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Degree of unsaturation information


In the analysis of the molecular formula of organic molecules, the degree of unsaturation (DU) (also known as the index of hydrogen deficiency (IHD), double bond equivalents (DBE), or unsaturation index[1]) is a calculation that determines the total number of rings and π bonds. A formula is used in organic chemistry to help draw chemical structures. It does not give any information about those components individually—the specific number of rings, or of double bonds (one π bond each), or of triple bonds (two π bonds each). The final structure is verified with use of NMR, mass spectrometry and IR spectroscopy, as well as qualitative inspection. It is based on comparing the actual molecular formula to what would be a possible formula if the structure were saturated—having no rings and containing only σ bonds—with all atoms having their standard valence.

  1. ^ Sparkman, David O. (2006). Mass Spectrometry Desk Reference. Pittsburgh: Global View Pub. p. 54. ISBN 0-9660813-9-0.

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Degree of unsaturation

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In the analysis of the molecular formula of organic molecules, the degree of unsaturation (DU) (also known as the index of hydrogen deficiency (IHD), double...

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Degree

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transparency Degree of unsaturation, in organic chemistry, also known as the index of hydrogen deficiency or rings plus double bonds dGH, degrees of general...

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Saturation

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unsaturated compounds, a classification of compounds related to their ability to resist addition reactions Degree of unsaturation Saturated fat or saturated fatty...

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Saturated and unsaturated compounds

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a system of naming conventions used to describe the type and location of unsaturation within organic compounds. The "degree of unsaturation" is a formula...

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Unsaturated fat

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e., fewer calories) than an equivalent amount of saturated fat. The greater the degree of unsaturation in a fatty acid (i.e., the more double bonds in...

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Iodine value

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mass of iodine in grams that is consumed by 100 grams of a chemical substance. Iodine numbers are often used to determine the degree of unsaturation in...

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Peroxide value

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a high degree of unsaturation are most susceptible to autoxidation. The best test for autoxidation (oxidative rancidity) is determination of the peroxide...

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Urushiol

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likelihood and severity of allergic reaction to urushiol is dependent on the degree of unsaturation of the hydrocarbon chain. Less than half of the general population...

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Mass spectral interpretation

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the degree of unsaturation is u = ( n − r + 2 ) 2 {\displaystyle u={\frac {\left(n-r+2\right)}{2}}\,} A negative value of u indicates the presence of heteroatoms...

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Chia seed

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phenolic compounds, whereas high temperature reduces oil content and degree of unsaturation, and raises protein content. S. hispanica is described and pictured...

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Alkene

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used to test the saturation of hydrocarbons. The bromine test can also be used as an indication of the degree of unsaturation for unsaturated hydrocarbons...

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Cardanol

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compound because the composition of the side chain varies in its degree of unsaturation. Tri-unsaturated cardanol, the major component (41%) is shown below...

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Linoleum

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would crack. Linoleum in essence consists of two components, a polymerizable organic compound and a collection of fillers, pigments, catalysts. The polymerizable...

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Aromaticity

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so unreactive toward addition reactions, given its presumed high degree of unsaturation. The cyclohexatriene structure for benzene was first proposed by...

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Triglyceride

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and 10.58 kcal/g – a decrease of about 0.6% for each additional double bond. The greater the degree of unsaturation in a fatty acid (i.e., the more...

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Salvia hispanica

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temperature reduces oil content and degree of unsaturation, and raises protein content.[citation needed] The cultivation of S. hispanica requires light to...

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Alkenone

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proportionally. This means that the relative degree of unsaturation of alkenones can be used to estimate the temperature of the water in which the alkenone-producing...

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Halogenation

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analytical method. The iodine number and bromine number are measures of the degree of unsaturation for fats and other organic compounds. Aromatic compounds are...

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Glyceride

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contain different carbon numbers, different degrees of unsaturation, and different configurations and positions of olefins. Vegetable oils and animal fats...

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Hyperconjugation

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the strain of the molecule would have to be considered. The strain of five-membered rings increased with a decrease degree of unsaturation. This was a...

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Trans fat

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amount of hydrogen (and, thus, single bonds) in the fatty acid. This subsequent lesser degree of unsaturation (and, simultaneously, greater degree of saturation)...

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Bromine number

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The bromine number indicates the degree of unsaturation of a sample. The technique can be subject to a variety of problems, whereby the sample consumes...

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Elaidinization

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the degree of unsaturation. The term originates from elaidic acid, the trans-isomer of oleic acid. Elaidinization of oleic acid, a common component of vegetable...

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Drying oil

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polymerize) by the action of oxygen (not through the evaporation of water or other solvents). Drying oils are a key component of oil paint and some varnishes...

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Aromatization

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pathway for aromatization. The activation barrier decreases with the degree of unsaturation. Thus, cyclohexadienes are especially prone to aromatization. Formally...

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Cell membrane

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unsaturated, with the configuration of the double bonds nearly always "cis". The length and the degree of unsaturation of fatty acid chains have a profound...

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Membrane lipid

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configuration of the double bonds nearly always cis. The length and the degree of unsaturation of FAs chains have a profound effect on membranes' fluidity. Plant...

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Oil paint

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(arsenic sulfide), have fallen from use. Many pigments are toxic to some degree. Commonly used reds and yellows are produced using cadmium, and vermilion...

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