Fullerene molecule with additional atoms, ions, or clusters enclosed within itself
Rendering of a buckminsterfullerene containing a noble gas atom (M@C60).Electron microscopy images of M3N@C80 peapods. Metal atoms (M = Ho or Sc) are seen as dark spots inside the fullerene molecules; they are doubly encapsulated in the C80 molecules and in the nanotubes.[1]
Endohedral fullerenes, also called endofullerenes, are fullerenes that have additional atoms, ions, or clusters enclosed within their inner spheres. The first lanthanum C60 complex called La@C60 was synthesized in 1985.[2] The @ (at sign) in the name reflects the notion of a small molecule trapped inside a shell. Two types of endohedral complexes exist: endohedral metallofullerenes and non-metal doped fullerenes.
^Gimenez-Lopez, Maria del Carmen; Chuvilin, Andrey; Kaiser, Ute; Khlobystov, Andrei N. (2010). "Functionalised endohedral fullerenes in single-walled carbon nanotubes". Chem. Commun. 47 (7): 2116–2118. doi:10.1039/C0CC02929G. hdl:10347/32317. PMID 21183975.
^Chai, Yan; Guo, Ting; Jin, Changming; Haufler, Robert E.; Chibante, L. P. Felipe; Fure, Jan; Wang, Lihong; Alford, J. Michael; Smalley, Richard E. (1991). "Fullerenes wlth Metals Inside". Journal of Physical Chemistry. 95 (20): 7564–7568. doi:10.1021/j100173a002.
and 29 Related for: Endohedral fullerene information
Endohedralfullerenes, also called endofullerenes, are fullerenes that have additional atoms, ions, or clusters enclosed within their inner spheres. The...
trapped inside fullerenes to form inclusion compounds known as endohedralfullerenes. An unusual example is the egg-shaped fullerene Tb3N@C 84, which...
Endohedral hydrogen fullerene (H2@C60) is an endohedralfullerene containing molecular hydrogen. This chemical compound has a potential application in...
classes: exohedral fullerenes with substituents outside the cage and endohedralfullerenes with trapped molecules inside the cage. This article covers the...
H2 and noble gas can be encapsulated inside the C60 cage. These endohedralfullerenes are usually synthesized by doping in the metal atoms in an arc reactor...
materials, and as supramolecular building blocks. Exohedral fullereneEndohedralfullerene Alan L. Balch; Joong W. Lee; Bruce C. Noll; Marilyn M. Olmstead...
the fullerene. Researchers had originally been puzzled by C 72 being absent in fullerene plasma-generated soot extract, but found in endohedral samples...
in ice. Noble gases can form endohedralfullerene compounds, in which the noble gas atom is trapped inside a fullerene molecule. In 1993, it was discovered...
This notation was proposed in 1991 with the discovery of fullerene cages (endohedralfullerenes), which can trap atoms such as La to form, for example,...
produced. Noble gases can also form endohedralfullerene compounds where the noble gas atom is trapped inside a fullerene molecule. In 1993, it was discovered...
intercalation compounds alkali metal fullerides endohedralfullerenes, where the metal atom is encapsulated within a fullerene molecule metallacarbohedrenes (met-cars)...
such as C50Cl10 and C60H8. or fullerene ligands. Fullerene ligands Endohedralfullerene "Capturing the Labile Fullerene[50] as C50Cl10". Science. 304...
molecules. For instance, La@C60 means lanthanum inside a fullerene cage. See article Endohedralfullerene for details. In Malagasy, @ is an informal abbreviation...
also form endohedralfullerene compounds, where a xenon atom is trapped inside a fullerene molecule. The xenon atom trapped in the fullerene can be observed...
the fullerenes as the third allotropic form of carbon. Subsequent discoveries included the endohedralfullerenes, and the larger family of fullerenes the...
into the hollow carbon cage molecules (the fullerenes) by heating under high pressure. The endohedralfullerene molecules formed are stable at high temperatures...
ендоедральному фулерені Не2@C60 (On the Problem of He–He Bond in the EndohedralFullerene He2@C60)". Ukrainian Journal of Physics. 63 (4): 288. doi:10.15407/ujpe63...
research into the formation of alternate fullerene compounds (e.g. C28, C70), as well as the synthesis of endohedral metallofullerenes (M@C60), reports of...
the team moved on to synthesize endohedralfullerenes that had a metal atom inside the hollow carbon shell. The fullerenes, a class of molecules of which...
ways to carry therapeutic radioactive ions to cancerous tissue. Endohedralfullerene "Support for top-down theory of how 'buckyballs' form". KurzweilAI...
is of comparable size to fullerene and should be capable of containing small atoms in the same manner as endohedralfullerenes, and indeed exists a Sn12...
previously undetected higher fullerenes (larger than C70) (until 2018 when this record was broken) and endohedralfullerenes (those that contain encaged...
Examples of supramolecular host molecule include carcerands and endohedralfullerenes. An important implication of encapsulation is that the guest behaves...
also form endohedralfullerene compounds, where a xenon atom is trapped inside a fullerene molecule. The xenon atom trapped in the fullerene can be observed...
enclosed by the all-carbon shell of the fullerene. This inclusion is denoted by the "@"symbol in endohedralfullerenes. For example, an ion consisting of a...
reaction parameters, multiple carbon allotropes can be achieved, including endohedral particles composed of predominantly amorphous carbon, carbon nanotubes...
applied to fullerenes by Maurizio Prato, thus gaining the name. It is known that the Prato reaction is very useful to functionalize endohedral metallofullerenes...
compounds graphite–Y or graphite–Y 2O 3 leads to the formation of endohedralfullerenes such as Y@C82. Electron spin resonance studies indicated the formation...
Global Information
