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Enthalpy of sublimation information


In thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at a given combination of temperature and pressure, usually standard temperature and pressure (STP). It is equal to the cohesive energy of the solid. For elemental metals, it is also equal to the standard enthalpy of formation of the gaseous metal atoms.[1] The heat of sublimation is usually expressed in kJ/mol, although the less customary kJ/kg is also encountered.

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Enthalpy of sublimation

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thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at...

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Enthalpy of vaporization

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dependence of the heat of vaporization Enthalpy of fusion, specific heat of melting Enthalpy of sublimation Joback method, estimation of the heat of vaporization...

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Enthalpy of atomization

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bond dissociation enthalpies. The enthalpy of atomization of an elemental solid is exactly the same as the enthalpy of sublimation for any elemental solid...

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Enthalpy

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In thermodynamics, enthalpy /ˈɛnθəlpi/ , is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. It is a state...

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Standard enthalpy of formation

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the sum of several steps, each with its own enthalpy (or energy, approximately): Hsub, the standard enthalpy of atomization (or sublimation) of solid lithium...

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Dry ice

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sublimation to a gas makes dry ice an effective coolant, since it is colder than water ice and leaves no residue as it changes state. Its enthalpy of...

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Surface energy

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reason, considering the enthalpy of sublimation can be useful in determining the pairwise intermolecular energy. Enthalpy of sublimation can be calculated by...

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Latent heat

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of vaporization falls to zero. Bowen ratio Eddy covariance flux (eddy correlation, eddy flux) Sublimation (physics) Specific heat capacity Enthalpy of...

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State of matter

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freezing. Solids can also change directly into gases through the process of sublimation, and gases can likewise change directly into solids through deposition...

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Thermodynamic databases for pure substances

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applies to the transition of a liquid to a vapor and is designated ΔHv. Enthalpy of sublimation. This applies to the transition of a solid to a vapor and...

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Mendelevium

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mendelevium metal to have an enthalpy of sublimation between 134 and 142 kJ/mol. Divalent mendelevium metal should have a metallic radius of around 194±10 pm. Like...

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Hexachlorophosphazene

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Purification by sublimation gives mainly the trimer and tetramer. Slow vacuum sublimation at approximately 60 °C affords the pure trimer free of the tetramer...

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Ununennium

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than the K–K bond. From these M2 dissociation energies, the enthalpy of sublimation (ΔHsub) of ununennium is predicted to be 94 kJ/mol (the value for francium...

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Dinitrobenzene

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(2011). "Triacetone triperoxide thermogravimetric study of vapor pressure and enthalpy of sublimation in 303–338K temperature range". Thermochimica Acta....

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Lawrencium

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yet known experimentally. The enthalpy of sublimation of lawrencium is estimated at 352 kJ/mol, close to the value of lutetium and strongly suggesting...

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Unbinilium

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dissociation energies, the enthalpy of sublimation (ΔHsub) of unbinilium is predicted to be 150 kJ/mol. The Ubn–Au bond should be the weakest of all bonds between...

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Platinum tetrafluoride

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tetrafluoride vapour at 298.15 K consists of individual molecules. The enthalpy of sublimation is 210 kJmol−1. Original analysis of powdered PtF4 suggested a tetrahedral...

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Nobelium

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and actinides. In 1986, nobelium metal was estimated to have an enthalpy of sublimation between 126 kJ/mol, a value close to the values for einsteinium...

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Endothermic process

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In terms of thermodynamics and thermochemistry, it is a thermodynamic process with an increase in the enthalpy H (or internal energy U) of the system...

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Nihonium

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theoretically predicted that nihonium should have an enthalpy of sublimation around 150 kJ/mol and an enthalpy of adsorption on a gold surface around −159 kJ/mol...

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Tin telluride

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be particularly good. Standard enthalpy of formation: - 14.6 ± 0.3 kcal/mole at 298 K Standard Enthalpy of sublimation: 52.1 ± 1.4 kcal/mole at 298 K...

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Acenaphthylene

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fluorescence. Acenaphthylene occurs as about 2% of coal tar. It is produced industrially by gas phase dehydrogenation of acenaphthene. Hydrogenation gives the more...

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Wind tunnel

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introduction of turbulent airflow into the airstream. Sublimation (alternate definition): A flow visualization technique is to coat the model in a sublimatable material...

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