine/fluorides. This test is no longer frequently used. One reason why it is...

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Chlorine

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atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate...

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Nitrification

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Nitrification is the biological oxidation of ammonia to nitrate via the intermediary nitrite. Nitrification is an important step in the nitrogen cycle...

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Zirconium nitrate

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Zirconium nitrate is a volatile anhydrous transition metal nitrate salt of zirconium with formula Zr(NO3)4. It has alternate names of zirconium tetranitrate...

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Period 2 element

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contains the elements lithium, beryllium, boron, carbon, nitrogen, oxygen, fluorine, and neon. In a quantum mechanical description of atomic structure, this...

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Magnesium acetate

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ashing organic compounds in preparation for a fluorine analysis when high or low concentrations of fluorine are present. Magnesium acetate is a relatively...

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Silver

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compounds are used in photographic and X-ray film. Dilute solutions of silver nitrate and other silver compounds are used as disinfectants and microbiocides...

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Nuclear reprocessing

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via oxidation, and fluoride volatility (which uses extremely reactive Fluorine). Each process results in some form of refined nuclear product, with radioactive...

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Explosive

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industry tends to use nitrate-based explosives such as emulsions of fuel oil and ammonium nitrate solutions, mixtures of ammonium nitrate prills (fertilizer...

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Nitrogen compounds

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are -3 and +3. Nitrogen can form nitride and nitrate ions. It also forms a part of nitric acid and nitrate salts. Nitrogen compounds also have an important...

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Chlorine trifluoride oxide

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monoxide with fluorine. Other substances that could react with fluorine to make it includes sodium chlorite (NaClO2), and chlorine nitrate (ClONO2). The...

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Electrophilic aromatic directing groups

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dominates for purposes of directing the sites of reactivity. For nitration, for example, fluorine directs strongly to the para position because the ortho position...

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Astatine

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estimated from its position on the periodic table as a heavier analog of fluorine, chlorine, bromine, and iodine, the four stable halogens. However, astatine...

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Redox

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Eo ox(anode) In the reaction between hydrogen and fluorine, hydrogen is being oxidized and fluorine is being reduced: H2 + F2 → 2 HF This reaction is...

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Adamantane

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