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Caesium cadmium chloride information


Caesium cadmium chloride
Names
IUPAC name
Caesium cadmium chloride
Other names
  • Caesium trichlorocadmate
  • Caesium chlorocadmate
  • Caesium trichlorocadmate(II)
Identifiers
CAS Number
  • 13845-08-4
3D model (JSmol)
  • Interactive image
PubChem CID
  • 159356594
InChI
  • InChI=1S/Cd.3ClH.Cs/h;3*1H;/q+2;;;;+1/p-3
    Key: LHZPOBUPLFKLBV-UHFFFAOYSA-K
SMILES
  • [Cd+2]([Cl-])([Cl-])[Cl-].[Cs+]
  • [Cs+].[Cl-] [Cd+2]([Cl-])[Cl-]
Properties
Chemical formula
Cs Cd Cl3
Molar mass 351.675 g/mol
Appearance White or colourless solid
Structure
Crystal structure
hexagonal
Space group
P63/mmc
Lattice constant
a = 7.403, c = 18.406
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Caesium cadmium chloride (CsCdCl3) is a synthetic crystalline material. It belongs to the AMX3 group (where A=alkali metal, M=bivalent metal, X=halogen ions). It crystallizes in a hexagonal space group P63/mmc with unit cell lengths a = 7.403 Å and c = 18.406 Å, with one cadmium ion having D3d symmetry and the other having C3v symmetry.[1]

It is formed when an aqueous solution of hydrochloric acid containing an equimolar solution of caesium chloride and cadmium chloride.[2]

  1. ^ Chang, Jin Rong.; McPherson, Gary L.; Atwood, Jerry L. (December 1975). "Electron paramagnetic resonance spectra of vanadium(II) and nickel(II) doped into crystals of cesium cadmium chloride and a redetermination of the structure of cesium cadmium chloride". Inorganic Chemistry. 14 (12): 3079–3085. doi:10.1021/ic50154a044.
  2. ^ Electron paramagnetic spectrum of manganese(II)-manganese(II) pairs in single crystals of cesium cadmium chloride. Electronic structure of the nonachlorodimanganate(5-) dimer Gary L. McPherson, and Jin Rong Chang, Inorg. Chem., 1976, 15 (5), 1018-1022. doi:10.1021/ic50159a006

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Caesium cadmium chloride

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Caesium cadmium chloride (CsCdCl3) is a synthetic crystalline material. It belongs to the AMX3 group (where A=alkali metal, M=bivalent metal, X=halogen...

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Caesium

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soluble chlorides is produced, and the insoluble chloride double salts of caesium are precipitated as caesium antimony chloride (Cs 4SbCl 7), caesium iodine...

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Cubic crystal system

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is the "interpenetrating primitive cubic" structure, also called a "caesium chloride" or B2 structure. This structure is often confused for a body-centered...

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Alkali metal

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chemical elements lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr). Together with hydrogen they constitute group 1...

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Germane

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sodium chloride structure implying a free rotation of the trihydrogen germanide anion GeH3−, the caesium compound, caesium germyl or caesium trihydrogen...

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Cadmium

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sulfuric acid, and nitric acid dissolve cadmium by forming cadmium chloride (CdCl2), cadmium sulfate (CdSO4), or cadmium nitrate (Cd(NO3)2). The oxidation state...

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Zinc chloride

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and Cl− anions, so, the compound is not caesium pentachlorozincate, but caesium tetrachlorozincate chloride. No compounds containing the [ZnCl6]4− ion...

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Francium

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produced by the reaction of francium chloride and sodium perchlorate. The francium perchlorate coprecipitates with caesium perchlorate. This coprecipitation...

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Rubidium

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yielded 7.3 grams of caesium chloride and 9.2 grams of rubidium chloride. Rubidium was the second element, shortly after caesium, to be discovered by...

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Nuclear reprocessing

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liquid cadmium cathode. Many of the fission products (such as caesium, zirconium and strontium) remain in the salt. As alternatives to the molten cadmium electrode...

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List of inorganic compounds

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Cadmium oxide – CdO Cadmium phosphide – Cd3P2 Cadmium selenide – CdSe Cadmium sulfate – CdSO4 Cadmium sulfide – CdS Cadmium telluride – CdTe Caesium bicarbonate...

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Chlorine

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which commonly involved the heating of chloride salts like ammonium chloride (sal ammoniac) and sodium chloride (common salt), producing various chemical...

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Toxic heavy metal

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especially in environmental contexts. The term has particular application to cadmium, mercury and lead, all of which appear in the World Health Organization's...

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Glossary of chemical formulae

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spellings may differ, such as aluminum/aluminium, sulfur/sulphur, and caesium/cesium. Contents A B C Ca–Cu D E F G H I K L M N O P R S T U V W X Y Z...

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Sodium

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higher than those of the heavier alkali metals potassium, rubidium, and caesium, following periodic trends down the group. These properties change dramatically...

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Radium

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fluorescent chemicals and cause radioluminescence. Radium, in the form of radium chloride, was discovered by Marie and Pierre Curie in 1898 from ore mined at Jáchymov...

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Solubility chart

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Reilly; R. H. Strokes (1971). "The diffusion coefficients of cadmium chloride and cadmium perchlorate in water at 25°". Australian Journal of Chemistry...

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Oxalate

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oxalate adopts the planar, D2h conformation. However, in the structure of caesium oxalate Cs2C2O4 the O–C–C–O dihedral angle is 81(1)°. Therefore, Cs2C2O4...

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Silver

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are palladium (element 46) isotopes, and the primary products after are cadmium (element 48) isotopes. The palladium isotope 107Pd decays by beta emission...

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Flame test

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Period 6 element

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contains 32 elements, tied for the most with period 7, beginning with caesium and ending with radon. Lead is currently the last stable element; all subsequent...

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Potassium

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potassium mineral ends up as potassium chloride after processing. The mineral industry refers to potassium chloride either as potash, muriate of potash,...

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Bismuth

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make joints to other parts. Addition of bismuth to caesium enhances the quantum yield of caesium cathodes. Sintering of bismuth and manganese powders...

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Standard enthalpy of formation

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sulfate Solid CdSO4 −935 Caesium Solid Cs 0 Caesium Gas Cs 76.50 Caesium Liquid Cs 2.09 Caesium(I) ion Gas Cs+ 457.964 Caesium chloride Solid CsCl −443.04 Calcium...

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Ion

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in ionized form it is commonly found with one gained electron, as Cl−. Caesium has the lowest measured ionization energy of all the elements and helium...

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Color of chemicals

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cyan to a greyish hue. The vast majority of simple inorganic (e.g. sodium chloride) and organic compounds (e.g. ethanol) are colorless. Transition metal compounds...

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Phytoremediation

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for the extraction of sodium chloride (common salt) to reclaim fields that were previously flooded by sea water. Caesium-137 and strontium-90 were removed...

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List of CAS numbers by chemical compound

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CsCl caesium chloride 7647–17–8 CsClO3 caesium chlorate 13763–67–2 CsClO4 caesium perchlorate 13454–84–7 CsF caesium fluoride 13400–13–0 CsH caesium hydride...

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