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Fig. 1: Radical disproportionation via a radical elimination mechanismFig. 2: Depolymerization of polystyrene via a radical elimination mechanismFig. 3: An acyl-CoA dehydrogenase-catalyzed reaction in a radical elimination reaction
An elimination reaction of free radicals is the mechanism by which free radicals can undergo an elimination reaction to form olefins.[1] Such reactions are usually not major pathways for radical mediated reactions.
^Ansylen, E. V.; Dougherty, D. A. Modern Physical Organic Chemistry. p. 586, ISBN 978-1-891389-31-3
and 23 Related for: Elimination reaction of free radicals information
Organic reactions are chemical reactions involving organic compounds. The basic organic chemistry reaction types are addition reactions, elimination reactions...
in this reaction. Radicals are highly reactive and short-lived, as they have an unpaired electron which makes it extremely unstable. Radicals often react...
addition of free-radical building blocks (repeat units). Freeradicals can be formed by a number of different mechanisms, usually involving separate initiator...
double-bond character. An addition reaction is the reverse of an eliminationreaction. For instance, the hydration of an alkene to an alcohol is reversed...
freeradicals. As with the free-radical substitution, the radical addition proceeds as a chain reaction, and such reactions are the basis of the free-radical...
stable precursors to hydroxyl radicals. 60%–70% of cellular DNA damage is caused by hydroxyl radicals, yet hydroxyl radicals are so reactive that they can...
short-lived, like most radicals; however, they form an important part of nitrogen chemistry. In sufficiently high concentration, amino radicals dimerise to form...
mechanism (Elimination Internal/Intramolecular), also known as a thermal syn elimination or a pericyclic syn elimination, is a special type ofelimination reaction...
Radical disproportionation encompasses a group ofreactions in organic chemistry in which two radicals react to form two different non-radical products...
the hydroxyl radical cannot be eliminated by an enzymatic reaction. Mechanisms for scavenging peroxyl radicals for the protection of cellular structures...
a radical clock is a chemical compound that assists in the indirect methodology to determine the kinetics of a free-radicalreaction. The radical-clock...
temperatures, leaving radicals on the polymer backbone. Radicals formed on the polymer backbone by either hydrogen abstraction side-group elimination can cause the...
oxidation–reduction: 150 ) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase...
and reductive elimination using sodium amalgam[1][2] or SmI2.[3] The reaction is named after the French chemist Marc Julia. The utility of this connective...
the reaction mechanism is unclear, involvement of an aryl radical is presumed after loss of nitrogen in the diazonium salt followed by a freeradical addition...
its most characteristic reaction, AIBN decomposes, eliminating a molecule of nitrogen gas to form two 2-cyanoprop-2-yl radicals: Because azobisisobutyronitrile...
effort was undertaken in the developments of Cu-free Sonogashira reaction. Along the development of new reaction conditions, many experimental and computational...
allow a milder syn-elimination such as the Chugaev elimination and the Grieco elimination. Related reactions include eliminations by β-haloethers (the...
nitroxide radicals would react with any carbon radicals formed during polymerization, use of a monomer with a nitroxide radical isn't practical. One of the...
polymerization reactions and ... paved the way for new and highly useful industrial processes". He is also known for his work involving free-radicals, many-membered...
possibility is a free-radical process, if radical initiators are present in the reaction mixture. For example, the ene reactionof cyclopentene and cyclohexene...
Desulfonylation reactions are chemical reactions leading to the removal of a sulfonyl group from organic compounds. As the sulfonyl functional group is...
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