Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Caesium hydroxide is a strong base (pKa= 15.76) containing the highly reactive alkali metal caesium, much like the other alkali metal hydroxides such as sodium hydroxide and potassium hydroxide. It is the strongest of the five alkali metal hydroxides.[7] Fused Caesium hydroxide dissolves glass by attacking silica framework and it has applications in bringing glass samples into a solution for analytical purposes in commercial glass industry and defense waste processing facility. The melting process is carried out in a nickel or zirconium crucible.[8] Caesium hydroxide fusion at 750°C produces complete dissolution of glass pellets.[8]
Due to its high reactivity, caesium hydroxide is extremely hygroscopic. Laboratory caesium hydroxide is typically a hydrate.
It is an anisotropic etchant of silicon, exposing octahedral planes. This technique can form pyramids and regularly shaped etch pits for uses such as Microelectromechanical systems. It is known to have a higher selectivity to etch highly p-doped silicon than the more commonly used potassium hydroxide.
This compound is not commonly used in experiments due to the high extraction cost of caesium and its reactive behaviour. It acts in similar fashion to the compounds rubidium hydroxide and potassium hydroxide, although more reactive.
^
Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, pp. 4–51, ISBN 0-8493-0594-2
^"Sortierte Liste: pKb-Werte, nach Ordnungszahl sortiert. – Das Periodensystem online".
^"ICSC 1592 - Cesium Hydroxide".
^
Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, pp. 5–14, ISBN 0-8493-0594-2
^ abcNIOSH Pocket Guide to Chemical Hazards. "#0111". National Institute for Occupational Safety and Health (NIOSH).
^Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases., 21(1)(29), 1977
^Considine, Douglas M.; Considine, Glenn D. (2013-12-11). Van Nostrand's Scientific Encyclopedia. Springer Science & Business Media. ISBN 978-1-4757-6918-0.
^ abColeman, C.J; Spencer, W.A. (April 1998). "CsOH is a very strong base that attacks the silica framework of glass under fusion conditions. Cesium Hydroxide Fusion Dissolution of Analytical Reference Glass-1 in Both Powder and Shard Form" (PDF). Westinghouse Savannah River Company. CsOH is a very strong base that attacks the silica framework of glass under fusion conditions.
Caesiumhydroxide is a strong base (pKa= 15.76) containing the highly reactive alkali metal caesium, much like the other alkali metal hydroxides such as...
temperature of caesium is −116 °C (−177 °F), and it ignites explosively in air to form caesiumhydroxide and various oxides. Caesiumhydroxide is a very strong...
Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a...
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids....
Caesium chloride or cesium chloride is the inorganic compound with the formula CsCl. This colorless salt is an important source of caesium ions in a variety...
electronegativity. Caesium fluoride can be prepared by the reaction of caesiumhydroxide (CsOH) with hydrofluoric acid (HF) and the resulting salt can then...
Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of...
It can also be synthesized by reacting caesiumhydroxide with carbon dioxide. 2 CsOH + CO2 → Cs2CO3 + H2O Caesium carbonate facilitates the N-alkylation...
francium has never been made. Francium hydroxide's alkalinity is predicted to be stronger than caesiumhydroxide. Robert Krebs (2006), "Francium", The...
CH3COOCs. It is a white solid that may be formed by the reaction of caesiumhydroxide or caesium carbonate with acetic acid. It is used in organic synthesis....
Because metallic caesium is too reactive to handle, it is normally offered as caesium azide (CsN3). Caesiumhydroxide is formed when caesium interacts aggressively...
lattice and the attractions between water molecules. Dissolving potassium hydroxide is exothermic, as more energy is released during solvation than is used...
Caesium monoxide or caesium oxide is an chemical compound with the chemical formula Cs2O. It is the simplest and most common oxide of the caesium. It...
22 minutes. It is the second-most electropositive element, behind only caesium, and is the second rarest naturally occurring element (after astatine)...
semiconductor with band gap 2.6 eV. The compound hydrolyzes readily, yielding caesiumhydroxide, metallic gold, and hydrogen. 2 CsAu + 2 H2O → 2 CsOH + 2 Au + H2...
reacting ozone with caesium superoxide: CsO2 + O3 → CsO3 + O2 The compound reacts strongly with any water in the air forming caesiumhydroxide. 4 CsO3 + 2 H2O...
for the hydroxide ion (Epa = 1635 kJ/mol), one of the strongest known proton acceptors in the gas phase. Suspensions of potassium hydroxide in dimethyl...
structure. Caesium azide can be prepared from the neutralization reaction between hydrazoic acid and caesiumhydroxide: CsOH + HN3 → CsN3 + H2O Caesium carbonate...
{\displaystyle \uparrow } caesium selenate can also be prepared by the neutralization reaction of selenic acid and caesiumhydroxide: 2 CsOH + H 2 SeO 4 ⟶...
spellings may differ, such as aluminum/aluminium, sulfur/sulphur, and caesium/cesium. Contents A B C Ca–Cu D E F G H I K L M N O P R S T U V W X Y Z...
reaction between caesium chloride (CsCl) and silver tungstate (Ag2WO4) or the reaction between tungstic acid and caesiumhydroxide. Cesium tungstate v t e...
sugar. Caesium cyanide has chemical properties similar to potassium cyanide and is very toxic. Hydrogen cyanide reacts with cesium hydroxide giving cesium...