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Caesium hydroxide information


Caesium hydroxide
Names
Other names
Cesium hydrate
Identifiers
CAS Number
  • 21351-79-1 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:33988 checkY
ChemSpider
  • 56494 checkY
ECHA InfoCard 100.040.298 Edit this at Wikidata
EC Number
  • 244-344-1
PubChem CID
  • 62750
RTECS number
  • FK9800000
UNII
  • 458ZFZ6235
UN number 2682
CompTox Dashboard (EPA)
  • DTXSID7066699 Edit this at Wikidata
InChI
  • InChI=1S/Cs.H2O/h;1H2/q+1;/p-1 checkY
    Key: HUCVOHYBFXVBRW-UHFFFAOYSA-M checkY
  • InChI=1/Cs.H2O/h;1H2/q+1;/p-1
    Key: HUCVOHYBFXVBRW-REWHXWOFAG
SMILES
  • [OH-].[Cs+]
Properties
Chemical formula
CsOH
Molar mass 149.912 g/mol
Appearance Whitish-yellow deliquescent crystals
Density 3.675 g/cm3
Melting point 272 °C (522 °F; 545 K)[3]
Solubility in water
300 g/100 mL at 30 °C
Solubility Soluble in ethanol[1]
Acidity (pKa) 15.76 [2]
Thermochemistry
Heat capacity (C)
69.9 J·mol−1·K−1[4]
Std molar
entropy (S298)
104.2 J·K−1·mol−1
Std enthalpy of
formation fH298)
−416.2 kJ·mol−1
Hazards
GHS labelling:
Pictograms
GHS05: CorrosiveGHS08: Health hazard
Signal word
Danger
Hazard statements
H302, H314, H361, H373
Precautionary statements
P201, P202, P260, P264, P270, P280, P281, P301+P312, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P310, P314, P321, P330, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazard ALK: Alkaline
3
0
1
ALK
Flash point Not flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
570 mg/kg (oral, rat)[6]
NIOSH (US health exposure limits):
PEL (Permissible)
none[5]
REL (Recommended)
TWA 2 mg/m3[5]
IDLH (Immediate danger)
N.D.[5]
Safety data sheet (SDS) ICSC 1592
Related compounds
Other anions
Cæsium oxide
Cæsium fluoride
Other cations
Lithium hydroxide
Sodium hydroxide
Potassium hydroxide
Rubidium hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Caesium hydroxide is a strong base (pKa= 15.76) containing the highly reactive alkali metal caesium, much like the other alkali metal hydroxides such as sodium hydroxide and potassium hydroxide. It is the strongest of the five alkali metal hydroxides.[7] Fused Caesium hydroxide dissolves glass by attacking silica framework and it has applications in bringing glass samples into a solution for analytical purposes in commercial glass industry and defense waste processing facility. The melting process is carried out in a nickel or zirconium crucible.[8] Caesium hydroxide fusion at 750°C produces complete dissolution of glass pellets.[8]

Due to its high reactivity, caesium hydroxide is extremely hygroscopic. Laboratory caesium hydroxide is typically a hydrate.

It is an anisotropic etchant of silicon, exposing octahedral planes. This technique can form pyramids and regularly shaped etch pits for uses such as Microelectromechanical systems. It is known to have a higher selectivity to etch highly p-doped silicon than the more commonly used potassium hydroxide.

This compound is not commonly used in experiments due to the high extraction cost of caesium and its reactive behaviour. It acts in similar fashion to the compounds rubidium hydroxide and potassium hydroxide, although more reactive.

  1. ^ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, pp. 4–51, ISBN 0-8493-0594-2
  2. ^ "Sortierte Liste: pKb-Werte, nach Ordnungszahl sortiert. – Das Periodensystem online".
  3. ^ "ICSC 1592 - Cesium Hydroxide".
  4. ^ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, pp. 5–14, ISBN 0-8493-0594-2
  5. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0111". National Institute for Occupational Safety and Health (NIOSH).
  6. ^ Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases., 21(1)(29), 1977
  7. ^ Considine, Douglas M.; Considine, Glenn D. (2013-12-11). Van Nostrand's Scientific Encyclopedia. Springer Science & Business Media. ISBN 978-1-4757-6918-0.
  8. ^ a b Coleman, C.J; Spencer, W.A. (April 1998). "CsOH is a very strong base that attacks the silica framework of glass under fusion conditions. Cesium Hydroxide Fusion Dissolution of Analytical Reference Glass-1 in Both Powder and Shard Form" (PDF). Westinghouse Savannah River Company. CsOH is a very strong base that attacks the silica framework of glass under fusion conditions.

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Caesium hydroxide

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Caesium hydroxide is a strong base (pKa= 15.76) containing the highly reactive alkali metal caesium, much like the other alkali metal hydroxides such as...

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Caesium

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temperature of caesium is −116 °C (−177 °F), and it ignites explosively in air to form caesium hydroxide and various oxides. Caesium hydroxide is a very strong...

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Alkali hydroxide

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Lithium hydroxide (LiOH) Sodium hydroxide (NaOH) Potassium hydroxide (KOH) Rubidium hydroxide (RbOH) Caesium hydroxide (CsOH) Francium hydroxide (FrOH)...

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Potassium hydroxide

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Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a...

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Lithium hydroxide

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Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids....

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Caesium chloride

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Caesium chloride or cesium chloride is the inorganic compound with the formula CsCl. This colorless salt is an important source of caesium ions in a variety...

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Caesium fluoride

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electronegativity. Caesium fluoride can be prepared by the reaction of caesium hydroxide (CsOH) with hydrofluoric acid (HF) and the resulting salt can then...

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Sodium hydroxide

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Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of...

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Caesium carbonate

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It can also be synthesized by reacting caesium hydroxide with carbon dioxide. 2 CsOH + CO2 → Cs2CO3 + H2O Caesium carbonate facilitates the N-alkylation...

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Francium hydroxide

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francium has never been made. Francium hydroxide's alkalinity is predicted to be stronger than caesium hydroxide. Robert Krebs (2006), "Francium", The...

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Strong electrolyte

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bases Lithium hydroxide, LiOH Sodium hydroxide, NaOH Potassium hydroxide, KOH Rubidium hydroxide, RbOH Caesium hydroxide, CsOH Calcium hydroxide, Ca(OH)2 Strontium...

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Caesium acetate

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CH3COOCs. It is a white solid that may be formed by the reaction of caesium hydroxide or caesium carbonate with acetic acid. It is used in organic synthesis....

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Basic oxide

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produce potassium hydroxide: K2O + H2O → 2 KOH Rubidium oxide reacts with water to produce rubidium hydroxide: Rb2O + H2O → 2 RbOH Caesium oxide reacts with...

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Alkali metal

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Because metallic caesium is too reactive to handle, it is normally offered as caesium azide (CsN3). Caesium hydroxide is formed when caesium interacts aggressively...

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Caesium superoxide

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peroxide and caesium hydroxide. 2 CsO2 + 2 H2O → O2↑ + H2O2 + 2 CsOH Heating to approximately 400 °C induces thermal decomposition to caesium peroxide. The...

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Enthalpy change of solution

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lattice and the attractions between water molecules. Dissolving potassium hydroxide is exothermic, as more energy is released during solvation than is used...

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Caesium monoxide

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Caesium monoxide or caesium oxide is an chemical compound with the chemical formula Cs2O. It is the simplest and most common oxide of the caesium. It...

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Francium

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22 minutes. It is the second-most electropositive element, behind only caesium, and is the second rarest naturally occurring element (after astatine)...

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Caesium auride

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semiconductor with band gap 2.6 eV. The compound hydrolyzes readily, yielding caesium hydroxide, metallic gold, and hydrogen. 2 CsAu + 2 H2O → 2 CsOH + 2 Au + H2...

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Caesium ozonide

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reacting ozone with caesium superoxide: CsO2 + O3 → CsO3 + O2 The compound reacts strongly with any water in the air forming caesium hydroxide. 4 CsO3 + 2 H2O...

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Proton affinity

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for the hydroxide ion (Epa = 1635 kJ/mol), one of the strongest known proton acceptors in the gas phase. Suspensions of potassium hydroxide in dimethyl...

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Caesium azide

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structure. Caesium azide can be prepared from the neutralization reaction between hydrazoic acid and caesium hydroxide: CsOH + HN3 → CsN3 + H2O Caesium carbonate...

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Caesium selenate

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{\displaystyle \uparrow } caesium selenate can also be prepared by the neutralization reaction of selenic acid and caesium hydroxide: 2 CsOH + H 2 SeO 4 ⟶...

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Glossary of chemical formulae

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spellings may differ, such as aluminum/aluminium, sulfur/sulphur, and caesium/cesium. Contents A B C Ca–Cu D E F G H I K L M N O P R S T U V W X Y Z...

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Caesium tungstate

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reaction between caesium chloride (CsCl) and silver tungstate (Ag2WO4) or the reaction between tungstic acid and caesium hydroxide. Cesium tungstate v t e...

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List of CAS numbers by chemical compound

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CsNO2 caesium nitrite 13454–83–6 CsNO3 caesium nitrate 7789–18–6 CsN3 caesium azide 22750–57–8 CsOH caesium hydroxide 21351–79–1 CsO2 caesium superoxide...

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Caesium cyanide

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sugar. Caesium cyanide has chemical properties similar to potassium cyanide and is very toxic. Hydrogen cyanide reacts with cesium hydroxide giving cesium...

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