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Caesium acetate information


Caesium acetate[1]

Structural formula
anhydrous caesium acetate crystallizes in a hexagonal unit cell.
Unit cell of anhydrous caesium acetate.
Names
Preferred IUPAC name
Caesium acetate
Other names
Cesium acetate
Identifiers
CAS Number
  • 3396-11-0 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 141192 checkY
ECHA InfoCard 100.020.226 Edit this at Wikidata
PubChem CID
  • 160687
UNII
  • M74D2UJ8C9 checkY
CompTox Dashboard (EPA)
  • DTXSID00883971 Edit this at Wikidata
InChI
  • InChI=1S/C2H4O2.Cs/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1 checkY
    Key: ZOAIGCHJWKDIPJ-UHFFFAOYSA-M checkY
  • InChI=1/C2H4O2.Cs/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
    Key: ZOAIGCHJWKDIPJ-REWHXWOFAB
SMILES
  • [Cs+].[O-]C(=O)C
Properties
Chemical formula
C2H3CsO2
Molar mass 191.949 g/mol
Appearance colourless, hygroscopic
Density 2.423 g/cm3, solid
Melting point 194 °C (381 °F; 467 K)
Boiling point 945 °C (1,733 °F; 1,218 K)
Solubility in water
945.1 g/100 g (−2.5 °C)
1345.5 g/100 ml (88.5 °C)
Structure[2]
Crystal structure
Primitve hexagonal
Space group
P6/m, No. 175
Lattice constant
a = 1488.0 pm, c = 397.65 pm[2]
Lattice volume (V)
76.542 cm3·mol−1
Formula units (Z)
6
Hazards
Flash point Non-flammable
Related compounds
Other anions
Caesium formate
Other cations
Lithium acetate
Sodium acetate
Potassium acetate
Rubidium acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Caesium acetate or cesium acetate is an ionic caesium compound with the molecular formula CH3COOCs. It is a white solid that may be formed by the reaction of caesium hydroxide or caesium carbonate with acetic acid.[3]

  1. ^ Weast, Robert C., ed. (1981). CRC Handbook of Chemistry and Physics (62nd ed.). Boca Raton, FL: CRC Press. p. B-91. ISBN 0-8493-0462-8..
  2. ^ a b Lossin, Adalbert; Meyer, Gerd (1993). "Kristallstruktur von Caesiumacetat, Cs(CH3COO)". Zeitschrift für Anorganische und Allgemeine Chemie. 619 (8): 1462–1464. doi:10.1002/zaac.19936190823.
  3. ^ Yode, Ryan (2015), "Cesium Acetate", Encyclopedia of Reagents for Organic Synthesis, John Wiley & Sons, pp. 1–11, doi:10.1002/047084289x.rn01845, ISBN 978-0-470-84289-8, retrieved 2020-07-21

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