Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Dimethylformamide is an organic compound with the chemical formula HCON(CH3)2. Its structure is HC(=O)−N(−CH3)2. Commonly abbreviated as DMF (although this initialism is sometimes used for dimethylfuran, or dimethyl fumarate), this colourless liquid is miscible with water and the majority of organic liquids. DMF is a common solvent for chemical reactions. Dimethylformamide is odorless, but technical-grade or degraded samples often have a fishy smell due to impurity of dimethylamine. Dimethylamine degradation impurities can be removed by sparging samples with an inert gas such as argon or by sonicating the samples under reduced pressure. As its name indicates, it is structurally related to formamide, having two methyl groups in the place of the two hydrogens. DMF is a polar (hydrophilic) aprotic solvent with a high boiling point. It facilitates reactions that follow polar mechanisms, such as SN2 reactions.
^N,N-Dimethylmethanamide, NIST web thermo tables
^Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. pp. 841, 844. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4. The traditional name 'formamide' is retained for HCO-NH2 and is the preferred IUPAC name. Substitution is permitted on the –NH2 group.
^"Hazardous Substances Data Bank (HSDB) - N,N-DIMETHYLFORMAMIDE".
^ abcNIOSH Pocket Guide to Chemical Hazards. "#0226". National Institute for Occupational Safety and Health (NIOSH).
^ ab"Dimethylformamide". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
Dimethylformamide is an organic compound with the chemical formula HCON(CH3)2. Its structure is HC(=O)−N(−CH3)2. Commonly abbreviated as DMF (although...
(H−C(=O)−NH2), acetamide (H3C−C(=O)−NH2), benzamide (C6H5−C(=O)−NH2), and dimethylformamide (H−C(=O)−N(−CH3)2). Some uncommon examples of amides are N-chloroacetamide...
Turpentine Naphtha Toluene Lacquer thinner Methyl ethyl ketone (MEK) Dimethylformamide (DMF) Glycol ethers, such as 2-Butoxyethanol Less common solvents...
acids with thionyl chloride (SOCl2). The reaction is catalyzed by dimethylformamide and other additives. Thionyl chloride is a well-suited reagent as...
Swern oxidation. Oxalyl chloride is mainly used together with a N,N-dimethylformamide catalyst in organic synthesis for the preparation of acyl chlorides...
Deuterated dimethylformamide ((CD3)2NCOD), also known as deuterated DMF, is an isotopologue of DMF ((CH3)2NCOH) in which the hydrogen atom ("H") is replaced...
from 0.8 g/mL at 20 °C to 0.3 g/mL at 80 °C for [CH3NH3]PbBr3 in dimethylformamide. This property is used in the growth of MALH single crystals and films...
the four CO ligands. A classic example of a fluxional molecule is dimethylformamide (DMF). At temperatures near 100 °C, the 500 MHz 1H NMR spectrum of...
20 {\displaystyle [\alpha ]_{D}^{20}} +65° to +72° cm3/dm·g (1% in dimethylformamide). In 2010, Teva and Perrigo launched the first generic inhalable triamcinolone...
Formamides are compounds of the type RR′NCHO. One important formamide is dimethylformamide, (CH3)2NCHO. In the past, formamide was produced by treating formic...
DMF may refer to: Dimethylformamide, a common solvent Dimethyl fumarate, a small molecule anti-inflammatory human medicine 2,5-Dimethylfuran, a liquid...
dipolar solvent. It is an environmentally friendly alternative to dimethylformamide (DMF) and N-methyl-2-pyrrolidone (NMP). Dihydrolevoglucosenone can...
pyridinium cations. The Cornforth reagent is readily soluble in water, dimethylformamide and dimethyl sulfoxide (DMSO). It is poorly soluble in acetone and...
created at the Buna Werke Schkopau (Polyacrylonitrile) and Leuna works (Dimethylformamide). In the same year, the collective was awarded the GDR's National...
Vilsmeier reaction or Vilsmeier-Haack reaction that use mixtures of dimethylformamide and phosphorus oxychloride to generate the Vilsmeier reagent, which...
softening cured cyanoacrylate. Other solvents include nitromethane, dimethylformamide, dimethyl sulfoxide, and methylene chloride. Another viable solvent...
the substance which then need to be further purified. The solvents dimethylformamide and dimethylacetamide are derived from dimethylamine. It is raw material...
Kazunori; Watanabe, Takao; Ikeda, Masayuki (1992-01-01). "Occupational dimethylformamide exposure". International Archives of Occupational and Environmental...
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