Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Cycloheptatriene (CHT) is an organic compound with the formula C7H8. It is a closed ring of seven carbon atoms joined by three double bonds (as the name implies) and four single bonds. This colourless liquid has been of recurring theoretical interest in organic chemistry. It is a ligand in organometallic chemistry and a building block in organic synthesis. Cycloheptatriene is not aromatic, as reflected by the nonplanarity of the methylene bridge (-CH2-) with respect to the other atoms; however the related tropylium cation is.
^Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. p. 223. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4.
Cycloheptatriene (CHT) is an organic compound with the formula C7H8. It is a closed ring of seven carbon atoms joined by three double bonds (as the name...
of [C7H7]+. Its name derives from the molecule tropine from which cycloheptatriene (tropylidene) was first synthesized in 1881. Salts of the tropylium...
The compound has no practical value but is a prototypical complex of cycloheptatriene. The compound is prepared by thermal reaction of the triene with molybdenum...
The molecular formula C7H8 (molar mass: 92.14 g/mol) may refer to: Cycloheptatriene Isotoluenes Norbornadiene Quadricyclane Toluene, or toluol This set...
using both thermal and photochemical pathways in the synthesis of cycloheptatriene derivatives. The resulting product was a mixture of four isomeric carboxylic...
is usually viewed as resulting from fusion of cyclopentadiene and cycloheptatriene rings. Like naphthalene and cyclodecapentaene, it is a 10 pi electron...
with methanol. The scheme by Kline is based on the reaction of 2,4,6-cycloheptatriene-7-carboxylic acid with methylamine. This is a modified version of U...
with a tricoordinate boron in it. Simple borepins are analogues of cycloheptatriene, which is a seven-membered ring containing three carbon-carbon double...
chemical formula C12H10. It is composed of linked cyclopentadiene and cycloheptatriene rings. In the ground state, which is a singlet state, the central double...
6577-10-2 1,3-Cycloheptadiene 1,4-Cycloheptadiene Cycloheptatriene or its theoretical isomer 1,3,5-Cycloheptatriene Cycloheptene This set index article lists...
Bangladesh Cylinder Head Temperature gauge, an engine control sensor Cycloheptatriene, an organic chemical compound Ford CHT engine, a Compound High Turbulence...
can be stable, e.g. tropylium tetrafluoroborate. It can be made from cycloheptatriene (tropylidene) and bromine or phosphorus pentachloride. It is a planar...
polycyclic hydrocarbon with chemical formula C12H10, composed of one cycloheptatriene ring and two fused cyclopentene rings. List of chemical compounds with...
is a white solid. This compound may be prepared by the reaction of cycloheptatriene with phosphorus pentachloride, followed by tetrafluoroboric acid. Triphenylmethyl...
Technologies in 2004. It is made in two steps from cycloheptatriene. A Diels–Alder reaction of cycloheptatriene with maleic anhydride forms the main ring system...
polycyclic hydrocarbon with chemical formula C12H10, composed of two fused cycloheptatriene rings. It is an unstable, non-planar compound which is non-aromatic...
readily cleaved by ligands to give monoRu half-sandwich derivatives. Cycloheptatriene molybdenum tricarbonyl Cp2V2(CO)5 featuring a pair of semi-bridging...
(1969). "Electrochemical determinations of pKa's. Triphenylmethanes and cycloheptatriene". Journal of the American Chemical Society. 92 (7): 2165. doi:10.1021/ja00710a077...
several adjacent carbon centers. Common examples of such ligands are cycloheptatriene and cyclooctatetraene. The bonding is often denoted using the hapticity...
hydride. Tropylium, C 7H+ 7 arises by the aromatization reaction of cycloheptatriene with hydride acceptors. C 7H 8 + Br 2 → C 7H+ 7 + Br− + HBr The aromatization...
also be obtained in about 1% yield by thermolysis of the adduct of cycloheptatriene and dimethyl acetylenedicarboxylate. Allyl chloride undergoes dehydrohalogenation...
1891 when G. Merling reported that he added bromine to tropylidene (cycloheptatriene) and then heated the product to obtain a crystalline, water-soluble...
laser-pumping source. Adamantane is added to some dyes to prolong their life. Cycloheptatriene and cyclooctatetraene (COT) can be added as triplet quenchers for rhodamine...
rearrangement is the shift of substituents on tropilidenes (1,3,5-cycloheptatrienes). When heated, the pi-system goes through an electrocyclic ring closing...