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Bromochloromethane information


Bromochloromethane
Stereo, skeletal formula of bromochloromethane with all explicit hydrogens added
Spacefill model of bromochloromethane
Names
Preferred IUPAC name
Bromo(chloro)methane
Other names
  • Bromochloromethane
  • Borothene[citation needed]
  • Chloromethyl bromide
  • Halon 1011[1]
  • Methylene bromochloride
  • Methyl chlorobromide[1]
  • Monochloromonobromomethane
  • Chlorobromomethane[1]
  • Fluorocarbon 1011[1]
Identifiers
CAS Number
  • 74-97-5 checkY
3D model (JSmol)
  • Interactive image
3DMet
  • B00481
Abbreviations
  • BCM[citation needed]
  • CBM[1]
  • UN 1887
Beilstein Reference
1730801
ChEBI
  • CHEBI:17194 checkY
ChEMBL
  • ChEMBL346918 checkY
ChemSpider
  • 6093 checkY
ECHA InfoCard 100.000.752 Edit this at Wikidata
EC Number
  • 200-826-3
Gmelin Reference
25577
KEGG
  • C02661 checkY
MeSH bromochloromethane
PubChem CID
  • 6333
RTECS number
  • PA5250000
UNII
  • 45WX84110G checkY
UN number 1887
CompTox Dashboard (EPA)
  • DTXSID4021503 Edit this at Wikidata
InChI
  • InChI=1S/CH2BrCl/c2-1-3/h1H2 checkY
    Key: JPOXNPPZZKNXOV-UHFFFAOYSA-N checkY
SMILES
  • ClCBr
Properties
Chemical formula
CH2BrCl
Molar mass 129.38 g·mol−1
Appearance Colorless liquid
Odor Chloroform-like[1]
Density 1.991 g·mL−1
Melting point −88.0 °C; −126.3 °F; 185.2 K
Boiling point 68 °C; 154 °F; 341 K
Solubility in water
16.7 g·L−1
log P 1.55
Vapor pressure 15.60 kPa (at 20.0 °C)
Magnetic susceptibility (χ)
−86.88·10−6·cm3/mol
Refractive index (nD)
1.482
Hazards
GHS labelling:
Pictograms
GHS05: Corrosive GHS07: Exclamation mark
Signal word
Danger
Hazard statements
H315, H318, H332, H335
Precautionary statements
P261, P280, P305+P351+P338
Flash point Non-combustible[1]
Lethal dose or concentration (LD, LC):
LD50 (median dose)
  • 5 g·mol−1 (oral, rat)
  • 20 g·kg−1 (dermal, rabbit)
  • 4300 mg·kg−1 (oral, mouse)[2]
LC50 (median concentration)
3000 ppm (mouse, 7 hr)[2]
LCLo (lowest published)
  • 28,800 ppm (rat, 15 min)
  • 29,000 ppm (rat, 15 min)
  • 27,000 ppm (mouse, 15 min)[2]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 200 ppm (1050 mg/m3)[1]
REL (Recommended)
TWA 200 ppm (1050 mg/m3)[1]
IDLH (Immediate danger)
2000 ppm[1]
Related compounds
Related alkanes
  • Chloromethane
  • Chloroiodomethane
  • Dibromochloromethane
Related compounds
2-Chloroethanol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Bromochloromethane or methylene bromochloride and Halon 1011 is a mixed halomethane. It is a heavy low-viscosity liquid with refractive index 1.4808.

Halon 1011 was invented for use in fire extinguishers in Germany during the mid-1940s, in an attempt to create a less toxic, more effective alternative to carbon tetrachloride. This was a concern in aircraft and tanks as carbon tetrachloride produced highly toxic by-products when discharged onto a fire. It was slightly less toxic, and used up until the late 1960s, being officially banned by the NFPA for use in fire extinguishers in 1969, as safer and more effective agents such as halon 1211 and 1301 were developed. Due to its ozone depletion potential its production was banned from January 1, 2002, at the Eleventh Meeting of the Parties for the Montreal Protocol on Substances that Deplete the Ozone Layer.

A 1950s US CBM fire extinguisher.
Pyrene 1qt. pump-type chlorobromomethane (CB or CBM), 1960s, UK

Bromochloromethane's biodegradation is catalyzed by the hydrolase enzyme alkylhalidase:

CH2BrCl + H2O → CH2O + HBr + HCl
  1. ^ a b c d e f g h i j NIOSH Pocket Guide to Chemical Hazards. "#0123". National Institute for Occupational Safety and Health (NIOSH).
  2. ^ a b c "Chlorobromomethane". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).

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used for gaseous fire suppression as a far less toxic alternative to bromochloromethane. Bromotrifluoromethane is commercially synthesized in a two-step process...

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Halon

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respectively. Hydrogen bromide reacts with dichloromethane to give bromochloromethane and dibromomethane, sequentially: HBr + CH2Cl2 → HCl + CH2BrCl HBr...

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BCM

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Dibromochloromethane

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