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Desulfonylation reactions information


Desulfonylation reactions are chemical reactions leading to the removal of a sulfonyl group from organic compounds. As the sulfonyl functional group is electron-withdrawing,[1] methods for cleaving the sulfur–carbon bonds of sulfones are typically reductive in nature. Olefination or replacement with hydrogen may be accomplished using reductive desulfonylation methods.[2]

  1. ^ Kharasch, Norman; Meyers, Cal Y. (2013-10-22). The Chemistry of Organic Sulfur Compounds. Elsevier. ISBN 978-1-4831-5611-8.
  2. ^ Alonso, Diego A.; Ájera, Carmen N (2009). "Desulfonylation Reactions". Organic Reactions. doi:10.1002/0471264180.or072.02. ISBN 978-0471264187.

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Desulfonylation reactions

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Desulfonylation reactions are chemical reactions leading to the removal of a sulfonyl group from organic compounds. As the sulfonyl functional group is...

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Samarium

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Friedel–Crafts reaction with alkenes. Samarium(II) iodide is a very common reducing and coupling agent in organic synthesis, for example in desulfonylation reactions;...

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to bases, eliminating to give an alkene. Sulfones can also undergo desulfonylation. Sulfolane is used to extract valuable aromatic compounds from petroleum...

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ISSN 0022-3263. Little, R.Daniel; Myong, Sun Ok (1980). "Oxidative desulfonylation. Phenyl vinyl sulfone as a ketene synthetic equivalent". Tetrahedron...

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