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Cyclopentadienyl radical information


Cyclopentadienyl radical
Names
Preferred IUPAC name
Cyclopenta-2,4-dien-1-yl[1]
Other names
Cyclopentadienyl[1]
Identifiers
CAS Number
  • 2143-53-5
3D model (JSmol)
  • Interactive image
Beilstein Reference
2070324
ChEBI
  • CHEBI:36769
ChemSpider
  • 121110 checkY
Gmelin Reference
323080
PubChem CID
  • 137443
CompTox Dashboard (EPA)
  • DTXSID00175702 Edit this at Wikidata
InChI
  • InChI=1S/C5H5/c1-2-4-5-3-1/h1-5H checkY
    Key: HPYIUKIBUJFXII-UHFFFAOYSA-N checkY
SMILES
  • [CH]1C=CC=C1
Properties
Chemical formula
C5H5
Molar mass 65.095 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

In chemistry, cyclopentadienyl is a radical with the formula C5H5.

The related cyclopentadienyl anion (which can formally be converted to the cyclopentadienyl radical by one-electron reduction) is aromatic, and forms salts and coordination compounds.

  1. ^ a b Henri A. Favre; Warren H. Powell (2014). Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013. Cambridge, England: The Royal Society of Chemistry. p. 1052. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.

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Cyclopentadienyl radical

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chemistry, cyclopentadienyl is a radical with the formula C5H5. The related cyclopentadienyl anion (which can formally be converted to the cyclopentadienyl radical...

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Cyclopentadienyl

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Cyclopentadienyl can refer to Cyclopentadienyl anion, or cyclopentadienide, [C 5H 5]− Cyclopentadienyl ligand Cyclopentadienyl radical, [C 5H 5]• Cyclopentadienyl...

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Cyclopentadienyl anion

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cyclopentadienyl anion. Cyclopentadienyl anions form a variety of cyclopentadienyl complexes. Cyclopentadienyl radical, [C 5H 5]• Cyclopentadienyl cation...

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CPH

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railmotor, a diesel train in Australia Cyclopentadiene, C5H6 (the cyclopentadienyl radical, C5H5, is often abbreviated Cp) This disambiguation page lists...

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Benzopyran

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reactive than one would expect otherwise. A similar example is the cyclopentadienyl radical. Commonly, benzopyran is encountered in the reduced state, in which...

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Ferrocene

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the formula Fe(C5H5)2. The molecule is a complex consisting of two cyclopentadienyl rings sandwiching a central iron atom. It is an orange solid with a...

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Rhodocene

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(−196 °C [−321 °F]). At room temperature, pairs of these radicals join via their cyclopentadienyl rings to form a dimer, a yellow solid. The history of organometallic...

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Cyclopentadienylcobalt dicarbonyl

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It is a dark red air sensitive liquid. This compound features one cyclopentadienyl ring that is bound in an η5-manner and two carbonyl ligands. The compound...

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Titanocene dichloride

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Bis(η5-Cyclopentadienyl) Titanium(IV), Zirconium(IV), Molybdenum(IV), and Tungsten(IV)". Cyclometallapolysulfanes (and Selanes) of Bis(η5-Cyclopentadienyl)...

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Functional group

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named -um. Examples are tropylium and triphenylmethyl cations and the cyclopentadienyl anion. Haloalkanes are a class of molecule that is defined by a carbon–halogen...

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Cyclopentadiene

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compound with the formula C5H6. It is often abbreviated CpH because the cyclopentadienyl anion is abbreviated Cp−. This colorless liquid has a strong and unpleasant...

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List of compounds with carbon number 5

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furancarboxylic acid 26447-28-9 C5H5 cyclopentadiene 542-92-7 C5H5 cyclopentadienyl radical 2143-53-5 C5H5As arsabenzene 289-31-6 C5H5Bi bismin 289-52-1 C5H5Co...

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Cyclopentadienylcobalt dinitrosyl

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was insensitive to the polarity of the solvent. Substitutions on the cyclopentadienyl did not affect the reactivity of the intermediate, but the permethylated...

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Ferrous

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organometallic compounds, such as the ferrocene [Fe(C2H5)2], where two cyclopentadienyl anions are bound to the FeII centre. All known forms of life require...

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Methylcyclopentadienyl manganese tricarbonyl

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Methylcyclopentadienyl Manganese Tricarbonyl: Photolysis, Reaction with Hydroxyl Radicals and Ozone". Environmental Science & Technology. 33 (23): 4232–4238. Bibcode:1999EnST...

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Living polymerization

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chelates and phenoxy-imine chelates. Ansa-cyclopentadienyl-amido (CpA) initiators CpA initiators have one cyclopentadienyl substituent and one or more nitrogen...

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Arenium ion

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water and then with triethylamine hydrolyzes the ether group. Aryl radical Cyclopentadienyl anion Meisenheimer complex, the analogous intermediate in nucleophilic...

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Electron counting

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2 cyclopentadienyl-rings contribute 5 each: 8 + 2 × 5 = 18 electrons ionic counting: Fe2+ contributes 6 electrons, the two aromatic cyclopentadienyl rings...

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Allotropes of arsenic

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gray arsenic towards transition metals are known. In these reactions, cyclopentadienyl complexes of molybdenum, tungsten and chromium proceed via loss of...

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Zirconocene dichloride

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organozirconium compound composed of a zirconium central atom, with two cyclopentadienyl and two chloro ligands. It is a colourless diamagnetic solid that is...

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Pentadiene

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pentadienyl anion is a ligand, the acyclic analogue of the more-common cyclopentadienyl anion. The pentadienyl anion is generated by deprotonation of pentadiene...

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Aromaticity

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is found in ions as well: the cyclopropenyl cation (2e system), the cyclopentadienyl anion (6e system), the tropylium ion (6e), and the cyclooctatetraene...

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Chemical symbol

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denote iso-, sec-, or tert- isomers, respectively) Bz: benzoyl Cp: cyclopentadienyl Cp*: pentamethylcyclopentadienyl Cy: cyclohexyl Cyp: cyclopentyl Et:...

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Borinic acid

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properties and applications of subvalent thallium complexes with alkyl, cyclopentadienyl, arene or hydrotris (pyrazolyl) borate ligands". Coordination Chemistry...

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CP

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basis set superposition error in quantum chemistry Cross-polarization Cyclopentadienyl ligand (Cp), read as "C P", the cyclic C 5H 5 fragment in a coordination...

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IUPAC nomenclature of inorganic chemistry 2005

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are discrete molecules of bis(η5-cyclopentadienyl)metal (and ring-substituted analogues), where the cyclopentadienyl rings are essentially parallel, and...

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