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Diacetyl peroxide information


Diacetyl peroxide
Skeletal formula
Ball-and-stick model
Names
Preferred IUPAC name
Acetic peroxyanhydride[2]
Other names
acetyl peroxide (2:1); diacetyl peroxide; Peroxide, diacetyl; ethanoyl peroxide; acetyl ethaneperoxoate; ethanoyl ethane peroxoate;[1] peracetic acid acetyl ester
Identifiers
CAS Number
  • 110-22-5 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 7749 checkY
ECHA InfoCard 100.003.409 Edit this at Wikidata
EC Number
  • 203-748-8
PubChem CID
  • 8040
UNII
  • FDU6Y8075A checkY
UN number 2084
CompTox Dashboard (EPA)
  • DTXSID4059384 Edit this at Wikidata
InChI
  • InChI=1S/C4H6O4/c1-3(5)7-8-4(2)6/h1-2H3 checkY
    Key: ZQMIGQNCOMNODD-UHFFFAOYSA-N checkY
SMILES
  • O=C(OOC(=O)C)C
Properties
Chemical formula
C4H6O4
Molar mass 118.088 g·mol−1
Appearance Colorless crystals[3]
Density 1.163 g/cm3[3]
Melting point 30 °C (86 °F; 303 K)
Boiling point 121.4 °C (250.5 °F; 394.5 K) at 760 mmHg; 63 °C (145 °F; 336 K) at 21 mmHg[4]
Solubility in water
slight in cold water [3]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Explosive, oxidizer
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 2: Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Flash point between 38 and 93 °C (100 and 200 °F). E.g. diesel fuelInstability 4: Readily capable of detonation or explosive decomposition at normal temperatures and pressures. E.g. nitroglycerinSpecial hazards (white): no code
1
2
4
Flash point 32.2 °C (90.0 °F; 305.3 K) (45 °C [113 °F; 318 K][5])
Explosive data
Shock sensitivity Very high / moderate when wet
Friction sensitivity Very high / moderate when wet
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Diacetyl peroxide is the organic peroxide with the formula (CH3CO2)2. It is a white solid or oily liquid with a sharp odor.[5] As with a number of organic peroxides, it is explosive.[6] It is often used as a solution, e.g., in dimethyl phthalate.[3]

  1. ^ Diacetyl peroxide
  2. ^ International Union of Pure and Applied Chemistry (2014). Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013. The Royal Society of Chemistry. p. 829. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.
  3. ^ a b c d Lewis, R. J. Sr, ed. (1997). Hawley's Condensed Chemical Dictionary (13th ed.). New York, NY: John Wiley & Sons. p. 13.
  4. ^ Lide, D. R., ed. (1998–1999). CRC Handbook of Chemistry and Physics (79th ed.). Boca Raton, Florida: CRC Press. pp. 3–250.
  5. ^ a b "Acetyl peroxide" (PDF). NJ.gov.
  6. ^ Sax, N. I. (1975). Dangerous Properties of Industrial Materials (4th ed.). New York, NY: Van Nostrand Reinhold. p. 357. ISBN 9780442273682.

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Diacetyl peroxide

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C4H6O4

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molecular formula C4H6O4 (molar mass: 118.09 g/mol) may refer to: Diacetyl peroxide Dimethyl oxalate Glycerol-1,2-carbonate Methylmalonic acid (MMA) Succinic...

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Highly hazardous chemical

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List of compounds with carbon number 4

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Butanone

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by reaction with ethyl nitrite to give diacetyl monoxime followed by conversion to the dioxime: In the peroxide process on producing hydrazine, the starting...

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Urea

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Urea is readily quantified by a number of different methods, such as the diacetyl monoxime colorimetric method, and the Berthelot reaction (after initial...

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Peroxyacyl nitrates

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ketones, or the photolysis of dicarbonyl compounds such as methylglyoxal or diacetyl. Since they dissociate quite slowly in the atmosphere into radicals and...

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Lactobacillus

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diverse mix of anaerobic microorganisms. Lactobacilli produce hydrogen peroxide which inhibits the growth and virulence of the fungal pathogen Candida...

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E number

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diglycerides of fatty acids emulsifier Approved in the EU. E472e Mono- and diacetyl tartaric acid esters of mono- and diglycerides of fatty acids emulsifier...

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Certain flavorings contain diacetyl and acetyl propionyl which give a buttery taste. Some sweet flavors containing diacetyl and acetyl propionyl include...

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Glossary of chemical formulae

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4-Butynediol C4H6O2 gamma-Butyrolactone C4H6O2 crotonic acid 3724-65-0 C4H6O2 diacetyl C4H6O2 diepoxybutane C4H6O2 1,4-Dioxene C4H6O2 isocrotonic acid C4H6O2...

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Ketone

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of diketones are known, some with unusual properties. The simplest is diacetyl (CH3C(O)C(O)CH3), once used as butter-flavoring in popcorn. Acetylacetone...

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Winemaking

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reason why some chardonnays can taste "buttery" due to the production of diacetyl by the bacteria. Most red wines go through complete malolactic fermentation...

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Homoserine dehydrogenase EC 1.1.1.3 Aminopropanol oxidoreductase EC 1.1.1.4 Diacetyl reductase EC 1.1.1.5 Glycerol dehydrogenase EC 1.1.1.6 Propanediol-phosphate...

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